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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-phenylcarbamate —— C13H10Cl2N4O2S
    [(E)-(4,6-dichloro-2-methylsulfanylpyrimidin-5-yl)methylideneamino] N-phenylcarbamate
    —— (1E)-1-(dimethylaminomethylidene)-3-(3-methylsulfanylphenyl)thiourea —— C11H15N3S2
    (1E)-1-(dimethylaminomethylidene)-3-(3-methylsulfanylphenyl)thiourea
    —— N'-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide —— C12H10ClN5S3
    N'-[5-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide
    —— N,N-dimethyl-N'-[5-(5-nitropyridin-2-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide —— C10H10N6O2S2
    N,N-dimethyl-N'-[5-(5-nitropyridin-2-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide
    —— N,N-dimethyl-N'-[5-(2-methylquinolin-4-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide —— C15H15N5S2
    N,N-dimethyl-N'-[5-(2-methylquinolin-4-yl)sulfanyl-1,3,4-thiadiazol-2-yl]methanimidamide
    —— methyl (2Z)-2-[(2Z)-3-(3-methylsulfanylphenyl)-4-oxo-2-pyridin-2-ylimino-1,3-thiazolidin-5-ylidene]acetate —— C18H15N3O3S2
    methyl (2Z)-2-[(2Z)-3-(3-methylsulfanylphenyl)-4-oxo-2-pyridin-2-ylimino-1,3-thiazolidin-5-ylidene]acetate
    —— (E)-N-{2-[(4-chlorophenyl)sulfanyl]-2-methylpropylidene}hydroxylamine —— C10H12ClNOS
    (E)-N-{2-[(4-chlorophenyl)sulfanyl]-2-methylpropylidene}hydroxylamine
    —— [(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate —— C18H27NO3S
    [(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate
    —— [(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl 3-(2-fluorophenyl)sulfanylpropanoate —— C18H26FNO3S
    [(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl 3-(2-fluorophenyl)sulfanylpropanoate
    —— 3-nitro-4-{[3-(trifluoromethyl)phenyl]sulfanyl}benzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime —— C21H13Cl2F3N2O3S
    3-nitro-4-{[3-(trifluoromethyl)phenyl]sulfanyl}benzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime
    —— [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate —— C18H27NO3S
    [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate
    —— (E)-N-{2-methyl-2-[(4-methylphenyl)sulfanyl]propylidene}hydroxylamine —— C11H15NOS
    (E)-N-{2-methyl-2-[(4-methylphenyl)sulfanyl]propylidene}hydroxylamine
    —— [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 3-(2-fluorophenyl)sulfanylpropanoate —— C18H26FNO3S
    [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 3-(2-fluorophenyl)sulfanylpropanoate
    —— 3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-methyloxime —— C14H12N2O3S
    3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-methyloxime
    —— 2-propan-2-yloxyethyl (2S)-2-phenylsulfanylpropanoate —— C14H20O3S
    2-propan-2-yloxyethyl (2S)-2-phenylsulfanylpropanoate
    —— N,N-dimethyl-N'-[5-(octylthio)-1,3,4-thiadiazol-2-yl]iminoformamide —— C13H24N4S2
    N,N-dimethyl-N'-[5-(octylthio)-1,3,4-thiadiazol-2-yl]iminoformamide
    —— 3-Nitro-4-(phenylsulfanyl)benzenecarbaldehyde oxime —— C13H10N2O3S
    3-Nitro-4-(phenylsulfanyl)benzenecarbaldehyde oxime
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime —— C14H11ClN2O3S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide —— C16H15ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-cyano-1-cyclopropylethyl]acetamide
    —— [(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(2-methylphenyl)sulfanylacetate —— C18H27NO3S
    [(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(2-methylphenyl)sulfanylacetate
    —— 2-propan-2-yloxyethyl (2R)-2-phenylsulfanylpropanoate —— C14H20O3S
    2-propan-2-yloxyethyl (2R)-2-phenylsulfanylpropanoate
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime —— C20H13Cl3N2O3S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 2-methoxyethyl (2S)-2-phenylsulfanylpropanoate —— C12H16O3S
    2-methoxyethyl (2S)-2-phenylsulfanylpropanoate
    —— 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime —— C21H16Cl2N2O3S
    4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,4-dichlorobenzyl)oxime
    —— [(E)-but-2-enyl] (2S)-2-phenylsulfanylpropanoate —— C13H16O2S
    [(E)-but-2-enyl] (2S)-2-phenylsulfanylpropanoate
    —— [(E)-but-2-enyl] (2R)-2-phenylsulfanylpropanoate —— C13H16O2S
    [(E)-but-2-enyl] (2R)-2-phenylsulfanylpropanoate
    —— [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl (2R)-2-phenylsulfanylpropanoate —— C18H27NO3S
    [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl (2R)-2-phenylsulfanylpropanoate
    —— 4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(4-nitrobenzyl)oxime —— C20H14ClN3O5S
    4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(4-nitrobenzyl)oxime
    —— 4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime —— C21H16Cl2N2O3S
    4-[(4-methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-(2,6-dichlorobenzyl)oxime
    —— 2-methoxyethyl (2R)-2-phenylsulfanylpropanoate —— C12H16O3S
    2-methoxyethyl (2R)-2-phenylsulfanylpropanoate
    —— [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(2-methylphenyl)sulfanylacetate —— C18H27NO3S
    [(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl 2-(2-methylphenyl)sulfanylacetate
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide —— C16H15ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-cyano-1-cyclopropylethyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H17ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]acetamide
    —— N-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]benzenesulfonamide —— C19H13ClF3N3O2S2
    N-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]benzenesulfonamide
    —— 1-(3-chlorophenyl)-5-(4-chlorophenyl)sulfanyl-N-[(E)-dimethylaminomethylideneamino]-4-oxopyridazine-3-carboxamide —— C20H17Cl2N5O2S
    1-(3-chlorophenyl)-5-(4-chlorophenyl)sulfanyl-N-[(E)-dimethylaminomethylideneamino]-4-oxopyridazine-3-carboxamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide —— C16H17ClN4O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide
    —— N,N-dimethyl-N'-(5-octadecylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide —— C23H44N4S2
    N,N-dimethyl-N'-(5-octadecylsulfanyl-1,3,4-thiadiazol-2-yl)methanimidamide
    —— 1-(4-chlorophenyl)-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea —— C20H13Cl2F3N4S2
    1-(4-chlorophenyl)-3-[(E)-[3-(4-chlorophenyl)sulfanyl-5-(trifluoromethyl)pyridin-2-yl]methylideneamino]thiourea
    —— 1-(4-chlorophenyl)-3-[(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea —— C19H13Cl2N5S3
    1-(4-chlorophenyl)-3-[(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea
    —— [(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea —— C13H10ClN5S3
    [(E)-[6-(4-chlorophenyl)sulfanylimidazo[2,1-b][1,3]thiazol-5-yl]methylideneamino]thiourea
    —— 2-(Methylthio)thiophene-3-carbaldehyde oxime —— C6H7NOS2
    2-(Methylthio)thiophene-3-carbaldehyde oxime
    —— N'-[(E)-[5-(Phenylsulfanyl)furan-2-YL]methylidene]pyridine-4-carbohydrazide —— C17H13N3O2S
    N'-[(E)-[5-(Phenylsulfanyl)furan-2-YL]methylidene]pyridine-4-carbohydrazide
    —— (1S)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine —— C21H19FN6O2S
    (1S)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine
    —— (1R)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine —— C21H19FN6O2S
    (1R)-1-[4-(4-fluorophenyl)-5-(8-nitroisoquinolin-5-yl)sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylethanamine
    —— 2-[(4-chlorophenyl)sulfanyl]-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide —— C16H15ClN2OS
    2-[(4-chlorophenyl)sulfanyl]-N'-[(E)-(3-methylphenyl)methylidene]acetohydrazide
    —— N-[(E)-(4-fluorophenyl)methylidene]-3-(methylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine —— C11H9FN6S
    N-[(E)-(4-fluorophenyl)methylidene]-3-(methylsulfanyl)-7H-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-amine
    —— N-[(E)-benzylideneamino]-2-[2-(dimethylamino)-6-methylpyrimidin-4-yl]sulfanylacetamide —— C16H19N5OS
    N-[(E)-benzylideneamino]-2-[2-(dimethylamino)-6-methylpyrimidin-4-yl]sulfanylacetamide
    —— S-methyl (2Z)-5-benzylsulfanyl-2-methylsulfanylcarbonylimino-1,3,4-thiadiazole-3-carbothioate; S-methyl (2Z)-5-benzylsulfanyl-2-propanoylimino-1,3,4-thiadiazole-3-carbothioate —— C27H28N6O4S7
    S-methyl (2Z)-5-benzylsulfanyl-2-methylsulfanylcarbonylimino-1,3,4-thiadiazole-3-carbothioate; S-methyl (2Z)-5-benzylsulfanyl-2-propanoylimino-1,3,4-thiadiazole-3-carbothioate
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [3-(4-chloro-phenyl)-4-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C24H17ClN6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [3-(4-chloro-phenyl)-4-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide
    —— (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-(4-chloro-phenyl)-3-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide —— C24H17ClN6OS3
    (5-Pyridin-2-yl-[1,3,4]thiadiazol-2-ylsulfanyl)-acetic acid [4-(4-chloro-phenyl)-3-phenyl-3H-thiazol-(2E)-ylidene]-hydrazide