[(2R,4aR,6S,7R,8aS)-6-ethenyl-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-7-yl]oxy-tert-butyl-dimethylsilane | 131311-03-0

分子结构分类

有机化合物 - 有机杂环化合物 - 吡喃二恶英

中文名称

——

中文别名

——

英文名称

[(2R,4aR,6S,7R,8aS)-6-ethenyl-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-7-yl]oxy-tert-butyl-dimethylsilane

英文别名

——

[(2R,4aR,6S,7R,8aS)-6-ethenyl-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-7-yl]oxy-tert-butyl-dimethylsilane化学式

CAS

131311-03-0

化学式

C₂₃H₃₆O₄Si

mdl

——

分子量

404.622

InChiKey

GRCAZJHBZBMODI-NDHNYZRRSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

5.61
重原子数：

28
可旋转键数：

5
环数：

3.0
sp3杂化的碳原子比例：

0.65
拓扑面积：

36.9
氢给体数：

0
氢受体数：

4

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	(2R,4aR,6S,7R,8aS)-6-ethenyl-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-7-ol	131311-02-9	C₁₇H₂₂O₄	290.359
——	[(2R,4S,5R)-4-[[(2R,3R)-3-ethenyl-3-methyloxiran-2-yl]methyl]-5-methyl-2-phenyl-1,3-dioxan-5-yl]oxy-trimethylsilane	131311-00-7	C₂₀H₃₀O₄Si	362.541
——	[(2R,3R)-2-methyl-3-[[(2R,4S,5R)-5-methyl-2-phenyl-5-trimethylsilyloxy-1,3-dioxan-4-yl]methyl]oxiran-2-yl]methanol	131310-98-0	C₁₉H₃₀O₅Si	366.53
——	(2R,4S,5R)-4-[[(2R,3R)-3-ethenyl-3-methyloxiran-2-yl]methyl]-5-methyl-2-phenyl-1,3-dioxan-5-ol	131311-01-8	C₁₇H₂₂O₄	290.359

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	(E)-3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-prop-2-en-1-ol	378741-92-5	C₂₄H₃₈O₅Si	434.648
——	[(2R,4aR,6S,7R,8aS)-6-[[(2R,3R)-3-ethenyl-3-methyloxiran-2-yl]methyl]-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-7-yl]oxy-tert-butyl-dimethylsilane	131311-10-9	C₂₇H₄₂O₅Si	474.713
——	(S)-1-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-but-3-en-1-ol	374638-44-5	C₂₅H₄₀O₅Si	448.675
——	[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2,8a-dimethyl-2-vinyl-octahydro-pyrano[3,2-b]pyran-3-yloxy]-tert-butyl-dimethyl-silane	378742-02-0	C₃₅H₅₂O₅Si	580.88
——	(1S)-1-[(2R,4aR,6S,7R,8aS)-7-[tert-butyl(dimethyl)silyl]oxy-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl]propane-1,3-diol	378741-93-6	C₂₄H₄₀O₆Si	452.663
——	[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-acetaldehyde	131311-05-2	C₂₃H₃₆O₅Si	420.621
——	[(2R,3R)-3-[[(2R,4aR,6S,7R,8aS)-7-[tert-butyl(dimethyl)silyl]oxy-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-6-yl]methyl]-2-methyloxiran-2-yl]methanol	131311-08-5	C₂₆H₄₂O₆Si	478.701
——	(2R,4aR,6R,7R,8aS)-7-[tert-butyl(dimethyl)silyl]oxy-4a,6-dimethyl-2-phenyl-4,7,8,8a-tetrahydropyrano[3,2-d][1,3]dioxine-6-carbaldehyde	374638-43-4	C₂₂H₃₄O₅Si	406.594
——	(S)-3-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-3-(4-methoxy-benzyloxy)-propan-1-ol	378741-94-7	C₃₂H₄₈O₇Si	572.814
——	3-((2R,4aR,5S,7S,8aR,9aS,10aR)-4a,10a-Dimethyl-2-phenyl-5-triisopropylsilanyloxy-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-propan-1-ol	374638-50-3	C₃₀H₅₀O₆Si	534.809
——	2-((2R,4aR,5S,7S,8aR,9aS,10aR)-4a,10a-Dimethyl-2-phenyl-5-triisopropylsilanyloxy-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-ethanol	374638-49-0	C₂₉H₄₈O₆Si	520.782
——	(E)-(S)-5-[(2R,4aR,6S,7R,8aS)-7-(tert-Butyl-dimethyl-silanyloxy)-4a,6-dimethyl-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yl]-5-(4-methoxy-benzyloxy)-pent-2-enoic acid methyl ester	378741-95-8	C₃₅H₅₀O₈Si	626.863
——	((2R,4aR,5S,7R,8aR,9aS,10aR)-4a,10a-Dimethyl-2-phenyl-5-triisopropylsilanyloxy-octahydro-1,3,8,10-tetraoxa-anthracen-7-yl)-acetic acid methyl ester	374638-48-9	C₃₀H₄₈O₇Si	548.792
——	[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-2,8a-dimethyl-2-((2S,3S)-3-vinyl-oxiranylmethyl)-octahydro-pyrano[3,2-b]pyran-3-yloxy]-tert-butyl-dimethyl-silane	378742-04-2	C₃₈H₅₆O₆Si	636.945
——	[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,8a-dimethyl-octahydro-pyrano[3,2-b]pyran-2-yl]-methanol	378742-01-9	C₃₄H₅₂O₆Si	584.869
——	(E)-4-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,8a-dimethyl-octahydro-pyrano[3,2-b]pyran-2-yl]-but-2-en-1-ol	378742-12-2	C₃₇H₅₆O₆Si	624.934
——	2-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,8a-dimethyl-octahydro-pyrano[3,2-b]pyran-2-yl]-ethanol	494760-56-4	C₃₅H₅₄O₆Si	598.896
——	ethyl (E)-4-[(2R,3S,4aR,6S,8S,8aS)-3-[tert-butyl(dimethyl)silyl]oxy-2,8a-dimethyl-8-phenylmethoxy-6-(3-phenylmethoxypropyl)-3,4,4a,6,7,8-hexahydropyrano[3,2-b]pyran-2-yl]but-2-enoate	378742-03-1	C₃₉H₅₈O₇Si	666.971
——	{(2S,3S)-3-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-6-(3-benzyloxy-propyl)-3-(tert-butyl-dimethyl-silanyloxy)-2,8a-dimethyl-octahydro-pyrano[3,2-b]pyran-2-ylmethyl]-oxiranyl}-methanol	378742-13-3	C₃₇H₅₆O₇Si	640.933
——	[(2S,3R,4aS,6R,7S,8aR)-7-[tert-butyl(dimethyl)silyl]oxy-2,4a,6-trimethyl-3-phenylmethoxy-2-(2-phenylmethoxyethyl)-4,7,8,8a-tetrahydro-3H-pyrano[3,2-b]pyran-6-yl]methanol	131311-17-6	C₃₄H₅₂O₆Si	584.869
——	(1S,3R,6R,8S,10R,12S,13R)-12-ethenyl-1,3,12-trimethyl-6-phenyl-2,5,7,11-tetraoxatricyclo[8.4.0.03,8]tetradecan-13-ol	131311-11-0	C₂₁H₂₈O₅	360.45
——	(1S,3R,6R,8S,10R,12S,13R)-12-ethenyl-1,3,12-trimethyl-6-phenyl-13-phenylmethoxy-2,5,7,11-tetraoxatricyclo[8.4.0.03,8]tetradecane	131311-12-1	C