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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[2-(3-chloro-benzylsulfanyl)-phenyl]-1,4,5,6-tetrahydro-pyrimidine —— C17H17ClN2S
    2-[2-(3-chloro-benzylsulfanyl)-phenyl]-1,4,5,6-tetrahydro-pyrimidine
    —— tert-butyl 2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H23N3O3S2
    tert-butyl 2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 3-ethylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazole —— C13H17N3OS2
    3-ethylsulfanyl-4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazole
    —— tert-butyl 2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetate —— C17H23N3O3S2
    tert-butyl 2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 3-[(3,5-dimethylphenyl)methylsulfanyl]-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine —— C18H20N4S
    3-[(3,5-dimethylphenyl)methylsulfanyl]-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine
    —— 2-methyl-6-[(E)-4-(4-methylpyrimidin-2-yl)sulfanylbut-2-enyl]sulfanylpyrazine —— C14H16N4S2
    2-methyl-6-[(E)-4-(4-methylpyrimidin-2-yl)sulfanylbut-2-enyl]sulfanylpyrazine
    —— 3-(3-(5-Cyanopentylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine —— C14H20N4S2
    3-(3-(5-Cyanopentylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine
    —— 3-(3,3-dimethoxypropylsulfanyl)-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine —— C14H20N4O2S
    3-(3,3-dimethoxypropylsulfanyl)-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine
    —— 4-[2-[2-(1H-pyrrol-3-ylsulfanyl)ethoxy]ethylsulfanyl]phenol —— C14H17NO2S2
    4-[2-[2-(1H-pyrrol-3-ylsulfanyl)ethoxy]ethylsulfanyl]phenol
    —— [5-(benzylthio)-1H-[1,2,4]triazol-3-yl]-pyridin-3-yl-amine 334539-94-5 C14H13N5S
    [5-(benzylthio)-1H-[1,2,4]triazol-3-yl]-pyridin-3-yl-amine
    —— 3-[(Z)-2-methylbut-2-enyl]sulfanyl-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine —— C14H18N4S
    3-[(Z)-2-methylbut-2-enyl]sulfanyl-N-(4-methylphenyl)-1H-1,2,4-triazol-5-amine
    —— 1-Carboxymethyl-5-[(5-nitrothiazol-2-yl)mercapto]tetrazole —— C6H4N6O4S2
    1-Carboxymethyl-5-[(5-nitrothiazol-2-yl)mercapto]tetrazole
    —— 3-[(3S)-1-azabicyclo[2.2.1]heptan-3-yl]-4-butylsulfanyl-1,2,5-thiadiazole —— C12H19N3S2
    3-[(3S)-1-azabicyclo[2.2.1]heptan-3-yl]-4-butylsulfanyl-1,2,5-thiadiazole
    —— endo-6-(3-propylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane —— C12H19N3S2
    endo-6-(3-propylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane
    —— Dithionane-3-carboxylic acid —— C8H14O2S2
    Dithionane-3-carboxylic acid
    —— 3-anilino-5-allyllthio-1,2,4-triazole 334538-52-2 C11H12N4S
    3-anilino-5-allyllthio-1,2,4-triazole
    —— 3-methoxy-4,5-dimethyl-6-allylthiopyridazine —— C10H14N2OS
    3-methoxy-4,5-dimethyl-6-allylthiopyridazine
    —— (1R,9S)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine —— C9H12N4S
    (1R,9S)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine
    —— (1S,9R)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine —— C9H12N4S
    (1S,9R)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine
    —— (1S,9S)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine —— C9H12N4S
    (1S,9S)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine
    —— (1R,9R)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine —— C9H12N4S
    (1R,9R)-8-thia-4,6,11-triazatricyclo[7.4.0.02,7]trideca-2,4,6-trien-3-amine
    —— (2R)-N-(5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-ylmethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide —— C17H20N4OS
    (2R)-N-(5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-ylmethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2S)-N-(5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-ylmethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide —— C17H20N4OS
    (2S)-N-(5,6,7,8-tetrahydro-4H-pyrazolo[1,5-a][1,4]diazepin-2-ylmethyl)-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— (2E)-2-[[5-(4-bromophenyl)sulfanylfuran-2-yl]methylidene]-[1,3]thiazolo[3,2-a]benzimidazol-1-one —— C20H11BrN2O2S2
    (2E)-2-[[5-(4-bromophenyl)sulfanylfuran-2-yl]methylidene]-[1,3]thiazolo[3,2-a]benzimidazol-1-one
    —— (5Z)-5-[[5-(4-bromophenyl)sulfanylfuran-2-yl]methylidene]-2-piperidin-1-yl-1,3-thiazol-4-one —— C19H17BrN2O2S2
    (5Z)-5-[[5-(4-bromophenyl)sulfanylfuran-2-yl]methylidene]-2-piperidin-1-yl-1,3-thiazol-4-one
    —— (Z)-3-[5-(4-bromophenyl)sulfanylfuran-2-yl]-2-(4-oxo-1H-quinazolin-2-yl)prop-2-enenitrile —— C21H12BrN3O2S
    (Z)-3-[5-(4-bromophenyl)sulfanylfuran-2-yl]-2-(4-oxo-1H-quinazolin-2-yl)prop-2-enenitrile
    —— (Z)-2-(1,3-benzothiazol-2-yl)-3-[5-(4-bromophenyl)sulfanylfuran-2-yl]prop-2-enenitrile —— C20H11BrN2OS2
    (Z)-2-(1,3-benzothiazol-2-yl)-3-[5-(4-bromophenyl)sulfanylfuran-2-yl]prop-2-enenitrile
    —— pyridin-3-ylmethyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C12H14N4O2S
    pyridin-3-ylmethyl (2R)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— pyridin-3-ylmethyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate —— C12H14N4O2S
    pyridin-3-ylmethyl (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanoate
    —— (2R)-N-[(2-benzylsulfanylpyrimidin-5-yl)methyl]-N-methyl-1-pyrazin-2-ylpropan-2-amine —— C20H23N5S
    (2R)-N-[(2-benzylsulfanylpyrimidin-5-yl)methyl]-N-methyl-1-pyrazin-2-ylpropan-2-amine
    —— methyl (Z)-4-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]but-2-enoate —— C9H11N3O3S
    methyl (Z)-4-[(6-methyl-5-oxo-4H-1,2,4-triazin-3-yl)sulfanyl]but-2-enoate
    —— (2S)-N-[(2-benzylsulfanylpyrimidin-5-yl)methyl]-N-methyl-1-pyrazin-2-ylpropan-2-amine —— C20H23N5S
    (2S)-N-[(2-benzylsulfanylpyrimidin-5-yl)methyl]-N-methyl-1-pyrazin-2-ylpropan-2-amine
    —— (2S)-N-methyl-N-[3-(4-methylphenyl)sulfanylpropyl]spiro[2.2]pentane-2-carboxamide —— C17H23NOS
    (2S)-N-methyl-N-[3-(4-methylphenyl)sulfanylpropyl]spiro[2.2]pentane-2-carboxamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-methylsulfonylpropanamide —— C11H18N2O3S
    (2R)-N-(1-cyanocyclohexyl)-2-methylsulfonylpropanamide
    —— (2S)-N-(1-cyanocyclohexyl)-2-methylsulfonylpropanamide —— C11H18N2O3S
    (2S)-N-(1-cyanocyclohexyl)-2-methylsulfonylpropanamide
    —— N-[(R)-cyclopentyl-(4-fluorophenyl)methyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C22H22FN3O2S
    N-[(R)-cyclopentyl-(4-fluorophenyl)methyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(S)-cyclopentyl-(4-fluorophenyl)methyl]acetamide —— C22H21ClFN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(S)-cyclopentyl-(4-fluorophenyl)methyl]acetamide
    —— N-cyclopropyl-N-[(2R)-3-methylbutan-2-yl]-3-(2-methylpropylsulfonyl)propanamide —— C15H29NO3S
    N-cyclopropyl-N-[(2R)-3-methylbutan-2-yl]-3-(2-methylpropylsulfonyl)propanamide
    —— N-cyclopropyl-N-[(2S)-3-methylbutan-2-yl]-3-(2-methylpropylsulfonyl)propanamide —— C15H29NO3S
    N-cyclopropyl-N-[(2S)-3-methylbutan-2-yl]-3-(2-methylpropylsulfonyl)propanamide
    —— N-[(2R)-butan-2-yl]-N-methyl-3-(2-methylpropylsulfonyl)propanamide —— C12H25NO3S
    N-[(2R)-butan-2-yl]-N-methyl-3-(2-methylpropylsulfonyl)propanamide
    —— N-[(2S)-butan-2-yl]-N-methyl-3-(2-methylpropylsulfonyl)propanamide —— C12H25NO3S
    N-[(2S)-butan-2-yl]-N-methyl-3-(2-methylpropylsulfonyl)propanamide
    —— 2-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole —— C15H12FN3OS
    2-[(1R)-1-(2-fluorophenyl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole
    —— 2-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole —— C15H12FN3OS
    2-[(1S)-1-(2-fluorophenyl)ethyl]sulfanyl-5-pyridin-4-yl-1,3,4-oxadiazole
    —— [(1S,3R)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate —— C14H26O4S
    [(1S,3R)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate
    —— 5-[[(3S)-3-(3,5-dimethylpyrazol-1-yl)pyrrolidin-1-yl]methyl]-2-ethylsulfanylpyrimidine —— C16H23N5S
    5-[[(3S)-3-(3,5-dimethylpyrazol-1-yl)pyrrolidin-1-yl]methyl]-2-ethylsulfanylpyrimidine
    —— [(1R,3S)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate —— C14H26O4S
    [(1R,3S)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate
    —— [(1R,3R)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate —— C14H26O4S
    [(1R,3R)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate
    —— [(1S,3S)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate —— C14H26O4S
    [(1S,3S)-3-methylcyclohexyl] 3-(2-methylpropylsulfonyl)propanoate
    —— 5-[[(3R)-3-(3,5-dimethylpyrazol-1-yl)pyrrolidin-1-yl]methyl]-2-ethylsulfanylpyrimidine —— C16H23N5S
    5-[[(3R)-3-(3,5-dimethylpyrazol-1-yl)pyrrolidin-1-yl]methyl]-2-ethylsulfanylpyrimidine
    —— 2-[(Z)-2-(4-fluorophenyl)ethenyl]-3-phenylsulfanylquinoxaline —— C22H15FN2S
    2-[(Z)-2-(4-fluorophenyl)ethenyl]-3-phenylsulfanylquinoxaline