环氧化物是一类在碳链上含有一个环氧基团(即C-O-C三元环)的化合物。它们通常表示为R1-R2-OC-O-R3,其中R1、R2和R3可以是相同或不同的取代基。环氧化物广泛存在于自然界中,并且在有机化学、化学化工及生物医药领域中有着重要的应用。
环氧基团环氧基团的结构式为O=C-O-C=O,它具有高度反应性,能够参与多种类型的反应,例如加成反应、开环反应等。由于其特殊的化学性质,环氧化物可以被用作有机合成中的重要中间体,也可以作为聚合物化学中制备交联剂的基础。
应用领域环氧化物的合成方法多样,包括但不限于:
这些方法可根据具体需求选择最合适的合成路径。
| 中文名称 | 英文名称 | CAS号 | 化学式 |
|---|---|---|---|
| —— | β-Methyl-β-[p-(1-cyclohexenyl)-phenyl]-glycidic acid ethyl ester | 28164-65-0 | C18H22O3 |
| —— | (2S,4S)-2-ethyl-4-isobutyl-5,5-dipropyloxazolidine | 1173393-14-0 | C15H31NO |
| —— | 2-ethyl-1-oxa-spiro[2.4]heptane | 28256-58-8 | C8H14O |
| —— | 4-(3-Isopropyl-oxiranyl)-3-methyl-butan-1-ol | 62885-95-4 | C10H20O2 |
| —— | 2-(((6-(allyloxy)hexyl)oxy)methyl)oxirane | 1246463-46-6 | C12H22O3 |
| —— | 3-Isopropyliden-2,2-dimethyloxiran | 25564-49-2 | C7H12O |
| —— | 1-<(2,3-Epoxy-propyloxy)-methyl>-2-vinyl-cyclopropan | 60728-66-7 | C9H14O2 |
| —— | 1,2-Epoxy-2-propin-(2)-yl-pentin-(4) | 68697-98-3 | C8H8O |
| —— | 1192036-70-6 | C10H18O2 | |
| —— | 2-((2S,3R)-3-Octyl-oxiranyl)-ethanol | 255040-40-5 | C12H24O2 |
| —— | (2'S*,3S*)-3-<2-(2-methoxyethoxy)methoxy-3-methylbutyl>-2,2-dimethyloxirane | 142321-63-9 | C13H26O4 |
| —— | 4,5-epoxy-1-methoxy-pent-2-yne | 857788-28-4 | C6H8O2 |
| —— | cis-<(2)H2>ethylene oxide | 13482-12-7 | C2H4O |
| —— | (1R,2S,6S,9S,10S,12S,15S)-10-methoxy-2-(methoxymethoxy)-5,5-dimethyl-11,13-dioxatetracyclo[10.2.1.0<sup>1,6</sup>.0<sup>9,15</sup>]pentadec-7-en-14-ol | 374570-66-8 | C18H28O6 |
| —— | cis-(5-methyl-1,3-dioxan-2-yl)methyl radical | 138943-84-7 | C6H11O2 |
| —— | 9-(2,3-Dibrompropyl)-1,3,5,7-tetramethyltotcyn | 26421-85-2 | C12H18Br2O4 |
| —— | (6R,7S,9R,10S)-6,7:9,10-bisepoxyhenicosane | 129436-94-8 | C21H40O2 |
| —— | Barium(2+);1-oxaspiro[2.5]octane-2-carboxylic acid | 6326-84-7 | C8H12BaO3+2 |
| —— | [(2S,3S)-3-[(2R)-pentan-2-yl]oxiran-2-yl]methanol | 1438399-39-3 | C8H16O2 |
| —— | 4-tert-butoxy-2,3-epoxybutanol | 116503-38-9 | C8H16O3 |
| —— | 2-chloro-3-(chloro-difluoro-methyl)-2-fluoro-3-methyl-oxirane | 37586-14-4 | C4H3Cl2F3O |
| —— | 63482-54-2 | C17H30N6O7 | |
| —— | 1253041-45-0 | C10H17NO5 | |
| —— | β-Methyl-β-<but-3-enyl>-glycid-ethylester | 65422-07-3 | C10H16O3 |
| —— | 6-oxabicyclo<3.2.2>non-3-ene | 63838-83-5 | C8H12O |
| —— | 2,3:4,5-diepoxy-2,3,4,5-tetrahydrofuran | 187-30-4 | C4H4O3 |
| —— | Sodium;3,3-dimethyloxirane-2-carboxylic acid | 34886-30-1 | C5H8NaO3+ |
| —— | 2-(Chloromethyl)oxirane--ammonia--hydrogen chloride (1/1/1) | 80044-11-7 | C3H9Cl2NO |
| —— | 2-Methyl-5-((2S,3R)-3-pentyl-2-trimethylsilanyl-oxiranyl)-pentanenitrile | 120332-54-9 | C16H31NOSi |
| —— | (2'S*,3R*)-3-<2-(2-methoxyethoxy)methoxy-3-methylbutyl>-2,2-dimethyloxirane | 142321-62-8 | C13H26O4 |
| —— | (2R,3R)-2-Cyclohexyl-3-methoxymethyl-oxirane | 118043-44-0 | C10H18O2 |
| —— | 4-(chloromethyl)-2-(4,6-dimethylcyclohex-3-en-1-yl)-1,3-dioxolane | 97303-69-0 | C12H19ClO2 |
| —— | (4S,5S)-2-Difluoromethyl-4,5-difluoro-2-trifluoromethyl-[1,3]dioxolane | 64688-13-7 | C5H3F7O2 |
| —— | (1S,4R,5R,6S)-1,5,6-Tris-methoxymethyl-7-oxa-bicyclo[2.2.1]hept-2-ene | 137936-85-7 | C12H20O4 |
| —— | (6R,7S,9R,10S)-6,7:9,10-bisepoxynonadecane | 129436-88-0 | C19H36O2 |
| —— | 4-bromo-1,2-epoxyperfluorobutane | 72266-32-1 | C4BrF7O |
| —— | 2-[1-(3-ethenoxypropoxy)ethoxymethyl]oxirane | 74802-06-5 | C10H18O4 |
| —— | cis-2,3-dichloro-2,3-epoxyhexafluorobutane | 143425-53-0 | C4Cl2F6O |
| —— | diethyl 2,3-dicyanooxiran-2,3-dicarboxylate | 3041-49-4 | C10H10N2O5 |
| —— | 2-Undecyl-2-vinyl-oxirane | 125380-12-3 | C15H28O |
| —— | 2-[(4-Prop-2-enoxycyclohexyl)oxymethyl]oxirane | 1246463-47-7 | C12H20O3 |
| —— | (4R,5R)-4-N,4-N,5-N,5-N-tetramethyl-2-[(E)-prop-1-enyl]-1,3-dioxolane-4,5-dicarboxamide | 91327-69-4 | C12H20N2O4 |
| —— | (2R,3R)-Oxirane-2,3-dicarboxylic acid mono-tert-butyl ester | 63550-90-3 | C8H12O5 |
| —— | 1,15-bis(trimethylsilyl)-3:3,8:8,13:13-tris(1,1,2,2-tetramethylethano)pentadeca-1,4,6,9,11,14-hexayne | 479193-07-2 | C39H54Si2 |
| —— | 1,2-Epoxy-3-isobutyloxymethoxy-propan | 90435-26-0 | C8H16O3 |
| —— | trans-N-Cyclopentyl-2-phenyl-3-carbamoyl-oxiran | 19464-97-2 | C14H17NO2 |
| —— | trans-(5-methyl-1,3-dioxan-2-yl)methyl radical | 138943-85-8 | C6H11O2 |
| —— | 2-((Z)-Heptadec-8-enyl)-2-methyl-oxirane | 120400-85-3 | C20H38O |
| —— | (2R,3R)-1-Hydroxy-2,3-epoxyundec-5-yne | 79083-57-1 | C11H18O2 |
| —— | (-)-4-methylene-1-oxaspiro<2.11>tetradecane | 107132-39-8 | C14H24O |