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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[4-[(Z)-(5-cyano-1,2-dimethylpyrrol-3-yl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H15N6O3S-
    2-[[4-[(Z)-(5-cyano-1,2-dimethylpyrrol-3-yl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[4-[(Z)-(4-ethylphenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C18H18N4O3S
    2-[[4-[(Z)-(4-ethylphenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H18N4O3S
    2-[[4-[(Z)-[(1S)-cyclohex-3-en-1-yl]methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(Z)-(4-chlorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H12ClN4O3S-
    2-[[4-[(Z)-(4-chlorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[4-[(Z)-(4-fluorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H12FN4O3S-
    2-[[4-[(Z)-(4-fluorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[4-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C20H23N5O3S
    2-[[4-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(2-methylfuran-3-yl)-4-[(Z)-pyridin-2-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C15H13N5O3S
    2-[[5-(2-methylfuran-3-yl)-4-[(Z)-pyridin-2-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(2-methylfuran-3-yl)-4-[(Z)-pyridin-3-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C15H13N5O3S
    2-[[5-(2-methylfuran-3-yl)-4-[(Z)-pyridin-3-ylmethylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(Z)-(3,4-difluorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H12F2N4O3S
    2-[[4-[(Z)-(3,4-difluorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-(2-methylfuran-3-yl)-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H15N4O3S2-
    2-[[5-(2-methylfuran-3-yl)-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2R)-N',N'-dimethyl-2-(4-methylphenyl)sulfanylpropanehydrazide —— C12H18N2OS
    (2R)-N',N'-dimethyl-2-(4-methylphenyl)sulfanylpropanehydrazide
    —— 2-[[4-[(Z)-(2-chlorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C16H12ClN4O3S-
    2-[[4-[(Z)-(2-chlorophenyl)methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[4-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C20H22N5O3S-
    2-[[4-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N',N'-dimethylacetohydrazide —— C14H19N5OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N',N'-dimethylacetohydrazide
    —— (2R)-N',N'-dimethyl-2-phenylsulfanylpropanehydrazide —— C11H16N2OS
    (2R)-N',N'-dimethyl-2-phenylsulfanylpropanehydrazide
    —— (2S)-N',N'-dimethyl-2-phenylsulfanylpropanehydrazide —— C11H16N2OS
    (2S)-N',N'-dimethyl-2-phenylsulfanylpropanehydrazide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N',N'-dimethylacetohydrazide —— C12H18N2OS
    2-(2,4-dimethylphenyl)sulfanyl-N',N'-dimethylacetohydrazide
    —— 2-(3,4-dimethylphenyl)sulfanyl-N',N'-dimethylacetohydrazide —— C12H18N2OS
    2-(3,4-dimethylphenyl)sulfanyl-N',N'-dimethylacetohydrazide
    —— (Z)-3-amino-2-[2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]but-2-enenitrile —— C14H15N5OS2
    (Z)-3-amino-2-[2-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 1-[(2S)-1-methoxypropan-2-yl]-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C13H19N3OS2
    1-[(2S)-1-methoxypropan-2-yl]-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— (2R)-2-(2-methoxyphenoxy)-N-(2-phenylsulfanylphenyl)propanamide —— C22H21NO3S
    (2R)-2-(2-methoxyphenoxy)-N-(2-phenylsulfanylphenyl)propanamide
    —— 4-(4-methoxyphenyl)sulfanyl-3-nitro-N-propan-2-ylbenzenesulfonamide —— C16H18N2O5S2
    4-(4-methoxyphenyl)sulfanyl-3-nitro-N-propan-2-ylbenzenesulfonamide
    —— 1-[4-(4-Methoxyphenyl)sulfanyl-3-nitrophenyl]sulfonylpyrrolidine —— C17H18N2O5S2
    1-[4-(4-Methoxyphenyl)sulfanyl-3-nitrophenyl]sulfonylpyrrolidine
    —— 4-[[4-(4-Methoxyphenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C20H24N3O2S2+
    4-[[4-(4-Methoxyphenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dichlorothiophen-3-yl)ethanone —— C11H9Cl2N3OS3
    2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dichlorothiophen-3-yl)ethanone
    —— (2R)-2-(2-phenylsulfanylethyl)piperidine —— C13H19NS
    (2R)-2-(2-phenylsulfanylethyl)piperidine
    —— 2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C12H18N4O2S2
    2-[[5-(cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4-Chlorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole —— C14H16ClN3OS
    2-[(4-Chlorophenyl)methylsulfanyl]-5-piperidin-4-yl-1,3,4-oxadiazole
    —— 2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C13H15N3OS3
    2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— N-(cyclohexen-1-yl)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methoxyethyl)acetamide —— C20H26N4O2S2
    N-(cyclohexen-1-yl)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-methoxyethyl)acetamide
    —— c-(5-Benzylsulfanyl-[1,3,4]oxadiazol-2-yl)-methylamine —— C10H11N3OS
    c-(5-Benzylsulfanyl-[1,3,4]oxadiazol-2-yl)-methylamine
    —— [5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium —— C10H11FN3OS+
    [5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methylazanium
    —— (1S,2S)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)-2-methylbutan-1-amine —— C14H19N3OS
    (1S,2S)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)-2-methylbutan-1-amine
    —— (5-Propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine —— C6H11N3OS
    (5-Propan-2-ylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine
    —— [(1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium —— C15H22N3OS+
    [(1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]azanium
    —— 2-Ethylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole —— C9H15N3OS
    2-Ethylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole
    —— [(1S)-3-methyl-1-(5-propylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]azanium —— C10H20N3OS+
    [(1S)-3-methyl-1-(5-propylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]azanium
    —— (1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18ClN3OS
    (1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— [(1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium —— C14H19ClN3OS+
    [(1S,2S)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium
    —— 3-(5-Benzylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium —— C12H16N3OS+
    3-(5-Benzylsulfanyl-1,3,4-oxadiazol-2-yl)propylazanium
    —— [5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methanamine —— C10H10ClN3OS
    [5-[(4-Chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]methanamine
    —— (5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine —— C6H11N3OS
    (5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)methanamine
    —— 4-[5-(Benzylsulfanyl)-1,3,4-oxadiazol-2-YL]piperidine —— C14H17N3OS
    4-[5-(Benzylsulfanyl)-1,3,4-oxadiazol-2-YL]piperidine
    —— 3-[5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium —— C12H15FN3OS+
    3-[5-[(4-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]propylazanium
    —— (1S,2S)-2-methyl-1-[5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine —— C15H21N3OS
    (1S,2S)-2-methyl-1-[5-[(3-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine
    —— (1S,2S)-1-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine —— C14H18ClN3OS
    (1S,2S)-1-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutan-1-amine
    —— 2-Methylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole —— C8H13N3OS
    2-Methylsulfanyl-5-piperidin-4-yl-1,3,4-oxadiazole
    —— (1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine —— C15H21N3OS
    (1S,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butan-1-amine
    —— 2-(5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)ethylazanium —— C7H14N3OS+
    2-(5-Propylsulfanyl-1,3,4-oxadiazol-2-yl)ethylazanium
    —— 2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-[1-[(4-fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]ethanone —— C20H21FN4OS2
    2-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-[1-[(4-fluorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]ethanone