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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(4-Chloro-phenylsulfanyl)-4-pyridin-4-ylmethyl-phthalazine —— C20H14ClN3S
    1-(4-Chloro-phenylsulfanyl)-4-pyridin-4-ylmethyl-phthalazine
    —— (18R,19R)-hexatriacontane-1,18,19,36-tetrathiol —— C36H74S4
    (18R,19R)-hexatriacontane-1,18,19,36-tetrathiol
    —— 3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-(prop-2-en-1-yl)-5H-[1,2,4]triazino[5,6-b]indole —— C18H11N7O2S2
    3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-(prop-2-en-1-yl)-5H-[1,2,4]triazino[5,6-b]indole
    —— (10S,11S)-icosane-10,11-dithiol —— C20H42S2
    (10S,11S)-icosane-10,11-dithiol
    —— 3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-propyl-5H-[1,2,4]triazino[5,6-b]indole —— C18H13N7O2S2
    3-[(7-nitro-2,1,3-benzothiadiazol-5-yl)sulfanyl]-5-propyl-5H-[1,2,4]triazino[5,6-b]indole
    —— (10R,11R)-icosane-10,11-dithiol —— C20H42S2
    (10R,11R)-icosane-10,11-dithiol
    —— (9S,10S)-octadecane-9,10-dithiol —— C18H38S2
    (9S,10S)-octadecane-9,10-dithiol
    —— (18S,19S)-hexatriacontane-1,18,19,36-tetrathiol —— C36H74S4
    (18S,19S)-hexatriacontane-1,18,19,36-tetrathiol
    —— (9S,10R)-octadecane-9,10-dithiol —— C18H38S2
    (9S,10R)-octadecane-9,10-dithiol
    —— (9R,10R)-octadecane-9,10-dithiol —— C18H38S2
    (9R,10R)-octadecane-9,10-dithiol
    —— (3S)-2-imino-4-oxothiolane-3-carboxylic acid —— C5H5NO3S
    (3S)-2-imino-4-oxothiolane-3-carboxylic acid
    —— (3S,6S)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-1-carboxamide —— C17H28N2OS
    (3S,6S)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-1-carboxamide
    —— (3R,5R)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide —— C16H26N2OS
    (3R,5R)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide
    —— (3S,5S)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide —— C16H26N2OS
    (3S,5S)-N-(dimethylcarbamothioyl)-3,5-dimethyladamantane-1-carboxamide
    —— (1R,8R)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-3-carboxamide —— C17H28N2OS
    (1R,8R)-N-(tert-butylcarbamothioyl)tricyclo[4.3.1.13,8]undecane-3-carboxamide
    —— (5R,7R)-3-chloro-N-methyladamantane-1-carbothioamide —— C12H18ClNS
    (5R,7R)-3-chloro-N-methyladamantane-1-carbothioamide
    —— [(2S)-3,3,4,4,4-pentafluoro-2-[(2S)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene —— C20H16F10S
    [(2S)-3,3,4,4,4-pentafluoro-2-[(2S)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(1Z)-1-(pyridin-4-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C20H19N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methylphenyl)sulfanyl]methyl}-N'-[(1Z)-1-(pyridin-4-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— [(2R)-3,3,4,4,4-pentafluoro-2-[(2R)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene —— C20H16F10S
    [(2R)-3,3,4,4,4-pentafluoro-2-[(2R)-3,3,4,4,4-pentafluoro-1-phenylbutan-2-yl]sulfanylbutyl]benzene
    —— 4-(4-Methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanylbutan-2-one —— C13H19N3O2S
    4-(4-Methyl-6-morpholin-4-ylpyrimidin-2-yl)sulfanylbutan-2-one
    —— (1R)-1-methyl-1-oxo-1lambda6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid —— C6H7NO3S
    (1R)-1-methyl-1-oxo-1lambda6-thia-2-azacyclohexa-1,3,5-triene-4-carboxylic acid
    —— 6-[[6-[(3-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine —— C29H20N8O2S2
    6-[[6-[(3-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine
    —— ethyl (2Z)-2-(cyclohex-3-en-1-ylmethylidene)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H26N2O3S2
    ethyl (2Z)-2-(cyclohex-3-en-1-ylmethylidene)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (3R,6R)-N-cyclohexyltricyclo[4.3.1.13,8]undecane-1-carbothioamide —— C18H29NS
    (3R,6R)-N-cyclohexyltricyclo[4.3.1.13,8]undecane-1-carbothioamide
    —— N-(3-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C27H18N6O5S3
    N-(3-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— 6-[[6-[(4-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine —— C29H20N8O2S2
    6-[[6-[(4-nitrophenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-2-N,4-N-diphenyl-1,3,5-triazine-2,4-diamine
    —— N-[(Z)-[(2Z)-2-benzylideneheptylidene]amino]-6-chloro-2-methylsulfanylpyrimidin-4-amine —— C19H23ClN4S
    N-[(Z)-[(2Z)-2-benzylideneheptylidene]amino]-6-chloro-2-methylsulfanylpyrimidin-4-amine
    —— N-(4-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C27H18N6O5S3
    N-(4-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— 1-(5-bromothiophen-2-yl)-2-[[(1R,8R)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]ethanone —— C17H18BrN3OS2
    1-(5-bromothiophen-2-yl)-2-[[(1R,8R)-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-trien-5-yl]sulfanyl]ethanone
    —— N-[2-[(4-nitrophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C26H17N5O4S3
    N-[2-[(4-nitrophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— N-[2-[(2,5-dichlorophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C26H16Cl2N4O2S3
    N-[2-[(2,5-dichlorophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— N-[2-[(4-bromophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C26H17BrN4O2S3
    N-[2-[(4-bromophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— N-[2-[(4-chlorophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C26H17ClN4O2S3
    N-[2-[(4-chlorophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— 2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-(2-phenoxyethyl)acetamide —— C29H23N5O4S3
    2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-(2-phenoxyethyl)acetamide
    —— N-benzyl-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C28H21N5O3S3
    N-benzyl-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— 2-[[6-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-cyclopropylacetamide —— C26H19N5O3S4
    2-[[6-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-cyclopropylacetamide
    —— N-[2-(1H-benzimidazol-2-ylmethylsulfanyl)-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C27H18N6O2S3
    N-[2-(1H-benzimidazol-2-ylmethylsulfanyl)-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— 1-benzyl-3-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]thiourea —— C21H17ClN4O2S2
    1-benzyl-3-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]thiourea
    —— 2-[[6-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C28H23N5O4S4
    2-[[6-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C26H23N5O4S3
    2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— N-(4-fluorophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C27H18FN5O3S3
    N-(4-fluorophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— 1-Morpholin-4-yl-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]ethanone —— C25H21N5O4S3
    1-Morpholin-4-yl-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]ethanone
    —— 2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C26H23N5O4S3
    2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 1-(4-Fluoronaphthalen-1-yl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]ethanone —— C31H19FN4O3S3
    1-(4-Fluoronaphthalen-1-yl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]ethanone
    —— 2-[[6-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C28H23N5O4S4
    2-[[6-[[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— N-[2-[(2,6-dichlorophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C26H16Cl2N4O2S3
    N-[2-[(2,6-dichlorophenyl)methylsulfanyl]-1,3-benzothiazol-6-yl]-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— 2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-phenylacetamide —— C27H19N5O3S3
    2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]-N-phenylacetamide
    —— N-(2-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide —— C27H18N6O5S3
    N-(2-nitrophenyl)-2-[[6-[(3-nitro-4-pyridin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzothiazol-2-yl]sulfanyl]acetamide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-4-nitroaniline —— C18H12N4O3S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-4-nitroaniline
    —— N-[(Z)-[3-bromo-4-(dimethylamino)phenyl]methylideneamino]-3-phenylsulfanylpropanamide —— C18H20BrN3OS
    N-[(Z)-[3-bromo-4-(dimethylamino)phenyl]methylideneamino]-3-phenylsulfanylpropanamide