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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H25N5OS
    (2R)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (1S)-1-[4-benzyl-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C22H27ClN4S
    (1S)-1-[4-benzyl-5-[(1S)-1-(2-chlorophenyl)ethyl]sulfanyl-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— tert-butyl 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C20H30N4O2S
    tert-butyl 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-propylacetamide —— C19H29N5OS
    2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-propylacetamide
    —— [(1S)-1-[4-benzyl-5-[(3R)-2-oxooxolan-3-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H25N4O2S+
    [(1S)-1-[4-benzyl-5-[(3R)-2-oxooxolan-3-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-4-benzyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C17H26N5OS+
    [(1R)-1-[5-[(2R)-1-amino-1-oxopropan-2-yl]sulfanyl-4-benzyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— N-benzyl-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H31N5OS
    N-benzyl-2-[[4-butyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— [(1S)-1-[4-benzyl-5-[(2S)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C22H30N5O2S+
    [(1S)-1-[4-benzyl-5-[(2S)-1-(furan-2-ylmethylamino)-1-oxopropan-2-yl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (2R)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C21H31N5OS
    (2R)-2-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— tert-butyl 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetate —— C20H30N4O2S
    tert-butyl 2-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— [(1S)-1-[4-butyl-5-[(3R)-3-cyano-4-imino-2-oxopentyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C17H29N6OS+
    [(1S)-1-[4-butyl-5-[(3R)-3-cyano-4-imino-2-oxopentyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— (3-Cyano-4-imino-2-oxopentyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H21N5O3S2
    (3-Cyano-4-imino-2-oxopentyl) 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— [5-(2-Fluorophenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium —— C15H17FN5OS+
    [5-(2-Fluorophenyl)furan-2-yl]methyl-[2-(1-methyltetrazol-5-yl)sulfanylethyl]azanium
    —— Dimethyl-[[5-[(6-methyl-2-pyrrolidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-2-sulfanylidene-1,3,4-oxadiazol-3-yl]methyl]azanium —— C15H23N6OS2+
    Dimethyl-[[5-[(6-methyl-2-pyrrolidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-2-sulfanylidene-1,3,4-oxadiazol-3-yl]methyl]azanium
    —— 4-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C19H17N5O2S
    4-[[4-Benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— (2S)-2-ethanimidoyl-4-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-oxobutanenitrile —— C14H15N5OS2
    (2S)-2-ethanimidoyl-4-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-oxobutanenitrile
    —— methyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-butylphenyl)propanoate —— C16H21N3O2S2
    methyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-(4-butylphenyl)propanoate
    —— ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-phenylpropanoate —— C13H15N3O2S2
    ethyl (2R)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-phenylpropanoate
    —— ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-phenylpropanoate —— C13H15N3O2S2
    ethyl (2S)-2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-3-phenylpropanoate
    —— 4-[2-[(5-Pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethyl]morpholin-4-ium —— C13H17N4O2S+
    4-[2-[(5-Pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]ethyl]morpholin-4-ium
    —— 2-(4-chlorophenyl)sulfanyl-N-(heptan-4-ylideneamino)acetamide —— C15H21ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-(heptan-4-ylideneamino)acetamide
    —— 2-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-pyridin-4-yl-1,3,4-oxadiazole —— C11H9Cl2N3OS
    2-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-5-pyridin-4-yl-1,3,4-oxadiazole
    —— (8R,8aR)-2-ethyl-6-imino-8-(4-methylsulfanylphenyl)-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile —— C21H22N5S+
    (8R,8aR)-2-ethyl-6-imino-8-(4-methylsulfanylphenyl)-1,2,3,5,8,8a-hexahydroisoquinolin-2-ium-5,7,7-tricarbonitrile
    —— 3,6-Dimethyl-5-[(4-methylphenyl)methyl]-2-prop-2-enylsulfanylpyrimidin-4-one —— C17H20N2OS
    3,6-Dimethyl-5-[(4-methylphenyl)methyl]-2-prop-2-enylsulfanylpyrimidin-4-one
    —— 3-(4-methylphenyl)sulfanyl-4-(2-methylpropyl)-2-nitro-5-propan-2-yl-3H-pyrrole —— C18H24N2O2S
    3-(4-methylphenyl)sulfanyl-4-(2-methylpropyl)-2-nitro-5-propan-2-yl-3H-pyrrole
    —— 7,7-dimethyl-4-N-propan-2-yl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-1-ium-4,9-diamine —— C15H22N5S+
    7,7-dimethyl-4-N-propan-2-yl-6,8-dihydropyrimido[4,5-b][1,4]benzothiazin-1-ium-4,9-diamine
    —— 3,6-dimethyl-5-(3-methylbenzyl)-2-[(3-methylbenzyl)sulfanyl]-4(3H)-pyrimidinone —— C22H24N2OS
    3,6-dimethyl-5-(3-methylbenzyl)-2-[(3-methylbenzyl)sulfanyl]-4(3H)-pyrimidinone
    —— (5R,7R)-5,7-dimethyl-2-sulfanylidene-[1,3]dithiolo[4,5-b][1,4]dithiepin-6-one —— C8H8OS5
    (5R,7R)-5,7-dimethyl-2-sulfanylidene-[1,3]dithiolo[4,5-b][1,4]dithiepin-6-one
    —— 2-{[(2-Fluorophenyl)methyl]sulfanyl}-3,6-dimethyl-5-[(2-methylphenyl)methyl]-3,4-dihydropyrimidin-4-one —— C21H21FN2OS
    2-{[(2-Fluorophenyl)methyl]sulfanyl}-3,6-dimethyl-5-[(2-methylphenyl)methyl]-3,4-dihydropyrimidin-4-one
    —— 1-({[4-(2-methoxyethyl)-5-(2-phenylethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetyl)azepane —— C21H30N4O2S
    1-({[4-(2-methoxyethyl)-5-(2-phenylethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetyl)azepane
    —— N,N-dimethyl-4-[(2R,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline —— C19H21N5OS2
    N,N-dimethyl-4-[(2R,5S)-5-[(5-pyridin-4-yl-1,3,4-thiadiazol-2-yl)sulfanylmethyl]-1,3-oxazolidin-2-yl]aniline
    —— 6-[(2S,3S,4S,5R)-3,4,5-trihydroxyoxan-2-yl]sulfanyl-2H-1,2,4-triazine-3,5-dione —— C8H11N3O6S
    6-[(2S,3S,4S,5R)-3,4,5-trihydroxyoxan-2-yl]sulfanyl-2H-1,2,4-triazine-3,5-dione
    —— 2-[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C16H21N3O3S
    2-[3-cyano-4-(methoxymethyl)-6-methylpyridin-2-yl]sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— [2-(4-Methylphenyl)-1,3-thiazol-4-yl]methyl 2-(2-methylphenyl)sulfanylacetate —— C20H19NO2S2
    [2-(4-Methylphenyl)-1,3-thiazol-4-yl]methyl 2-(2-methylphenyl)sulfanylacetate
    —— [(2R)-1-[2-(cyclohexen-1-yl)ethylamino]-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate —— C20H27NO3S
    [(2R)-1-[2-(cyclohexen-1-yl)ethylamino]-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C17H20N2O3S
    [2-[[(1R)-1-cyano-1-cyclopropylethyl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate —— C15H19NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] 2-(2-methylphenyl)sulfanylacetate
    —— [2-Oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] 2-(2-methylphenyl)sulfanylacetate —— C20H20N2O3S
    [2-Oxo-2-(5-phenyl-3,4-dihydropyrazol-2-yl)ethyl] 2-(2-methylphenyl)sulfanylacetate
    —— N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C18H20FNOS
    N-[(1R)-1-(3,4-dimethylphenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C19H21NO4S
    [2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— N-[3-[(2-chlorophenyl)methyl]-1,3-thiazol-2-ylidene]-2-(4-fluorophenyl)sulfanylacetamide —— C18H14ClFN2OS2
    N-[3-[(2-chlorophenyl)methyl]-1,3-thiazol-2-ylidene]-2-(4-fluorophenyl)sulfanylacetamide
    —— 7-{[(4-fluorophenyl)sulfanyl]methyl}-3-methyl-5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C14H11FN2OS2
    7-{[(4-fluorophenyl)sulfanyl]methyl}-3-methyl-5H-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] 1-methylpyrrole-2-carboxylate —— C20H17ClN2O3S
    [2-[2-(4-Chlorophenyl)sulfanylanilino]-2-oxoethyl] 1-methylpyrrole-2-carboxylate
    —— [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate —— C15H19NO5S2
    [2-[[(3R)-1,1-dioxothiolan-3-yl]amino]-2-oxoethyl] 2-(2-methylphenyl)sulfanylacetate
    —— N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide —— C18H20FNOS
    N-[(1S)-1-(3,4-dimethylphenyl)ethyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— (2S)-2-ethanimidoyl-3-oxo-4-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C11H15N5OS
    (2S)-2-ethanimidoyl-3-oxo-4-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (3R)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine —— C15H20N4S
    (3R)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidine
    —— (3R)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidin-1-ium —— C15H21N4S+
    (3R)-3-(5-benzylsulfanyl-4-methyl-1,2,4-triazol-3-yl)piperidin-1-ium
    —— [(4R)-4-[[2-(4-chloro-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetyl]amino]pentyl]-diethylazanium —— C19H33ClN5OS+
    [(4R)-4-[[2-(4-chloro-6-pyrrolidin-1-ylpyrimidin-2-yl)sulfanylacetyl]amino]pentyl]-diethylazanium
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C15H16N2O3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-[(4-phenyl-1,3-thiazol-2-yl)sulfanyl]acetamide