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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C19H23N3O4S
    [(2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 2-(2-Methylfuran-3-yl)-5-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole —— C15H11N3O2S3
    2-(2-Methylfuran-3-yl)-5-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C18H19N3O4S
    (2R)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— [(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C19H23N3O4S
    [(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— 1-(5-Chloro-2-phenylsulfanylphenyl)-3-cyclopropylthiourea —— C16H15ClN2S2
    1-(5-Chloro-2-phenylsulfanylphenyl)-3-cyclopropylthiourea
    —— 1-(5-chloro-2-phenylsulfanylphenyl)-3-[[(2R)-oxolan-2-yl]methyl]thiourea —— C18H19ClN2OS2
    1-(5-chloro-2-phenylsulfanylphenyl)-3-[[(2R)-oxolan-2-yl]methyl]thiourea
    —— 3-[2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetyl]-1,3-oxazolidin-2-one —— C12H16N4O3S
    3-[2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)acetyl]-1,3-oxazolidin-2-one
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C19H18ClN3O3S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— (2E)-5-nitro-2-(5-nitro-3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one —— C16H6N2O6S2
    (2E)-5-nitro-2-(5-nitro-3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one
    —— [(2R)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C20H22N2O3S
    [(2R)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— N-(1-Adamantylmethyl)-N'-allylthiourea —— C15H24N2S
    N-(1-Adamantylmethyl)-N'-allylthiourea
    —— N-benzyl-5-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H14N4S4
    N-benzyl-5-[(2-thiophen-3-yl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H17ClN2O3S
    [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-(tert-butylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C19H21ClN2O3S
    [(2R)-1-(tert-butylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C19H21ClN2O3S
    [(2R)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2R)-1-(methoxycarbonylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate —— C19H20N2O5S
    [(2R)-1-(methoxycarbonylamino)-1-oxopropan-2-yl] 2-(3,4-dimethylphenyl)sulfanylpyridine-3-carboxylate
    —— [(2S)-1-oxo-1-(propylamino)propan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate —— C18H19ClN2O3S
    [(2S)-1-oxo-1-(propylamino)propan-2-yl] 2-(2-chlorophenyl)sulfanylpyridine-3-carboxylate
    —— [(2S)-1-(2,6-dimethylanilino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate —— C24H24N2O3S
    [(2S)-1-(2,6-dimethylanilino)-1-oxopropan-2-yl] 2-(4-methylphenyl)sulfanylpyridine-3-carboxylate
    —— [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 1-methylpyrrole-2-carboxylate —— C21H20N2O3S
    [(2S)-1-oxo-1-(2-phenylsulfanylanilino)propan-2-yl] 1-methylpyrrole-2-carboxylate
    —— (1S)-1-[2-[(1S,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[2-[(1S,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— (1S)-1-[2-[(1S,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[2-[(1S,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— (1S)-1-[4-[(1S,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[4-[(1S,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— (1S)-1-[4-[(1R,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[4-[(1R,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— (2R)-N-[(4-methylphenyl)methyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C16H20N4OS
    (2R)-N-[(4-methylphenyl)methyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (1S)-1-[4-[(1S,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[4-[(1S,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— (2S)-N-[(2-chlorophenyl)methyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H17ClN4OS
    (2S)-N-[(2-chlorophenyl)methyl]-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (1S)-1-[2-[(1R,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[2-[(1R,3S)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— N-[(1R,2S,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H25N3OS3
    N-[(1R,2S,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H25N3OS3
    N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(1S,2S,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H25N3OS3
    N-[(1S,2S,3R)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (1S)-1-[4-[(1R,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H23NS
    (1S)-1-[4-[(1R,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H25N3OS3
    N-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-2-[[5-(2-methylprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— methyl N-[(2R)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C13H12BrN3O4S
    methyl N-[(2R)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— (2S)-N-(cyclopentylcarbamoyl)-2-(3,4-dimethylphenyl)sulfanylpropanamide —— C17H24N2O2S
    (2S)-N-(cyclopentylcarbamoyl)-2-(3,4-dimethylphenyl)sulfanylpropanamide
    —— [(2S)-1-oxo-1-(propylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate —— C14H18BrNO3S
    [(2S)-1-oxo-1-(propylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate
    —— (2R)-N-benzyl-N-tert-butyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C21H29N3OS
    (2R)-N-benzyl-N-tert-butyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2S)-N-benzyl-N-tert-butyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C21H29N3OS
    (2S)-N-benzyl-N-tert-butyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2R)-2-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide —— C15H21NO3S2
    (2R)-2-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]propanamide
    —— (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide —— C14H16BrN3O3S
    (2S)-2-[[5-(2-bromophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide
    —— [(2R)-1-oxo-1-(propylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate —— C14H18BrNO3S
    [(2R)-1-oxo-1-(propylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate
    —— (2R)-2-(3,4-dimethylphenyl)sulfanyl-N-(2-phenylethyl)propanamide —— C19H23NOS
    (2R)-2-(3,4-dimethylphenyl)sulfanyl-N-(2-phenylethyl)propanamide
    —— (2S)-N-(propan-2-ylcarbamoyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C14H22N4O2S
    (2S)-N-(propan-2-ylcarbamoyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate —— C16H16BrNO3S2
    [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate
    —— [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate —— C14H16BrNO3S
    [(2S)-1-oxo-1-(prop-2-enylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C14H21N3O3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[(4-fluorophenyl)methyl]propanamide —— C18H20FNOS
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[(4-fluorophenyl)methyl]propanamide
    —— [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate —— C16H16BrNO3S2
    [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(4-bromophenyl)sulfanylacetate
    —— (2S)-N-(2-phenylethyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C18H23N3OS
    (2S)-N-(2-phenylethyl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide
    —— 2-(2-Fluorophenyl)sulfanylethyl 3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate —— C16H22FNO4S
    2-(2-Fluorophenyl)sulfanylethyl 3-[(2-methylpropan-2-yl)oxycarbonylamino]propanoate
    —— (2S)-N-prop-2-enyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide —— C13H19N3OS
    (2S)-N-prop-2-enyl-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropanamide