(3R,4S)-3-[(4R)-2,2-二甲基-1,3-二氧戊环-4-基]-7,7-二甲基-4-丙-2-烯氧基-2,6,8-三氧杂双环[3.3.0]辛烷 | 20316-77-2

分子结构分类

有机化合物 - 有机氧化合物

中文名称

(3R,4S)-3-[(4R)-2,2-二甲基-1,3-二氧戊环-4-基]-7,7-二甲基-4-丙-2-烯氧基-2,6,8-三氧杂双环[3.3.0]辛烷

中文别名

——

英文名称

(3aR,5R,6S,6aR)-6-(allyloxy)-5-((R)-2,2-dimethyl[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydrofuro[2,3-d][1,3]dioxole

英文别名

3-O-allyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose；(3R,4S)-3-[(4R)-2,2-Dimethyl-1,3-dioxolan-4-YL]-7,7-dimethyl-4-prop-2-enoxy-2,6,8-trioxabicyclo[3.3.0]octane；(3aR,5R,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-6-prop-2-enoxy-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxole

(3R,4S)-3-[(4R)-2,2-二甲基-1,3-二氧戊环-4-基]-7,7-二甲基-4-丙-2-烯氧基-2,6,8-三氧杂双环[3.3.0]辛烷化学式

CAS

20316-77-2

化学式

C₁₅H₂₄O₆

mdl

——

分子量

300.352

InChiKey

XVJPYQDFXZAPEI-UJPOAAIJSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

1.2
重原子数：

21
可旋转键数：

4
环数：

3.0
sp3杂化的碳原子比例：

0.87
拓扑面积：

55.4
氢给体数：

0
氢受体数：

6

SDS

SDS：d847d4841fbf1dcfc3503ebfbb740950

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上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	1,2:5,6-di-O-isopropylidene-3-O-methylprenyl-α-D-glucofuranose	753488-63-0	C₁₈H₃₀O₆	342.433
双丙酮葡萄糖	1,2:5,6-di-O-isopropylidene-α-D-glucofuranose	582-52-5	C₁₂H₂₀O₆	260.287
——	1,2:5,6-diacetone-D-glucose	582-52-5	C₁₂H₂₀O₆	260.287
——	(3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyl-6-(propa-1,2-dien-1-yloxy)tetrahydrofuro[2,3-d][1,3]dioxole	142363-22-2	C₁₅H₂₂O₆	298.336
3-O-乙酰基-1,2:5,6-二-O-异丙基-Alpha-D-呋喃(型)葡萄糖	3-O-acetyl-1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose	16713-80-7	C₁₄H₂₂O₇	302.324
——	3-O-benzoyl-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose	13964-22-2	C₁₉H₂₄O₇	364.395
——	3-O-[(t-butyl)dimethylsilyl]-1,2:5,6-di-O-isopropylidene-α-D-glucofuranose	99605-27-3	C₁₈H₃₄O₆Si	374.55
——	D-glucose	610-85-5	C₆H₁₂O₆	180.158
二氧化硅	α-D-glucofuranose	610-85-5	C₆H₁₂O₆	180.158
a-无水葡萄糖酯	alpha-D-glucopyranose	492-62-6	C₆H₁₂O₆	180.158
D-葡萄糖	D-glu	2280-44-6	C₆H₁₂O₆	180.158

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	3-O-allyl-1,2-O-isopropylidene-α-D-glucofuranose	91882-92-7	C₁₂H₂₀O₆	260.287
——	3-O-allyl-1,2-O-isopropylidene-5-O-methallyl-α-D-glucofuranose	753488-52-7	C₁₆H₂₆O₆	314.379
——	(3aR,4R,5R,6S,6aR) 2-[5-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-6-yloxy]ethanol	34819-96-0	C₁₄H₂₄O₇	304.34
——	(2'S)-1,2,5,6-di-O-isopropylidene-3-O-[2',3'-epoxypropan-1'-yl]-α-D-glucofuranose	139973-62-9	C₁₅H₂₄O₇	316.351
——	(2'R)-1,2,5,6-di-O-isopropylidene-3-O-[2',3'-epoxypropan-1'-yl]-α-D-glucofuranose	139973-59-4	C₁₅H₂₄O₇	316.351
——	3-O-allyl-1,2-O-isopropylidene-5-O-methallyl-6-O-methylprenyl-α-D-glucofuranose	753488-53-8	C₂₂H₃₆O₆	396.524
——	(3aR,5R,6S,6aR)-6-(allyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-ylmethanol	182934-64-1	C₁₁H₁₈O₅	230.261
双丙酮葡萄糖	1,2:5,6-di-O-isopropylidene-α-D-glucofuranose	582-52-5	C₁₂H₂₀O₆	260.287
——	methyl (E)-4-[[(3aR,5R,6S,6aR)-5-[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-6-yl]oxy]but-2-enoate	188691-11-4	C₁₇H₂₆O₈	358.389
——	[(3aR,5R,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy]-acetaldehyde	176440-96-3	C₁₄H₂₂O₇	302.324
——	(E)-4-[(3aR,5R,6S,6aR)-5-((R)-1,2-Dihydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy]-but-2-enoic acid methyl ester	188691-12-5	C₁₄H₂₂O₈	318.324
——	(1R,2R,3S,4R,5R)-5-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-propenyloxy-tetrahydro-furo[2,3-d][1,3]dioxole	142435-23-2	C₁₅H₂₄O₆	300.352
——	(1R,2R,3S,4R,5R)-5-(2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-propenyloxy-tetrahydro-furo[2,3-d][1,3]dioxole	142435-25-4	C₁₅H₂₄O₆	300.352
——	1,2:5,6-di-O-isopropylidene-3-O-acrylate-α-D-glucopentoaldo-1,4-furanose	40690-74-2	C₁₅H₂₂O₇	314.335
——	3-O-allyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose	226919-74-0	C₁₂H₁₈O₄	226.273
——	3-O-Allyl-1,2-O-isopropylidene-α-D-xylo-pentodialdose	152185-56-3	C₁₁H₁₆O₅	228.245
——	(1S,6R,8R,9R)-8,9-dihydroxy-8,9-O-isopropylidene-2,7-dioxabicyclo[3.4.0]non-4-ene	226919-75-1	C₁₀H₁₄O₄	198.219
——	(E)-4-((3aR,5S,6S,6aR)-5-Formyl-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yloxy)-but-2-enoic acid methyl ester	188691-13-6	C₁₃H₁₈O₇	286.282
——	O-β-D-glucopyranosyl-(1->2)-O-β-D-glucopyranosyl-(1->4)-D-galactose	493-34-5	C₁₈H₃₂O₁₆	504.442
1,2,4,6-四-O-乙酰基-3-O-烯丙基-β-D-吡喃葡萄糖	1,2,4,6-tetra-O-acetyl-3-O-allyl-β-D-glucopyranose	39698-00-5	C₁₇H₂₄O₁₀	388.372
1,2:5,6-二-o-异亚丙基-alpha-d-ribo-3-己呋喃核糖	1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose	2847-00-9	C₁₂H₁₈O₆	258.271
——	3-O-allyl-D-glucopyranose	91109-44-3	C₉H₁₆O₆	220.222
——	3-O-Allyl-6-deoxy-D-glucose	134311-65-2	C₉H₁₆O₅	204.223
——	3-O-allyl-6-O-(tert-butyldimethylsilyl)-5-oxo-1,2-O-isopropylidene-α-D-xylo-hexofuranose	194997-06-3	C₁₈H₃₂O₆Si	372.534
——	methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->3)-2,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->3)-2-O-benzyl-(R)-4,6-O-benzylidene-α-D-mannopyranoside	502181-63-7	C₇₅H₈₀O₁₆	1237.45

反应信息

作为反应物：

描述：