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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Methylsulfanyl-5-piperidin-1-ylmethyl-[1,2,4]triazol-4-ylamine —— C9H17N5S
    3-Methylsulfanyl-5-piperidin-1-ylmethyl-[1,2,4]triazol-4-ylamine
    —— ethyl (1S,3S)-2-methyl-1,3-dioxo-1,3-dithiolane-2-carboxylate —— C7H12O4S2
    ethyl (1S,3S)-2-methyl-1,3-dioxo-1,3-dithiolane-2-carboxylate
    —— 3-[(2,6-Dimethylphenyl)thio]-2-methylpropan-1-amine —— C12H19NS
    3-[(2,6-Dimethylphenyl)thio]-2-methylpropan-1-amine
    —— 5-((E)-2-(N,N-dimethylamino)ethenyl)-6-methyl-3-methylmercapto-1,2,4-triazine —— C9H14N4S
    5-((E)-2-(N,N-dimethylamino)ethenyl)-6-methyl-3-methylmercapto-1,2,4-triazine
    —— (Z)-tert-butyl hex-1-enyl sulfide —— C10H20S
    (Z)-tert-butyl hex-1-enyl sulfide
    —— 2-[(Z)-4-(1,3,4-thiadiazol-2-ylsulfanyl)but-2-enyl]sulfanyl-1,3,4-thiadiazole —— C8H8N4S4
    2-[(Z)-4-(1,3,4-thiadiazol-2-ylsulfanyl)but-2-enyl]sulfanyl-1,3,4-thiadiazole
    —— 2-decylsulfanyl-5-[(1E,3E,5E,7E,9E)-10-[5-[6-[5-[(1E,3E,5E,7E,9E)-10-(5-decylsulfanylthiophen-2-yl)deca-1,3,5,7,9-pentaenyl]thiophen-2-yl]sulfanylhexylsulfanyl]thiophen-2-yl]deca-1,3,5,7,9-pentaenyl]thiophene —— C62H82S8
    2-decylsulfanyl-5-[(1E,3E,5E,7E,9E)-10-[5-[6-[5-[(1E,3E,5E,7E,9E)-10-(5-decylsulfanylthiophen-2-yl)deca-1,3,5,7,9-pentaenyl]thiophen-2-yl]sulfanylhexylsulfanyl]thiophen-2-yl]deca-1,3,5,7,9-pentaenyl]thiophene
    —— [1-[[1-[bis(phenylmethoxy)phosphorylmethyl]-3,6-dihydro-2H-pyridin-4-yl]methyl]-5-(3,5-dichlorophenyl)sulfanyl-4-propan-2-ylimidazol-2-yl]methyl carbamate —— C35H39Cl2N4O5PS
    [1-[[1-[bis(phenylmethoxy)phosphorylmethyl]-3,6-dihydro-2H-pyridin-4-yl]methyl]-5-(3,5-dichlorophenyl)sulfanyl-4-propan-2-ylimidazol-2-yl]methyl carbamate
    —— 2-decylsulfanyl-5-[(1E,3E,5E,7E,9E,11E)-12-(5-decylsulfanylthiophen-2-yl)dodeca-1,3,5,7,9,11-hexaenyl]thiophene —— C40H58S4
    2-decylsulfanyl-5-[(1E,3E,5E,7E,9E,11E)-12-(5-decylsulfanylthiophen-2-yl)dodeca-1,3,5,7,9,11-hexaenyl]thiophene
    —— S-<(pentachlorophenylsulfanyl)dichloromethyl>adamantane-1-thiosulfonate —— C17H15Cl7O2S3
    S-<(pentachlorophenylsulfanyl)dichloromethyl>adamantane-1-thiosulfonate
    —— 6-[(Z)-2-(furan-2-yl)ethenyl]-3-(phenylsulfanylmethyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole —— C16H12N4OS2
    6-[(Z)-2-(furan-2-yl)ethenyl]-3-(phenylsulfanylmethyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— ethyl (4-{4-[3-(2,3-dichlorophenyl)-1-phenethylureido]phenylsulphanyl}phenyl)acetate 735314-31-5 C31H28Cl2N2O3S
    ethyl (4-{4-[3-(2,3-dichlorophenyl)-1-phenethylureido]phenylsulphanyl}phenyl)acetate
    —— 1-[(2S)-2-(furan-2-yl)-2-hydroxyethyl]-3-(2-methyl-4-phenylsulfanylphenyl)urea —— C20H20N2O3S
    1-[(2S)-2-(furan-2-yl)-2-hydroxyethyl]-3-(2-methyl-4-phenylsulfanylphenyl)urea
    —— 1-[(2R)-2-(furan-2-yl)-2-hydroxyethyl]-3-(2-methyl-4-phenylsulfanylphenyl)urea —— C20H20N2O3S
    1-[(2R)-2-(furan-2-yl)-2-hydroxyethyl]-3-(2-methyl-4-phenylsulfanylphenyl)urea
    —— ethyl (3-{4-[3-benzyl-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetate 735273-64-0 C33H34N2O3S
    ethyl (3-{4-[3-benzyl-1-(3-phenylpropyl)ureido]phenylsulphanyl}phenyl)acetate
    —— 4-hydroxy-2-[(Z)-2-[5-(4-methylphenyl)sulfanylfuran-2-yl]ethenyl]-5-nitro-1H-pyrimidin-6-one —— C17H13N3O5S
    4-hydroxy-2-[(Z)-2-[5-(4-methylphenyl)sulfanylfuran-2-yl]ethenyl]-5-nitro-1H-pyrimidin-6-one
    —— (5Z)-5-[[4-(4-methylphenyl)sulfanylphenyl]methylidene]-1,3-thiazolidine-2,4-dione —— C17H13NO2S2
    (5Z)-5-[[4-(4-methylphenyl)sulfanylphenyl]methylidene]-1,3-thiazolidine-2,4-dione
    —— 1-[(4-ethyl-1,2,4-triazol-3-yl)methyl]-3-(2-methyl-4-phenylsulfanylphenyl)urea —— C19H21N5OS
    1-[(4-ethyl-1,2,4-triazol-3-yl)methyl]-3-(2-methyl-4-phenylsulfanylphenyl)urea
    —— [3-[4-[Butylcarbamoyl(1-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C29H34N2O3S
    [3-[4-[Butylcarbamoyl(1-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 3-(4-fluoro-phenylsulfanyl)-6-(4H-[1,2,4]triazole-3-yl-sulfanyl)-N-(thiazoleo[5,4-b]pyridine-2-yl)-2-pyridine carboxamide —— C20H12FN7OS3
    3-(4-fluoro-phenylsulfanyl)-6-(4H-[1,2,4]triazole-3-yl-sulfanyl)-N-(thiazoleo[5,4-b]pyridine-2-yl)-2-pyridine carboxamide
    —— 2-Benzylsulfanyl-5-[3-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)phenyl]-1,3,4-oxadiazole —— C24H18N4O2S2
    2-Benzylsulfanyl-5-[3-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)phenyl]-1,3,4-oxadiazole
    —— (Z,4R,5R)-5-[tert-butyl(dimethyl)silyl]oxy-1,1,1-trifluoro-7-phenyl-4-phenylsulfanylhept-2-en-2-ol —— C25H33F3O2SSi
    (Z,4R,5R)-5-[tert-butyl(dimethyl)silyl]oxy-1,1,1-trifluoro-7-phenyl-4-phenylsulfanylhept-2-en-2-ol
    —— 2-[(Z)-but-2-enyl]sulfonyl-N-cyclopentyl-N-cyclopropylacetamide —— C14H23NO3S
    2-[(Z)-but-2-enyl]sulfonyl-N-cyclopentyl-N-cyclopropylacetamide
    —— 2-[(Z)-but-2-enyl]sulfonyl-N-(cyclohexylmethyl)-N-methylacetamide —— C14H25NO3S
    2-[(Z)-but-2-enyl]sulfonyl-N-(cyclohexylmethyl)-N-methylacetamide
    —— (2S,3S,4R)-4-diphenylphosphinoyl-5-methyl-2-(phenylsulfanyl)hexane-1,3-diol —— C25H29O3PS
    (2S,3S,4R)-4-diphenylphosphinoyl-5-methyl-2-(phenylsulfanyl)hexane-1,3-diol
    —— N-[2-(5-chloro-2-methylphenyl)sulfanylpyridin-3-yl]-4-nitrobenzenesulfonamide —— C18H14ClN3O4S2
    N-[2-(5-chloro-2-methylphenyl)sulfanylpyridin-3-yl]-4-nitrobenzenesulfonamide
    —— 2-[4-Tert-butyl-5-(4-chlorophenyl)sulfanyl-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid —— C23H25ClN2O2S
    2-[4-Tert-butyl-5-(4-chlorophenyl)sulfanyl-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid
    —— [(Z)-1-butyltellanyl-2-phenylsulfanylethenoxy]-trimethylsilane —— C15H24OSSiTe
    [(Z)-1-butyltellanyl-2-phenylsulfanylethenoxy]-trimethylsilane
    —— 2-[4-methylsulfonyl-5-(1H-pyrazol-5-ylsulfanyl)-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid —— C17H18N4O4S2
    2-[4-methylsulfonyl-5-(1H-pyrazol-5-ylsulfanyl)-6,7,8,9-tetrahydropyrido[3,2-b]indolizin-6-yl]acetic acid
    —— [4-(Piperidine-1-carbothioylsulfanyl)phenyl] piperidine-1-carbodithioate —— C18H24N2S4
    [4-(Piperidine-1-carbothioylsulfanyl)phenyl] piperidine-1-carbodithioate
    —— (3R)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3R)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— (3S)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C11H15NOS2
    (3S)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— 4,5,6-tris(methylsulfanyl)-1,2,3-dithiazine —— C6H9NS5
    4,5,6-tris(methylsulfanyl)-1,2,3-dithiazine
    —— (3S)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3S)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— 4,5,6-Tris(methylsulfanyl)dithiazin-3-ium;iodide —— C6H10INS5
    4,5,6-Tris(methylsulfanyl)dithiazin-3-ium;iodide
    —— (3R)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3R)-4-[(3S)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— (3R)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one —— C11H15NOS2
    (3R)-1-propan-2-yl-3-thiophen-2-ylsulfanylpyrrolidin-2-one
    —— (3S)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile —— C14H14N2O2S
    (3S)-4-[(3R)-2,3-dihydro-1-benzothiophene-3-carbonyl]morpholine-3-carbonitrile
    —— Oct-4-ynethioic acid S-(cyclohexyl-phenylsulfanyl-methyl) ester —— C21H28OS2
    Oct-4-ynethioic acid S-(cyclohexyl-phenylsulfanyl-methyl) ester
    —— (2R)-2-[(R)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine hydrochloride 667876-43-9 C19H23NOS*ClH
    (2R)-2-[(R)-[(2-ethylphenyl)thio](phenyl)methyl]morpholine hydrochloride
    —— 1-(4-methylsulfanylphenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide —— C20H17NOS2
    1-(4-methylsulfanylphenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide
    —— 1-(4-nitrophenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide —— C19H14N2O3S
    1-(4-nitrophenyl)-N-(4-phenylsulfanylphenyl)methanimine oxide
    —— N-(4-hydroxybutyl)-3-{2-[(4-methylphenyl)thio]phenyl}propanamide 710960-03-5 C20H25NO2S
    N-(4-hydroxybutyl)-3-{2-[(4-methylphenyl)thio]phenyl}propanamide
    —— N-(3-fluorophenyl)-6-phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-amine —— C17H12FN5S
    N-(3-fluorophenyl)-6-phenylsulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-amine
    —— Thioacetic acid S-((E)-1-phenylsulfanyl-undec-5-enyl) ester —— C19H28OS2
    Thioacetic acid S-((E)-1-phenylsulfanyl-undec-5-enyl) ester
    —— 1-[5-[(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-1,3,4-oxadiazol-2-yl]ethanone —— C15H19N5O2S
    1-[5-[(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-1,3,4-oxadiazol-2-yl]ethanone
    —— (2R,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol —— C8H11BrN2OS
    (2R,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol
    —— (2S,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol —— C8H11BrN2OS
    (2S,3S)-3-(5-bromopyrimidin-2-yl)sulfanylbutan-2-ol
    —— (3S)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine —— C12H17NO2S2
    (3S)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine
    —— (3R)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine —— C12H17NO2S2
    (3R)-1-methylsulfonyl-3-(phenylsulfanylmethyl)pyrrolidine