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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(1-cyanocyclohexyl)propanamide —— C19H23N5OS2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(1-cyanocyclohexyl)propanamide
    —— 1-(4-Acetylpiperazin-1-yl)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C17H21N5O2S2
    1-(4-Acetylpiperazin-1-yl)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— N'-[3-(3,4-difluorophenyl)sulfanylpropanoyl]cyclohexanecarbohydrazide —— C16H20F2N2O2S
    N'-[3-(3,4-difluorophenyl)sulfanylpropanoyl]cyclohexanecarbohydrazide
    —— (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one —— C18H25N5OS2
    (2S)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— N-cyclopropyl-5-(6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-amine —— C17H13N5S3
    N-cyclopropyl-5-(6-phenylthieno[2,3-d]pyrimidin-4-yl)sulfanyl-1,3,4-thiadiazol-2-amine
    —— (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]propanamide —— C18H23N5OS2
    (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]propanamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C17H18N4OS3
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)-N-methylacetamide —— C17H18N4O2S2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(furan-2-ylmethyl)-N-methylacetamide
    —— (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one —— C18H25N5OS2
    (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C21H24N4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— N-benzyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C13H13N5OS2
    N-benzyl-5-[(5-methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-benzyl-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H14N4OS3
    N-benzyl-5-[(2-thiophen-2-yl-1,3-oxazol-4-yl)methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]-N-methylacetamide —— C19H19ClN4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(4-chlorophenyl)methyl]-N-methylacetamide
    —— N-benzyl-5-[[2-(4-fluorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C19H15FN4S3
    N-benzyl-5-[[2-(4-fluorophenyl)-1,3-thiazol-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N-benzyl-5-(2-chloroprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-amine —— C12H12ClN3S2
    N-benzyl-5-(2-chloroprop-2-enylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide —— C21H24N4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide
    —— [(3R,5R)-5-methyl-2-oxooxolan-3-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C15H17BrO4S
    [(3R,5R)-5-methyl-2-oxooxolan-3-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— (Z)-3-amino-2-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]but-2-enenitrile —— C10H11N3OS2
    (Z)-3-amino-2-[2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetyl]but-2-enenitrile
    —— (Z)-3-amino-2-[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]but-2-enenitrile —— C8H8N4OS2
    (Z)-3-amino-2-[2-(1,3,4-thiadiazol-2-ylsulfanyl)acetyl]but-2-enenitrile
    —— [(3S,5R)-5-methyl-2-oxooxolan-3-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C15H17BrO4S
    [(3S,5R)-5-methyl-2-oxooxolan-3-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— [(3S,5S)-5-methyl-2-oxooxolan-3-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate —— C15H17BrO4S
    [(3S,5S)-5-methyl-2-oxooxolan-3-yl] 2-(4-bromo-2,5-dimethylphenyl)sulfanylacetate
    —— 2-ethylsulfanyl-4-[(Z)-hydroxyiminomethyl]-1H-pyrimidin-6-one —— C7H9N3O2S
    2-ethylsulfanyl-4-[(Z)-hydroxyiminomethyl]-1H-pyrimidin-6-one
    —— 2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-chlorophenyl)ethyl]acetamide —— C16H20ClN3OS3
    2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-(4-chlorophenyl)ethyl]acetamide
    —— N,N-diethyl-4-[5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazol-2-yl]aniline —— C22H23N5O2S
    N,N-diethyl-4-[5-[(1S)-1-(5-phenyl-1,3,4-oxadiazol-2-yl)ethyl]sulfanyl-1,3,4-oxadiazol-2-yl]aniline
    —— (2R)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C17H22FN3OS3
    (2R)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— 2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclohexyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C18H29N3O3S4
    2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclohexyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— (2S)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C17H22FN3OS3
    (2S)-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2R)-N-benzyl-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-ethylpropanamide —— C18H25N3OS3
    (2R)-N-benzyl-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-ethylpropanamide
    —— 2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclohexyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C18H29N3O3S4
    2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-cyclohexyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— (2S)-N-benzyl-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-ethylpropanamide —— C18H25N3OS3
    (2S)-N-benzyl-2-[(5-butylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-ethylpropanamide
    —— (2S,5R)-5-methyl-2-phenylsulfanyloxolan-3-one —— C11H12O2S
    (2S,5R)-5-methyl-2-phenylsulfanyloxolan-3-one
    —— (5R)-4,4-dimethyl-5-(phenylsulfanylmethyl)oxolan-2-one —— C13H16O2S
    (5R)-4,4-dimethyl-5-(phenylsulfanylmethyl)oxolan-2-one
    —— (2S,5S)-5-methyl-2-phenylsulfanyloxolan-3-one —— C11H12O2S
    (2S,5S)-5-methyl-2-phenylsulfanyloxolan-3-one
    —— (2R,5R)-5-methyl-2-phenylsulfanyloxolan-3-one —— C11H12O2S
    (2R,5R)-5-methyl-2-phenylsulfanyloxolan-3-one
    —— (5S)-4,4-dimethyl-5-(phenylsulfanylmethyl)oxolan-2-one —— C13H16O2S
    (5S)-4,4-dimethyl-5-(phenylsulfanylmethyl)oxolan-2-one
    —— (2R,5S)-5-methyl-2-phenylsulfanyloxolan-3-one —— C11H12O2S
    (2R,5S)-5-methyl-2-phenylsulfanyloxolan-3-one
    —— (2R,3S,4S,5R)-4-methyl-5-pentyl-3-(phenylsulfanylmethyl)oxolan-2-ol —— C17H26O2S
    (2R,3S,4S,5R)-4-methyl-5-pentyl-3-(phenylsulfanylmethyl)oxolan-2-ol
    —— (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]propanamide —— C20H22N4OS2
    (2R)-2-[(4-cyclopropyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-phenylethyl]propanamide
    —— (2S)-2-[(R)-nitro(phenylsulfanyl)methyl]oxolane —— C11H13NO3S
    (2S)-2-[(R)-nitro(phenylsulfanyl)methyl]oxolane
    —— 2-(4-bromophenyl)-5-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,3,4-oxadiazole —— C16H16BrN5OS
    2-(4-bromophenyl)-5-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— (2R)-2-[(R)-nitro(phenylsulfanyl)methyl]oxolane —— C11H13NO3S
    (2R)-2-[(R)-nitro(phenylsulfanyl)methyl]oxolane
    —— (2R)-2-[(S)-nitro(phenylsulfanyl)methyl]oxolane —— C11H13NO3S
    (2R)-2-[(S)-nitro(phenylsulfanyl)methyl]oxolane
    —— (2S)-2-[(S)-nitro(phenylsulfanyl)methyl]oxolane —— C11H13NO3S
    (2S)-2-[(S)-nitro(phenylsulfanyl)methyl]oxolane
    —— 4-Amino-2-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]pyrimidine-5-carbonitrile —— C13H9N5O2S
    4-Amino-2-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]pyrimidine-5-carbonitrile
    —— (2R,3S,4S,5S)-4-methyl-5-pentyl-3-(phenylsulfanylmethyl)oxolan-2-ol —— C17H26O2S
    (2R,3S,4S,5S)-4-methyl-5-pentyl-3-(phenylsulfanylmethyl)oxolan-2-ol
    —— 2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C17H20N6O2S
    2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— (Z)-3-amino-2-[2-[6-(3,5-dimethylpyrazol-1-yl)pyridazin-3-yl]sulfanylacetyl]but-2-enenitrile —— C15H16N6OS
    (Z)-3-amino-2-[2-[6-(3,5-dimethylpyrazol-1-yl)pyridazin-3-yl]sulfanylacetyl]but-2-enenitrile
    —— (3S,5R)-3-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C13H15N3O2S2
    (3S,5R)-3-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— 2-(1-ethyltetrazol-5-yl)sulfanyl-1-[4-[(1S)-1-phenylethyl]piperazin-1-yl]ethanone —— C17H24N6OS
    2-(1-ethyltetrazol-5-yl)sulfanyl-1-[4-[(1S)-1-phenylethyl]piperazin-1-yl]ethanone
    —— 1-[(3R)-3-(furan-2-yl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H15N5O2S3
    1-[(3R)-3-(furan-2-yl)-5-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone