反-5-癸烯 | 7433-56-9

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 无环烃
• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 中文名称: 反-5-癸烯
• 中文别名: 5-癸烯；反-1,2-二丁基乙烯；反式-5-癸烯
• 英文名称: (E)-5-decene
• 英文别名: trans-5-decene；(E)-dec-5-ene；5-decene；trans-dec-5-ene；dec-5-ene
• CAS: 7433-56-9
• 化学式: C₁₀H₂₀
• 分子量: 140.269
• InChiKey: UURSXESKOOOTOV-MDZDMXLPSA-N

物化性质

• 熔点：
  -73°C
• 沸点：
  170 °C/750 mmHg (lit.)
• 密度：
  0.74 g/mL at 25 °C (lit.)
• 闪点：
  115 °F
• 介电常数：
  2.0299999999999998
• 保留指数：
  992;992;992;992;1000;1000;993;984;992;1000
• 稳定性/保质期：
  如果按照规格正确使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险等级：
  3
• 危险品标志：
  Xi
• 安全说明：
  S16,S26,S36/37/39
• 危险类别码：
  R10
• WGK Germany：
  3
• 危险品运输编号：
  UN 3295 3/PG 3
• RTECS号：
  HE2080000
• 包装等级：
  III
• 危险类别：
  3
• 储存条件：
  密封在阴凉干燥的环境中。

SDS

Name:	Trans-5-Decene 99+% Material Safety Data Sheet
Synonym:	None known
CAS:	7433-56-9

Section 1 - Chemical Product MSDS Name:Trans-5-Decene 99+% Material Safety Data Sheet
Synonym:None known

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
7433-56-9	Trans-5-Decene	>99	231-080-7

Hazard Symbols: None Listed.
Risk Phrases: 10

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Flammable.
Potential Health Effects
Eye:
May cause eye irritation. May cause chemical conjunctivitis and corneal damage.
Skin:
May cause irritation and dermatitis. May cause cyanosis of the extremities.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause CNS depression.
Inhalation:
The toxicological properties of this substance have not been fully investigated. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause burning sensation in the chest.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Flammables-area.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits CAS# 7433-56-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: clear, colorless
Odor: aromatic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 170 deg C @ 750.00mmHg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: 46 deg C ( 114.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .7400g/cm3
Molecular Formula: C10H20
Molecular Weight: 140.27

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7433-56-9: HE2080000 LD50/LC50:
Not available.
Carcinogenicity:
Trans-5-Decene - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: FLAMMABLE LIQUID, N.O.S.*
Hazard Class: 3
UN Number: 1993
Packing Group: III
IMO
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3.3
UN Number: 1993
Packing Group: III
RID/ADR
Shipping Name: FLAMMABLE LIQUID, N.O.S.
Hazard Class: 3
UN Number: 1993
Packing group: III

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
R 10 Flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 28A After contact with skin, wash immediately with
plenty of water.
S 33 Take precautionary measures against static
discharges.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 7433-56-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7433-56-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7433-56-9 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  反-5-癸烯 在 10% Pt/activated carbon 、 N,N-二异丙基乙胺 作用下， 以 对二甲苯 为溶剂， 反应 14.0h， 生成 癸烷
  参考文献：
  名称：

  内烯烃与叔胺作为氢供体在碳载贵金属上的氢转移反应†

  摘要：

  在碳载体上存在贵金属的情况下，观察到与叔胺的氢化物转移反应。以前已经在三乙胺的存在下以活化的烯丙基型碳-碳双键（含羰基衍生物）的形式记录了氢化物转移（共轭还原）。所提出的机理是氢化物转移反应，其中金属充当氢化物-金属亚胺鎓加合物形成的反应伙伴。在这项工作中首次观察到未活化的内部双键化合物（例如油酸甲酯和反式-5-癸烯）作为底物的饱和状态。预还原的催化剂样品显示出高活性。在Pd / C，Pt / C和铑/碳的存在下部分到完全转化在140℃下，在检测到p-不含分子氢的二甲苯溶剂。形成了较高分子量的胺副产物，而在底物的情况下，存在可忽略量的未反应但双键迁移的物质。除三乙胺外，还有可能使用其他烷基胺。因此，研究了使用三丁基-，三戊基-，三己基胺和N，N-二异丙基乙胺以及环状的1-乙基吡咯烷和1-乙基哌啶。作为H源的环胺和二异丙基衍生物产生的转化率最高，而具有较长烷基链的胺则显示出较小的活​​性。作

  DOI：

  10.1039/c7ob02614e
• 作为产物：
  描述：

  5,6-dichlorodecane 以 N,N-二甲基甲酰胺 为溶剂， 以100%的产率得到反-5-癸烯
  参考文献：
  名称：

  Zavada, Jiri; Krupicka, Josef; Kocian, Oldrich, Collection of Czechoslovak Chemical Communications, 1983, vol. 48, # 12, p. 3552 - 3558

  摘要：

  DOI：
• 作为试剂：
  描述：

  顺-4-辛烯 在 反-5-癸烯 、 乙烯 、 Mo(N^iPrPh)-(CHCMe₂Ph)(Me₂Pyrr)(OBitet) 作用下， 22.0 ℃ 、405.33 kPa 条件下， 反应 0.25h， 以45%的产率得到反-4-辛烯
  参考文献：
  名称：

  Isolation of Pure Disubstituted E Olefins through Mo-Catalyzed Z-Selective Ethenolysis of Stereoisomeric Mixtures

  摘要：

  Monoaryloxide-pyrrolide (MAP) complexes of molybdenum were employed for the selective ethenolysis of 1,2-disubstituted Z olefins in the presence of the corresponding E olefins. Reactions were performed in the presence of 0.02-3.0 mol % catalyst at 22 degrees C under 20 atm ethylene. We have demonstrated that the Z isomer of an easily accessible E:Z mixture can be destroyed through ethenolysis and the E alkene thereby isolated readily in high yield and exceptional stereoisomeric purity.

  DOI：

  10.1021/ja205002v

文献信息

• 醇供氢钯催化炔烃半还原选择性合成顺、反式烯烃的方法
  申请人：南通大学

  公开号：CN109776253B

  公开（公告）日：2022-07-15

  本发明提供了一种醇供氢钯催化炔烃半还原选择性合成顺、反式烯烃的方法，包括如下步骤：将TEOA、NaOAc、催化剂、醇与炔烃于有机溶剂中进行炔烃的还原反应，反应生成顺式烯烃；将配体、催化剂、醇与炔烃于有机溶剂中进行炔烃的还原反应，反应生成反式烯烃；还原反应的反应器为密封的耐压反应器，还原反应的温度为120～150℃，还原反应的时间为20～48h；催化剂的用量为炔烃摩尔用量的5～20％，醇的用量为炔烃摩尔用量的10～100倍；R,R‑DIPAMP的用量为炔烃摩尔用量的0.5～5倍。本发明中，催化剂体系具有极高的化学反应和立体选择性，能高产率合成顺式或者反式烯烃产物；催化体系对底物的普适性强，含各种官能团的炔烃都能高效地进行高选择性地还原反应。
• Metal-Free Epoxidation of Alkenes with Molecular Oxygen and Benzaldehyde under Visible Light Irradiation
  作者：Akichika Itoh、Norihiro Tada、Hiroaki Okubo、Tsuyoshi Miura

  DOI：10.1055/s-0029-1218271

  日期：2009.11

  A new convenient metal-free oxidation protocol of a wide variety of alkenes with molecular oxygen and benzaldehyde under visible light irradiation of fluorescent lamp afforded their corresponding epoxides in 49―99% yields.

  在荧光灯的可见光照射下，多种烯烃与分子氧和苯甲醛的一种新的方便的无金属氧化方案以 49-99% 的产率提供了相应的环氧化物。
• Iodine(III)-Promoted Intermolecular Diamination of Alkenes
  作者：José A. Souto、Yolanda González、Alvaro Iglesias、Debora Zian、Anton Lishchynskyi、Kilian Muñiz

  DOI：10.1002/asia.201101025

  日期：2012.5

  A rapid and productive vicinal diamination of alkenes takes place in the presence of a hypervalent iodine(III) reagent and bissulfonimides as nitrogen sources. A total of more than 60 examples are presented. The reaction is characterized by its robustness and its wide substrate scope: it proceeds selectively with both terminal and internal alkenes and tolerates a range of functional groups.

  在高价碘（III）试剂和双磺酰亚胺作为氮源的情况下，烯烃的快速邻位氨化反应迅速进行。总共提供了60多个示例。该反应的特点是它的耐用性和广泛的底物范围：它与末端烯烃和内部烯烃都选择性进行，并能耐受一定范围的官能团。
• Site-Selective Mono-Oxidation of 1,2-Bis(boronates)
  作者：Lu Yan、James P. Morken

  DOI：10.1021/acs.orglett.9b01204

  日期：2019.5.17

  Site-selective oxidation of vicinal bis(boronates) is accomplished through the use of trimethylamine N-oxide in 1-butanol solvent. The reaction occurs with good efficiency and selectivity across a range of substrates, providing 2-hydro-1-boronic esters which are shown to be versatile intermediates in the synthesis of chiral building blocks.

  通过在1-丁醇溶剂中使用三甲胺N-氧化物来完成邻位双（硼酸酯）的位点选择性氧化。该反应在一系列底物上以良好的效率和选择性进行，从而提供了2-氢-1-硼酸酯，该酯被证明是手性结构单元合成中的通用中间体。
• Active metals from potassium–graphite. Palladium–graphite as catalyst in the hydrogenation of nitro-compounds, alkenes, and alkynes
  作者：Diego Savoia、Claudio Trombini、Achille Umani-Ronchi、Giancarlo Verardo

  DOI：10.1039/c39810000540

  日期：——

  Palladium–graphite, prepared by reduction of PdCl2 by means of C8K in 1,2-dimethoxyethane, is an effective catalyst for the hydrogenation of aromatic nitro-compounds, alkenes, and alkynes to anilines, alkanes, and (Z)-alkenes, respectively.

  通过在1,2-二甲氧基乙烷中通过C 8 K还原PdCl 2制备的钯-石墨是一种有效的催化剂，用于将芳族硝基化合物，烯烃和炔烃氢化为苯胺，烷烃和（Z）-烯烃。

表征谱图