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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-benzyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-propan-2-ylacetamide —— C16H19N3O2S
    N-benzyl-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-propan-2-ylacetamide
    —— 2-[2-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one —— C20H18N4O3S
    2-[2-[(3S)-3-(furan-2-yl)-5-(4-methylphenyl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one
    —— (6E)-3-ethylsulfanyl-5-imino-6-[(5-phenylsulfanylfuran-2-yl)methylidene]-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C18H14N4O2S3
    (6E)-3-ethylsulfanyl-5-imino-6-[(5-phenylsulfanylfuran-2-yl)methylidene]-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C14H14BrN3O2S
    N-[(1R)-1-(4-bromophenyl)ethyl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(2R)-butan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C10H15N3O2S
    N-[(2R)-butan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 2-[2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one —— C14H15N3O3S
    2-[2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl]sulfanyl-1H-pyrimidin-6-one
    —— (6E)-5-imino-6-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-3-methylsulfanyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C18H14N4O2S3
    (6E)-5-imino-6-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-3-methylsulfanyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— ethyl 2,4-dimethyl-5-[(2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate —— C16H19N3O4S
    ethyl 2,4-dimethyl-5-[(2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoyl]-1H-pyrrole-3-carboxylate
    —— (6E)-6-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-5-imino-3-methylsulfanyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C17H11ClN4O2S3
    (6E)-6-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-5-imino-3-methylsulfanyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— N-(1-adamantyl)-N-(furan-2-ylmethyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C21H25N3O3S
    N-(1-adamantyl)-N-(furan-2-ylmethyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-(1-cyanocyclopentyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C12H14N4O2S
    N-(1-cyanocyclopentyl)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 7-[(6-oxo-1H-pyrimidin-2-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C11H8N4O2S2
    7-[(6-oxo-1H-pyrimidin-2-yl)sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-[(2S)-3-methylbutan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C11H17N3O2S
    N-[(2S)-3-methylbutan-2-yl]-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— (2R)-N-[(2-fluorophenyl)methyl]-2-(4-methylphenyl)sulfanylpropanamide —— C17H18FNOS
    (2R)-N-[(2-fluorophenyl)methyl]-2-(4-methylphenyl)sulfanylpropanamide
    —— 3-Cyclopropyl-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-4-amine —— C15H15N5S2
    3-Cyclopropyl-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,2,4-triazol-4-amine
    —— (1R)-N-ethyl-1-(4-pyrazin-2-ylsulfanylphenyl)ethanamine —— C14H17N3S
    (1R)-N-ethyl-1-(4-pyrazin-2-ylsulfanylphenyl)ethanamine
    —— (1S)-N-ethyl-1-(4-pyrazin-2-ylsulfanylphenyl)ethanamine —— C14H17N3S
    (1S)-N-ethyl-1-(4-pyrazin-2-ylsulfanylphenyl)ethanamine
    —— (2R)-2-methyl-2-(propan-2-ylamino)-4-pyrazin-2-ylsulfanylbutanenitrile —— C12H18N4S
    (2R)-2-methyl-2-(propan-2-ylamino)-4-pyrazin-2-ylsulfanylbutanenitrile
    —— [2-[[(1R,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C18H24ClNO3S
    [2-[[(1R,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate —— C18H24ClNO3S
    [2-[[(1S,2R)-2-methylcyclohexyl]amino]-2-oxoethyl] 3-(4-chlorophenyl)sulfanylpropanoate
    —— (5-Phenyl-1,3,4-oxadiazol-2-yl)methyl 3-(4-chlorophenyl)sulfanylpropanoate —— C18H15ClN2O3S
    (5-Phenyl-1,3,4-oxadiazol-2-yl)methyl 3-(4-chlorophenyl)sulfanylpropanoate
    —— (1S,2R,4R)-4-methyl-2-pyrimidin-4-ylsulfanylcyclohexane-1-carbonitrile —— C12H15N3S
    (1S,2R,4R)-4-methyl-2-pyrimidin-4-ylsulfanylcyclohexane-1-carbonitrile
    —— (2R)-2-methyl-2-(methylamino)-6-pyrazin-2-ylsulfanylhexanenitrile —— C12H18N4S
    (2R)-2-methyl-2-(methylamino)-6-pyrazin-2-ylsulfanylhexanenitrile
    —— (2S)-2-methyl-2-(methylamino)-6-pyrazin-2-ylsulfanylhexanenitrile —— C12H18N4S
    (2S)-2-methyl-2-(methylamino)-6-pyrazin-2-ylsulfanylhexanenitrile
    —— (1R,2R)-2-pyrimidin-4-ylsulfanylcycloheptane-1-carbonitrile —— C12H15N3S
    (1R,2R)-2-pyrimidin-4-ylsulfanylcycloheptane-1-carbonitrile
    —— (2R)-2-(ethylamino)-2-methyl-5-pyrazin-2-ylsulfanylpentanenitrile —— C12H18N4S
    (2R)-2-(ethylamino)-2-methyl-5-pyrazin-2-ylsulfanylpentanenitrile
    —— (1S,2S)-2-pyrimidin-4-ylsulfanylcycloheptane-1-carbonitrile —— C12H15N3S
    (1S,2S)-2-pyrimidin-4-ylsulfanylcycloheptane-1-carbonitrile
    —— (2S)-2-(cyclopropylamino)-2-methyl-6-pyrazin-2-ylsulfanylhexanenitrile —— C14H20N4S
    (2S)-2-(cyclopropylamino)-2-methyl-6-pyrazin-2-ylsulfanylhexanenitrile
    —— (2R)-2-(cyclopropylamino)-2-methyl-6-pyrazin-2-ylsulfanylhexanenitrile —— C14H20N4S
    (2R)-2-(cyclopropylamino)-2-methyl-6-pyrazin-2-ylsulfanylhexanenitrile
    —— (1R,2R,4R)-4-methyl-2-pyrimidin-4-ylsulfanylcyclohexane-1-carbonitrile —— C12H15N3S
    (1R,2R,4R)-4-methyl-2-pyrimidin-4-ylsulfanylcyclohexane-1-carbonitrile
    —— (2S)-2-(ethylamino)-2-methyl-5-pyrazin-2-ylsulfanylpentanenitrile —— C12H18N4S
    (2S)-2-(ethylamino)-2-methyl-5-pyrazin-2-ylsulfanylpentanenitrile
    —— (1R,2R,4S)-4-methyl-2-pyrimidin-4-ylsulfanylcyclohexane-1-carbonitrile —— C12H15N3S
    (1R,2R,4S)-4-methyl-2-pyrimidin-4-ylsulfanylcyclohexane-1-carbonitrile
    —— (3S)-N'-hydroxy-3-phenyl-3-pyrazin-2-ylsulfanylpropanimidamide —— C13H14N4OS
    (3S)-N'-hydroxy-3-phenyl-3-pyrazin-2-ylsulfanylpropanimidamide
    —— (3R)-N'-hydroxy-3-phenyl-3-pyrazin-2-ylsulfanylpropanimidamide —— C13H14N4OS
    (3R)-N'-hydroxy-3-phenyl-3-pyrazin-2-ylsulfanylpropanimidamide
    —— (1S,2R)-2-pyrimidin-4-ylsulfanylcycloheptane-1-carbonitrile —— C12H15N3S
    (1S,2R)-2-pyrimidin-4-ylsulfanylcycloheptane-1-carbonitrile
    —— N-benzyl-3-[2-(difluoromethylsulfanyl)-4,6-dimethylpyrimidin-5-yl]propanamide —— C17H19F2N3OS
    N-benzyl-3-[2-(difluoromethylsulfanyl)-4,6-dimethylpyrimidin-5-yl]propanamide
    —— 3-fluoro-N'-hydroxy-4-(pyrazin-2-ylsulfanylmethyl)benzenecarboximidamide —— C12H11FN4OS
    3-fluoro-N'-hydroxy-4-(pyrazin-2-ylsulfanylmethyl)benzenecarboximidamide
    —— N-cyclohexyl-3-[2-(difluoromethylsulfanyl)-4,6-dimethylpyrimidin-5-yl]propanamide —— C16H23F2N3OS
    N-cyclohexyl-3-[2-(difluoromethylsulfanyl)-4,6-dimethylpyrimidin-5-yl]propanamide
    —— 2-[[4-methyl-5-[(4S)-4-methylazepan-1-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H20N4O2S
    2-[[4-methyl-5-[(4S)-4-methylazepan-1-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-2-phenyl-2-pyrazin-2-ylsulfanylacetic acid —— C12H10N2O2S
    (2S)-2-phenyl-2-pyrazin-2-ylsulfanylacetic acid
    —— (1S,2S)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid —— C12H16N2O2S
    (1S,2S)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid
    —— 2-[[4-methyl-5-[(4R)-4-methylazepan-1-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H20N4O2S
    2-[[4-methyl-5-[(4R)-4-methylazepan-1-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (5,6-dimethyl-3-pyrazin-2-ylsulfanyl-1H-pyridazin-4-ylidene)-nitrosomethanamine —— C11H12N6OS
    (5,6-dimethyl-3-pyrazin-2-ylsulfanyl-1H-pyridazin-4-ylidene)-nitrosomethanamine
    —— (1R,2S)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid —— C12H16N2O2S
    (1R,2S)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid
    —— (1R,2R,4R)-4-ethyl-2-pyrazin-2-ylsulfanylcyclohexane-1-carbonitrile —— C13H17N3S
    (1R,2R,4R)-4-ethyl-2-pyrazin-2-ylsulfanylcyclohexane-1-carbonitrile
    —— (1R,2R)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid —— C12H16N2O2S
    (1R,2R)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid
    —— nitroso-(4-pyrazin-2-ylsulfanyl-1H-pyridin-2-ylidene)methanamine —— C10H9N5OS
    nitroso-(4-pyrazin-2-ylsulfanyl-1H-pyridin-2-ylidene)methanamine
    —— (1S,2R)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid —— C12H16N2O2S
    (1S,2R)-2-pyrazin-2-ylsulfanylcycloheptane-1-carboxylic acid
    —— (2R)-2-phenyl-2-pyrazin-2-ylsulfanylacetic acid —— C12H10N2O2S
    (2R)-2-phenyl-2-pyrazin-2-ylsulfanylacetic acid
    —— (1R,2R)-1-pyrazin-2-ylsulfanyl-1-pyridin-3-ylpropan-2-amine —— C12H14N4S
    (1R,2R)-1-pyrazin-2-ylsulfanyl-1-pyridin-3-ylpropan-2-amine