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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-N,N-Diethyl-4-[(4-amino-6-chloro-2-pyrimidinyl)thio]-2-pentenamide —— C13H19ClN4OS
    (E)-N,N-Diethyl-4-[(4-amino-6-chloro-2-pyrimidinyl)thio]-2-pentenamide
    —— 3,5-Bis(4-(methylthio)benzylidene)-4-piperidinone hydrochloride —— C21H21NOS2
    3,5-Bis(4-(methylthio)benzylidene)-4-piperidinone hydrochloride
    —— 1-[2-(Cycloocten-1-yloxy)ethoxymethyl]-5-(3, 5-dichlorophenylthio)-4-isopropyl-2-methyl-1H-imidazole —— C24H32Cl2N2O2S
    1-[2-(Cycloocten-1-yloxy)ethoxymethyl]-5-(3, 5-dichlorophenylthio)-4-isopropyl-2-methyl-1H-imidazole
    —— 6-(3,5-dimethylphenyl)sulfanyl-5-ethyl-1-[(E)-3-(2-furyl)allyl]pyrimidine-2,4-dione —— C21H22N2O3S
    6-(3,5-dimethylphenyl)sulfanyl-5-ethyl-1-[(E)-3-(2-furyl)allyl]pyrimidine-2,4-dione
    —— 6-(Furan-2-yl)-3-(phenylsulfanylmethyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole —— C14H10N4OS2
    6-(Furan-2-yl)-3-(phenylsulfanylmethyl)-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— N-cycloheptyl-2-[(1-methyl-1H-imidazol-2-yl)sulfanyl]acetamide —— C13H21N3OS
    N-cycloheptyl-2-[(1-methyl-1H-imidazol-2-yl)sulfanyl]acetamide
    —— 3-{[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanoic acid —— C10H10N2O4S
    3-{[5-(2-Methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}propanoic acid
    —— N-benzyl-2-[(1-benzyl-1H-tetrazol-5-yl)sulfanyl]acetamide —— C17H17N5OS
    N-benzyl-2-[(1-benzyl-1H-tetrazol-5-yl)sulfanyl]acetamide
    —— 6-Phenyl-3-[(phenylthio)methyl][1,2,4]triazolo[3,4-b][1,3,4]thiadiazole —— C16H12N4S2
    6-Phenyl-3-[(phenylthio)methyl][1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— methyl {[4-ethyl-5-(thiophen-2-ylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C12H15N3O2S2
    methyl {[4-ethyl-5-(thiophen-2-ylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 4-Methyl-2-{[(2-phenyl-1,3-thiazol-4-yl)methyl]sulfanyl}pyrimidine —— C15H13N3S2
    4-Methyl-2-{[(2-phenyl-1,3-thiazol-4-yl)methyl]sulfanyl}pyrimidine
    —— 3-cyclopropyl-5-[(4-methylbenzyl)sulfanyl]-4-(propan-2-yl)-4H-1,2,4-triazole —— C16H21N3S
    3-cyclopropyl-5-[(4-methylbenzyl)sulfanyl]-4-(propan-2-yl)-4H-1,2,4-triazole
    —— ethyl {[4-(prop-2-en-1-yl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C13H15N3O2S2
    ethyl {[4-(prop-2-en-1-yl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— N-[1-(3,4-dimethylphenyl)ethyl]-2-(phenylsulfanyl)acetamide —— C18H21NOS
    N-[1-(3,4-dimethylphenyl)ethyl]-2-(phenylsulfanyl)acetamide
    —— ethyl 2-((4-ethyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl)thio)acetate —— C12H15N3O2S2
    ethyl 2-((4-ethyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl)thio)acetate
    —— 2-{[5-methyl-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(1-phenylethyl)acetamide —— C16H20N4OS
    2-{[5-methyl-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(1-phenylethyl)acetamide
    —— N-cyclopentyl-2-{[4-(prop-2-en-1-yl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C16H20N4OS2
    N-cyclopentyl-2-{[4-(prop-2-en-1-yl)-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-({[2-(2-Methylphenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)pyrimidine —— C15H13N3S2
    2-({[2-(2-Methylphenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)pyrimidine
    —— methyl {[5-(5-ethylthiophen-3-yl)-4-methyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C12H15N3O2S2
    methyl {[5-(5-ethylthiophen-3-yl)-4-methyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 2-{[5-(2-methylfuran-3-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C12H16N4O2S
    2-{[5-(2-methylfuran-3-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— methyl {[4-methyl-5-(2-thienylmethyl)-4H-1,2,4-triazol-3-yl]thio}acetate —— C11H13N3O2S2
    methyl {[4-methyl-5-(2-thienylmethyl)-4H-1,2,4-triazol-3-yl]thio}acetate
    —— 2-{[5-(4,5-dimethylthiophen-3-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C13H16N4OS2
    2-{[5-(4,5-dimethylthiophen-3-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-cyclopropyl-2-{[5-(5-methylthiophen-3-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C15H20N4OS2
    N-cyclopropyl-2-{[5-(5-methylthiophen-3-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-(furan-2-ylmethyl)-2-{[5-(furan-2-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C16H18N4O3S
    N-(furan-2-ylmethyl)-2-{[5-(furan-2-yl)-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 2-{[5-(5-methylthiophen-3-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C12H14N4OS2
    2-{[5-(5-methylthiophen-3-yl)-4-(prop-2-en-1-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-cyclopropyl-2-{[4-methyl-5-(2-methylfuran-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C13H16N4O2S
    N-cyclopropyl-2-{[4-methyl-5-(2-methylfuran-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— 3-[(3-fluorobenzyl)sulfanyl]-4,5-dimethyl-4H-1,2,4-triazole —— C11H12FN3S
    3-[(3-fluorobenzyl)sulfanyl]-4,5-dimethyl-4H-1,2,4-triazole
    —— methyl {[4-ethyl-5-(5-methylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C12H15N3O2S2
    methyl {[4-ethyl-5-(5-methylthiophen-3-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— N-cyclopropyl-2-{[5-cyclopropyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide —— C13H20N4OS
    N-cyclopropyl-2-{[5-cyclopropyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}acetamide
    —— N-cyclopentyl-2-[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C10H16N4OS
    N-cyclopentyl-2-[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-{[5-methyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(1-phenylethyl)acetamide —— C16H22N4OS
    2-{[5-methyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}-N-(1-phenylethyl)acetamide
    —— methyl {[5-(5-methylthiophen-3-yl)-4-propyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetate —— C13H17N3O2S2
    methyl {[5-(5-methylthiophen-3-yl)-4-propyl-4H-1,2,4-triazol-3-yl]sulfanyl}acetate
    —— 2-phenyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3,4-oxadiazole —— C11H9N5OS
    2-phenyl-5-(1H-1,2,4-triazol-5-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— 3,3-Dimethyl-1-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}butan-2-one —— C9H14N2OS3
    3,3-Dimethyl-1-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}butan-2-one
    —— N-cyclopentyl-2-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetamide —— C10H15N3OS3
    N-cyclopentyl-2-{[3-(methylsulfanyl)-1,2,4-thiadiazol-5-yl]sulfanyl}acetamide
    —— 1-Methyl-4-[2-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]piperazine —— C11H21N5S
    1-Methyl-4-[2-(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)ethyl]piperazine
    —— 2,4-Di(propan-2-yl)-6-prop-1-en-2-yl-1,3,2-dioxaphosphinane-5,5-dithiol —— C12H23O2PS2
    2,4-Di(propan-2-yl)-6-prop-1-en-2-yl-1,3,2-dioxaphosphinane-5,5-dithiol
    —— [(Z)-(2,4,5-trimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate —— C9H16N2O2S2
    [(Z)-(2,4,5-trimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate
    —— Ethyl cis-1-propenyl disulfide —— C5H10S2
    Ethyl cis-1-propenyl disulfide
    —— Methyl pentyl tetrasulfide —— C6H14S4
    Methyl pentyl tetrasulfide
    —— Cyclohexane, 1,2-bis-(methylthio), trans —— C8H16S2
    Cyclohexane, 1,2-bis-(methylthio), trans
    —— 1-(Methylthio)propyl 1-propenyl disulfide —— C7H14S4
    1-(Methylthio)propyl 1-propenyl disulfide
    —— 2,5-Dichloro-4-cyano-6-pentafluoroethylthiopyridine —— C8HCl2F5N2S
    2,5-Dichloro-4-cyano-6-pentafluoroethylthiopyridine
    —— Di(3-chloro-4-methoxyphenyl)sulfide —— C14H12Cl2O2S
    Di(3-chloro-4-methoxyphenyl)sulfide
    —— 3-[(4R)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C15H18N4O2S
    3-[(4R)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— 3-[(4S)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide —— C15H18N4O2S
    3-[(4S)-3-methyl-5-oxo-1,4-dihydropyrazol-4-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]propanamide
    —— 2,4-Dimethyl-6-(methylthio)pyridine —— C8H11NS
    2,4-Dimethyl-6-(methylthio)pyridine
    —— 6,7-Dihydro-2,2-dimethylcyclopenta-1,3-dithian-4(5H)-thione —— C9H12S3
    6,7-Dihydro-2,2-dimethylcyclopenta-1,3-dithian-4(5H)-thione
    —— 3-[(3aR,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide —— C21H22ClN3O3S2
    3-[(3aR,7aS)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide
    —— 3-[(3aR,7aR)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide —— C21H22ClN3O3S2
    3-[(3aR,7aR)-1,3-dioxo-3a,4,5,6,7,7a-hexahydroisoindol-2-yl]-N-[3-chloro-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]propanamide