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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C24H31N5O3S
    N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C24H31N5O3S
    N-[[4-(dimethylamino)phenyl]methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— (3S)-3-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyrrolidine-2,5-dione —— C7H9N5O2S
    (3S)-3-[(5-amino-4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyrrolidine-2,5-dione
    —— 1-(Azepan-1-yl)-2-[[5-(2-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C18H24N4OS2
    1-(Azepan-1-yl)-2-[[5-(2-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 3-(3,4-dimethylphenyl)sulfanylpropanoate —— C21H28N2O3S
    [(2R)-1-[(1-cyanocyclohexyl)amino]-1-oxopropan-2-yl] 3-(3,4-dimethylphenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 3-(3,4-dimethylphenyl)sulfanylpropanoate —— C21H25NO3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 3-(3,4-dimethylphenyl)sulfanylpropanoate
    —— 1-[(3S)-3,5-bis(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C22H19N5O3S2
    1-[(3S)-3,5-bis(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N-[(Z)-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C19H20N4OS2
    N-[(Z)-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— ethyl 5-[[2-[3-(4-fluorophenyl)sulfanylpropanoyl]hydrazinyl]methylidene]-2,4-dimethylpyrrole-3-carboxylate —— C19H22FN3O3S
    ethyl 5-[[2-[3-(4-fluorophenyl)sulfanylpropanoyl]hydrazinyl]methylidene]-2,4-dimethylpyrrole-3-carboxylate
    —— ethyl 5-[[2-[2-(2-fluorophenyl)sulfanylacetyl]hydrazinyl]methylidene]-2,4-dimethylpyrrole-3-carboxylate —— C18H20FN3O3S
    ethyl 5-[[2-[2-(2-fluorophenyl)sulfanylacetyl]hydrazinyl]methylidene]-2,4-dimethylpyrrole-3-carboxylate
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(1-propylpiperidin-4-yl)acetamide —— C18H27N5O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-(1-propylpiperidin-4-yl)acetamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-(1-propylpiperidin-4-yl)propanamide —— C18H30N4OS
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-(1-propylpiperidin-4-yl)propanamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C17H22FNO4S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 1-(5-chlorothiophen-2-yl)-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C13H14ClN3O2S3
    1-(5-chlorothiophen-2-yl)-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 2-[2-[(3R)-3-(furan-2-yl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanylpyridine-3-carbonitrile —— C19H14N4O2S2
    2-[2-[(3R)-3-(furan-2-yl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanylpyridine-3-carbonitrile
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C17H22FNO4S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C17H22FNO4S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 4-[[5,6-Dimethyl-4-(1-propan-2-yltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C17H24N7OS2+
    4-[[5,6-Dimethyl-4-(1-propan-2-yltetrazol-5-yl)sulfanylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 2-[2-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanylpyridine-3-carbonitrile —— C19H14N4OS3
    2-[2-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanylpyridine-3-carbonitrile
    —— 1-methyl-N-[2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]pyrrole-2-carboxamide —— C15H19N5O3S2
    1-methyl-N-[2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]pyrrole-2-carboxamide
    —— N-[[(2R)-oxolan-2-yl]methyl]-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H18N4O2S2
    N-[[(2R)-oxolan-2-yl]methyl]-5-[(5-phenyl-1,2-oxazol-3-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(1-ethyltetrazol-5-yl)sulfanyl-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide —— C16H17N5OS2
    2-(1-ethyltetrazol-5-yl)sulfanyl-N-[(R)-phenyl(thiophen-2-yl)methyl]acetamide
    —— 7-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-2-ethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C13H14N6OS3
    7-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-2-ethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— N-benzyl-N-(2-methoxyethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C14H18N4O2S
    N-benzyl-N-(2-methoxyethyl)-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[2-(3-chlorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13ClN4OS
    N-[2-(3-chlorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-N-methyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C16H15ClN4O2S
    N-[[5-(4-chlorophenyl)furan-2-yl]methyl]-N-methyl-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-[(4-Bromophenyl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole —— C16H13BrN2OS
    2-[(4-Bromophenyl)sulfanylmethyl]-5-(3-methylphenyl)-1,3,4-oxadiazole
    —— N-[2-(2-methylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H16N4OS
    N-[2-(2-methylphenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-(2-cyanoethyl)-N-(furan-2-ylmethyl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C15H15N3O3S
    N-(2-cyanoethyl)-N-(furan-2-ylmethyl)-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C20H24N2O4S
    N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C21H27N3O3S
    N-[[4-(dimethylamino)phenyl]methyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— N-[2-(2-fluorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C12H13FN4OS
    N-[2-(2-fluorophenyl)ethyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C17H22N4O3S
    N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C18H28N2O2S
    N-[4-(2-methylbutan-2-yl)cyclohexyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— N-[(R)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C18H15FN2O2S2
    N-[(R)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 2-(3-Methylphenyl)-5-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C15H13N3O2S
    2-(3-Methylphenyl)-5-[(1-oxidopyridin-1-ium-2-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— (Z)-3-amino-2-[2-[1-(furan-2-ylmethyl)tetrazol-5-yl]sulfanylacetyl]but-2-enenitrile —— C12H12N6O2S
    (Z)-3-amino-2-[2-[1-(furan-2-ylmethyl)tetrazol-5-yl]sulfanylacetyl]but-2-enenitrile
    —— 1-Ethyl-3-(2-phenylsulfanylethyl)thiourea —— C11H16N2S2
    1-Ethyl-3-(2-phenylsulfanylethyl)thiourea
    —— 3-[2-(4-chlorophenyl)sulfanylethyl]-1-(dimethylamino)-1-[(3S)-1,1-dioxothiolan-3-yl]thiourea —— C15H22ClN3O2S3
    3-[2-(4-chlorophenyl)sulfanylethyl]-1-(dimethylamino)-1-[(3S)-1,1-dioxothiolan-3-yl]thiourea
    —— 1-[(1R,2S)-2-methylcyclohexyl]-3-(2-phenylsulfanylethyl)thiourea —— C16H24N2S2
    1-[(1R,2S)-2-methylcyclohexyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 1-[[(2S)-oxolan-2-yl]methyl]-3-(2-phenylsulfanylethyl)thiourea —— C14H20N2OS2
    1-[[(2S)-oxolan-2-yl]methyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 1-Cyclohexyl-3-(2-phenylsulfanylethyl)thiourea —— C15H22N2S2
    1-Cyclohexyl-3-(2-phenylsulfanylethyl)thiourea
    —— 1-Cyclohexyl-3-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]thiourea —— C17H31N5S2
    1-Cyclohexyl-3-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]thiourea
    —— 1-Methyl-3-[4-(2-methylbutan-2-yl)cyclohexyl]thiourea —— C13H26N2S
    1-Methyl-3-[4-(2-methylbutan-2-yl)cyclohexyl]thiourea
    —— 10-[(4-Methylpiperidin-1-ium-1-yl)methyl]-12-(1-methyltetrazol-5-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene —— C18H24N7S2+
    10-[(4-Methylpiperidin-1-ium-1-yl)methyl]-12-(1-methyltetrazol-5-yl)sulfanyl-7-thia-9,11-diazatricyclo[6.4.0.02,6]dodeca-1(8),2(6),9,11-tetraene
    —— 4-[[(7S)-7-methyl-4-(1-methyltetrazol-5-yl)sulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C18H24N7OS2+
    4-[[(7S)-7-methyl-4-(1-methyltetrazol-5-yl)sulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 5-(4-Bromophenyl)sulfanyl-4-chloro-2-phenylpyridazin-3-one —— C16H10BrClN2OS
    5-(4-Bromophenyl)sulfanyl-4-chloro-2-phenylpyridazin-3-one
    —— 1-Methyl-1-(4-methylcyclohexyl)-3-(2-phenylsulfanylethyl)thiourea —— C17H26N2S2
    1-Methyl-1-(4-methylcyclohexyl)-3-(2-phenylsulfanylethyl)thiourea
    —— 3-[2-(4-Chlorophenyl)sulfanylethyl]-1-prop-2-enyl-1-(thiophen-2-ylmethyl)thiourea —— C17H19ClN2S3
    3-[2-(4-Chlorophenyl)sulfanylethyl]-1-prop-2-enyl-1-(thiophen-2-ylmethyl)thiourea
    —— 6,7-Dimethoxy-4-(1-methylimidazol-2-yl)sulfanyl-2-phenylquinazoline —— C20H18N4O2S
    6,7-Dimethoxy-4-(1-methylimidazol-2-yl)sulfanyl-2-phenylquinazoline