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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(2S,6S)-2,6-dimethylcyclohexyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C16H21F3N2OS
    N-[(2S,6S)-2,6-dimethylcyclohexyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R,6S)-2,6-dimethylcyclohexyl]acetamide —— C23H28N4O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R,6S)-2,6-dimethylcyclohexyl]acetamide
    —— (2S)-N,N-diethyl-2-(2-methoxyethylsulfonyl)propanamide —— C10H21NO4S
    (2S)-N,N-diethyl-2-(2-methoxyethylsulfonyl)propanamide
    —— 5-[(2E)-2-(2-fluorobenzylidene)hydrazinyl]-3-(methylsulfanyl)-1,2-thiazole-4-carbonitrile —— C12H9FN4S2
    5-[(2E)-2-(2-fluorobenzylidene)hydrazinyl]-3-(methylsulfanyl)-1,2-thiazole-4-carbonitrile
    —— 2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N'-[(E)-(5-phenylfuran-2-yl)methylidene]acetohydrazide —— C16H14N4O2S2
    2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N'-[(E)-(5-phenylfuran-2-yl)methylidene]acetohydrazide
    —— 5-[(2E)-2-(3-hydroxybenzylidene)hydrazinyl]-3-(methylsulfanyl)-1,2-thiazole-4-carbonitrile —— C12H10N4OS2
    5-[(2E)-2-(3-hydroxybenzylidene)hydrazinyl]-3-(methylsulfanyl)-1,2-thiazole-4-carbonitrile
    —— 2-[(4-chlorophenyl)sulfanyl]-N'-[(2E)-1-phenylbutan-2-ylidene]acetohydrazide —— C18H19ClN2OS
    2-[(4-chlorophenyl)sulfanyl]-N'-[(2E)-1-phenylbutan-2-ylidene]acetohydrazide
    —— 3-methyl-5-[(S)-(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl-phenylmethyl]-1,2,4-oxadiazole —— C16H19N5OS
    3-methyl-5-[(S)-(5-methyl-4-propyl-1,2,4-triazol-3-yl)sulfanyl-phenylmethyl]-1,2,4-oxadiazole
    —— N-[[(1R,6R)-2,6-dimethylcyclohex-2-en-1-yl]methyl]-2-methyl-2-methylsulfonylpropan-1-amine —— C14H27NO2S
    N-[[(1R,6R)-2,6-dimethylcyclohex-2-en-1-yl]methyl]-2-methyl-2-methylsulfonylpropan-1-amine
    —— N-[[(1S,6R)-2,6-dimethylcyclohex-2-en-1-yl]methyl]-2-methyl-2-methylsulfonylpropan-1-amine —— C14H27NO2S
    N-[[(1S,6R)-2,6-dimethylcyclohex-2-en-1-yl]methyl]-2-methyl-2-methylsulfonylpropan-1-amine
    —— N-[[(1R,6S)-2,6-dimethylcyclohex-2-en-1-yl]methyl]-2-methyl-2-methylsulfonylpropan-1-amine —— C14H27NO2S
    N-[[(1R,6S)-2,6-dimethylcyclohex-2-en-1-yl]methyl]-2-methyl-2-methylsulfonylpropan-1-amine
    —— methyl (2S)-2-(2-methylphenyl)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C20H28N4O3S
    methyl (2S)-2-(2-methylphenyl)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— (2R)-1-[(6-methylsulfanylpyrazin-2-yl)amino]-3-piperidin-1-ylpropan-2-ol —— C13H22N4OS
    (2R)-1-[(6-methylsulfanylpyrazin-2-yl)amino]-3-piperidin-1-ylpropan-2-ol
    —— N-[[2-[(1S)-1-methoxyethyl]-1,3-thiazol-4-yl]methyl]-N-methyl-6-methylsulfanylpyrazin-2-amine —— C13H18N4OS2
    N-[[2-[(1S)-1-methoxyethyl]-1,3-thiazol-4-yl]methyl]-N-methyl-6-methylsulfanylpyrazin-2-amine
    —— N-[[2-[(1R)-1-methoxyethyl]-1,3-thiazol-4-yl]methyl]-N-methyl-6-methylsulfanylpyrazin-2-amine —— C13H18N4OS2
    N-[[2-[(1R)-1-methoxyethyl]-1,3-thiazol-4-yl]methyl]-N-methyl-6-methylsulfanylpyrazin-2-amine
    —— methyl (2R)-2-(2-methylphenyl)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C20H28N4O3S
    methyl (2R)-2-(2-methylphenyl)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-methylsulfanyl-6-[(3R)-3-(2-piperidin-1-ylethoxy)pyrrolidin-1-yl]pyrazine —— C16H26N4OS
    2-methylsulfanyl-6-[(3R)-3-(2-piperidin-1-ylethoxy)pyrrolidin-1-yl]pyrazine
    —— (2R,6S)-2,6-dimethyl-4-(6-methylsulfanylpyrazin-2-yl)thiomorpholine —— C11H17N3S2
    (2R,6S)-2,6-dimethyl-4-(6-methylsulfanylpyrazin-2-yl)thiomorpholine
    —— 6-methyl-N-[[(3R)-1-(6-methylsulfanylpyrazin-2-yl)pyrrolidin-3-yl]methyl]pyridin-2-amine —— C16H21N5S
    6-methyl-N-[[(3R)-1-(6-methylsulfanylpyrazin-2-yl)pyrrolidin-3-yl]methyl]pyridin-2-amine
    —— (2R)-2-methyl-2-(1-methylpyrazol-4-yl)-4-(6-methylsulfanylpyrazin-2-yl)morpholine —— C14H19N5OS
    (2R)-2-methyl-2-(1-methylpyrazol-4-yl)-4-(6-methylsulfanylpyrazin-2-yl)morpholine
    —— 6-methyl-N-[[(3S)-1-(6-methylsulfanylpyrazin-2-yl)pyrrolidin-3-yl]methyl]pyridin-2-amine —— C16H21N5S
    6-methyl-N-[[(3S)-1-(6-methylsulfanylpyrazin-2-yl)pyrrolidin-3-yl]methyl]pyridin-2-amine
    —— (2S)-1-[(6-methylsulfanylpyrazin-2-yl)amino]-3-piperidin-1-ylpropan-2-ol —— C13H22N4OS
    (2S)-1-[(6-methylsulfanylpyrazin-2-yl)amino]-3-piperidin-1-ylpropan-2-ol
    —— (2S)-2-methyl-2-(1-methylpyrazol-4-yl)-4-(6-methylsulfanylpyrazin-2-yl)morpholine —— C14H19N5OS
    (2S)-2-methyl-2-(1-methylpyrazol-4-yl)-4-(6-methylsulfanylpyrazin-2-yl)morpholine
    —— (2R,6R)-2,6-dimethyl-4-(6-methylsulfanylpyrazin-2-yl)thiomorpholine —— C11H17N3S2
    (2R,6R)-2,6-dimethyl-4-(6-methylsulfanylpyrazin-2-yl)thiomorpholine
    —— N-[(E)-(4-bromophenyl)methylideneamino]-2-(5-ethyl-4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)acetamide —— C17H19BrN4O2S
    N-[(E)-(4-bromophenyl)methylideneamino]-2-(5-ethyl-4-methyl-2-methylsulfanyl-6-oxopyrimidin-1-yl)acetamide
    —— 3-(4-amino-1,2,5-oxadiazol-3-yl)-5-methyl-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide —— C14H14N8O2S
    3-(4-amino-1,2,5-oxadiazol-3-yl)-5-methyl-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide
    —— (2E)-2-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-N-phenylhydrazinecarbothioamide —— C18H14ClN3OS2
    (2E)-2-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-N-phenylhydrazinecarbothioamide
    —— 1,3-bis[(E)-dodecylideneamino]thiourea —— C25H50N4S
    1,3-bis[(E)-dodecylideneamino]thiourea
    —— N-methyl-N-[(2R)-1-[(R)-methylsulfinyl]propan-2-yl]cyclopentanamine —— C10H21NOS
    N-methyl-N-[(2R)-1-[(R)-methylsulfinyl]propan-2-yl]cyclopentanamine
    —— N-methyl-N-[(2R)-1-[(S)-methylsulfinyl]propan-2-yl]cyclopentanamine —— C10H21NOS
    N-methyl-N-[(2R)-1-[(S)-methylsulfinyl]propan-2-yl]cyclopentanamine
    —— (2R)-N-(cycloheptylmethyl)-N-methyl-1-[(R)-methylsulfinyl]propan-2-amine —— C13H27NOS
    (2R)-N-(cycloheptylmethyl)-N-methyl-1-[(R)-methylsulfinyl]propan-2-amine
    —— (2S)-N-(cycloheptylmethyl)-N-methyl-1-[(S)-methylsulfinyl]propan-2-amine —— C13H27NOS
    (2S)-N-(cycloheptylmethyl)-N-methyl-1-[(S)-methylsulfinyl]propan-2-amine
    —— N-methyl-N-[(2S)-1-[(R)-methylsulfinyl]propan-2-yl]cyclopentanamine —— C10H21NOS
    N-methyl-N-[(2S)-1-[(R)-methylsulfinyl]propan-2-yl]cyclopentanamine
    —— (2R)-N-(cycloheptylmethyl)-N-methyl-1-[(S)-methylsulfinyl]propan-2-amine —— C13H27NOS
    (2R)-N-(cycloheptylmethyl)-N-methyl-1-[(S)-methylsulfinyl]propan-2-amine
    —— N-methyl-N-[(2S)-1-[(S)-methylsulfinyl]propan-2-yl]cyclopentanamine —— C10H21NOS
    N-methyl-N-[(2S)-1-[(S)-methylsulfinyl]propan-2-yl]cyclopentanamine
    —— (2S)-N-(cycloheptylmethyl)-N-methyl-1-[(R)-methylsulfinyl]propan-2-amine —— C13H27NOS
    (2S)-N-(cycloheptylmethyl)-N-methyl-1-[(R)-methylsulfinyl]propan-2-amine
    —— 3-nitro-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide —— C21H12N6O7S2
    3-nitro-N-[(E)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-furan-3-ylmethylidene]-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C18H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-furan-3-ylmethylidene]-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— [(2E)-2-benzylidenehydrazinyl] 2-[2-[[(E)-benzylideneamino]carbamoyloxymethylsulfanyl]-6-methylpyrimidin-4-yl]oxyacetate —— C23H22N6O5S
    [(2E)-2-benzylidenehydrazinyl] 2-[2-[[(E)-benzylideneamino]carbamoyloxymethylsulfanyl]-6-methylpyrimidin-4-yl]oxyacetate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(2-hydroxyphenyl)methylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C16H15N11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(2-hydroxyphenyl)methylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 4-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]phenolate —— C19H15ClN8O3S
    4-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]phenolate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-bromo-2-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C19H15BrN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-bromo-2-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 2-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]phenolate —— C20H18N8O3S
    2-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]phenolate
    —— 2-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]phenolate —— C19H15ClN8O3S
    2-[(E)-(2-{[1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-1H-1,2,3-triazol-4-yl]carbonyl}hydrazinylidene)methyl]phenolate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-chloro-2-hydroxyphenyl)methylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide —— C16H14ClN11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(5-chloro-2-hydroxyphenyl)methylidene]-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(4-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C19H16N8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-[(E)-(4-hydroxyphenyl)methylidene]-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 3-[(E)-N-[[1-(4-azaniumyl-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carbonyl]amino]-C-methylcarbonimidoyl]phenolate —— C17H17N11O3S
    3-[(E)-N-[[1-(4-azaniumyl-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carbonyl]amino]-C-methylcarbonimidoyl]phenolate
    —— (2E)-2-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]-N-(prop-2-en-1-yl)hydrazinecarbothioamide —— C16H15N5O2S2
    (2E)-2-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]-N-(prop-2-en-1-yl)hydrazinecarbothioamide
    —— 4-{(1E)-1-[2-({1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazol-4-yl}carbonyl)hydrazinylidene]ethyl}phenolate —— C20H18N8O3S
    4-{(1E)-1-[2-({1-(4-ammonio-1,2,5-oxadiazol-3-yl)-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazol-4-yl}carbonyl)hydrazinylidene]ethyl}phenolate
    —— N-[2-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-2-methylpropyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C15H26N4OS2
    N-[2-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-2-methylpropyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide