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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanehydrazide —— C9H17N5O2S
    (2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanehydrazide
    —— (2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanehydrazide —— C9H17N5O2S
    (2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylbutanehydrazide
    —— (2S,5R)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide —— C9H16N6O2S
    (2S,5R)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (2S,5S)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide —— C9H16N6O2S
    (2S,5S)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (4R)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide —— C10H19N5O2S
    (4R)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide
    —— (4R)-4-(4,6-diaminopyrimidin-2-yl)sulfanylpentanehydrazide —— C9H16N6OS
    (4R)-4-(4,6-diaminopyrimidin-2-yl)sulfanylpentanehydrazide
    —— (2S,5S)-5-(pyridin-2-ylsulfanylmethyl)oxolane-2-carbohydrazide —— C11H15N3O2S
    (2S,5S)-5-(pyridin-2-ylsulfanylmethyl)oxolane-2-carbohydrazide
    —— (4S)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide —— C10H19N5O2S
    (4S)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide
    —— (2R,5S)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide —— C9H16N6O2S
    (2R,5S)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (2R,5R)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide —— C9H16N6O2S
    (2R,5R)-5-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (4S)-4-(4,6-diaminopyrimidin-2-yl)sulfanylpentanehydrazide —— C9H16N6OS
    (4S)-4-(4,6-diaminopyrimidin-2-yl)sulfanylpentanehydrazide
    —— (3R)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]butanehydrazide —— C10H12N4O2S2
    (3R)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]butanehydrazide
    —— (2S)-2-methyl-3-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]propanehydrazide —— C11H18N4O2S
    (2S)-2-methyl-3-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]propanehydrazide
    —— (3S)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]butanehydrazide —— C10H12N4O2S2
    (3S)-3-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]butanehydrazide
    —— (2R)-2-methyl-3-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]propanehydrazide —— C11H18N4O2S
    (2R)-2-methyl-3-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]propanehydrazide
    —— (2R)-3-methyl-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]butanehydrazide —— C12H20N4O2S
    (2R)-3-methyl-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]butanehydrazide
    —— (4R)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide —— C10H19N5O2S
    (4R)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide
    —— 3-[(4-fluorophenyl)methyl]-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine —— C20H19FN6OS
    3-[(4-fluorophenyl)methyl]-5-[(1S)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— 3-[(4-fluorophenyl)methyl]-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine —— C20H19FN6OS
    3-[(4-fluorophenyl)methyl]-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— N-(3-chlorophenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C13H14ClN3OS2
    N-(3-chlorophenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2S,5R)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carbohydrazide —— C9H14N4O3S
    (2S,5R)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— 5-Ethylsulfanylthiophen-2-amine —— C6H9NS2
    5-Ethylsulfanylthiophen-2-amine
    —— (2S,5S)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carbohydrazide —— C9H14N4O3S
    (2S,5S)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (4S)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide —— C10H19N5O2S
    (4S)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide
    —— (2S)-N-ethyl-2-[[5-[(2S)-1-(ethylamino)-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C12H20N4O2S3
    (2S)-N-ethyl-2-[[5-[(2S)-1-(ethylamino)-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-3-methylbutanehydrazide —— C13H20N2OS
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-3-methylbutanehydrazide
    —— 1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C17H21N5O2S2
    1-[2,5-Dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-[2-(4-chlorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H19ClN4OS2
    N-[2-(4-chlorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— Methyl 3-[2,5-dimethyl-3-[2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]pyrrol-1-yl]propanoate —— C17H24N4O3S2
    Methyl 3-[2,5-dimethyl-3-[2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]pyrrol-1-yl]propanoate
    —— N-[(1S)-1-(4-bromophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H19BrN4OS2
    N-[(1S)-1-(4-bromophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(Propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone —— C14H20N4OS2
    2-[[5-(Propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— 2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C9H13F3N4OS2
    2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— (2R)-2-(2,4-dimethylphenyl)sulfanyl-3-methylbutanehydrazide —— C13H20N2OS
    (2R)-2-(2,4-dimethylphenyl)sulfanyl-3-methylbutanehydrazide
    —— N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H19ClN4OS2
    N-[(1R)-1-(3-chlorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H19N5OS2
    1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 5-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C14H14BrN5OS2
    5-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— (4S)-4-(3-chloro-4-fluorophenyl)sulfanylpentanehydrazide —— C11H14ClFN2OS
    (4S)-4-(3-chloro-4-fluorophenyl)sulfanylpentanehydrazide
    —— (2S,5R)-5-[(2,5-dimethylphenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C14H20N2O2S
    (2S,5R)-5-[(2,5-dimethylphenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (2R,5S)-5-[(2,5-dimethylphenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C14H20N2O2S
    (2R,5S)-5-[(2,5-dimethylphenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (3R)-3-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)butanehydrazide —— C13H18N2O3S
    (3R)-3-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)butanehydrazide
    —— 1-[2,5-Dimethyl-1-(thiophen-2-ylmethyl)pyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C18H22N4OS3
    1-[2,5-Dimethyl-1-(thiophen-2-ylmethyl)pyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C12H13BrFN3S2
    5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— (4R)-4-(3-chloro-4-fluorophenyl)sulfanylpentanehydrazide —— C11H14ClFN2OS
    (4R)-4-(3-chloro-4-fluorophenyl)sulfanylpentanehydrazide
    —— (2R)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C13H15N5OS3
    (2R)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— 1-[1-(2-Methoxyethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H24N4O2S2
    1-[1-(2-Methoxyethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (4S)-4-[(5-amino-4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide —— C10H20N6OS
    (4S)-4-[(5-amino-4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide
    —— (4R)-4-[(5-amino-4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide —— C10H20N6OS
    (4R)-4-[(5-amino-4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]pentanehydrazide
    —— (2S)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C13H15N5OS3
    (2S)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— (2S,5S)-5-[(2,5-dimethylphenyl)sulfanylmethyl]oxolane-2-carbohydrazide —— C14H20N2O2S
    (2S,5S)-5-[(2,5-dimethylphenyl)sulfanylmethyl]oxolane-2-carbohydrazide
    —— (3R)-3-[5-(trifluoromethyl)pyridin-2-yl]sulfanylbutanehydrazide —— C10H12F3N3OS
    (3R)-3-[5-(trifluoromethyl)pyridin-2-yl]sulfanylbutanehydrazide