4-methylphenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-1-thio-α,β-D-glucopyranoside | 929040-77-7

分子结构分类

有机化合物 - 有机氧化合物

中文名称

——

中文别名

——

英文名称

4-methylphenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-1-thio-α,β-D-glucopyranoside

英文别名

[(2R,3S,4R,5R)-3,4-diacetyloxy-5-azido-6-(4-methylphenyl)sulfanyloxan-2-yl]methyl acetate

4-methylphenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-1-thio-α,β-D-glucopyranoside化学式

CAS

929040-77-7

化学式

C₁₉H₂₃N₃O₇S

mdl

——

分子量

437.474

InChiKey

KETOCWAVUKUWCF-XTHKVDEBSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

3.4
重原子数：

30
可旋转键数：

10
环数：

2.0
sp3杂化的碳原子比例：

0.53
拓扑面积：

128
氢给体数：

0
氢受体数：

10

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
2-叠氮基-2-脱氧-D-吡喃葡萄糖1,3,4,6-四乙酸酯	1,3,4,6-tetra-O-acetyl-2-azido-2-deoxy-D-glucopyranose	171032-74-9	C₁₄H₁₉N₃O₉	373.32

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	[(3R,4R,5S,6R)-3-azido-5-hydroxy-2-(4-methylphenyl)sulfanyl-6-(phenylmethoxymethyl)oxan-4-yl] acetate	1426329-52-3	C₂₂H₂₅N₃O₅S	443.524
——	p-tolyl 4,6-di-O-acetyl-2-azido-3-O-benzyl-2-deoxy-1-thio-Dglucopyranoside	1426329-58-9	C₂₄H₂₇N₃O₆S	485.561
——	(2R,4aR,7R,8R,8aS)-7-azido-2-phenyl-6-(p-tolylthio)hexahydropyrano[3,2-d][1,3]dioxin-8-yl acetate	1426329-51-2	C₂₂H₂₃N₃O₅S	441.508
——	p-tolyl 2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-4-O-trichloroacetyl-D-glucopyranoside	——	C₂₉H₂₈Cl₃N₃O₅S	636.983
——	p-tolyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-1-thio-D-glucopyranoside	——	C₃₄H₃₅N₃O₄S	581.736
——	p-tolyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-thioglucopyranoside	671809-80-6	C₃₄H₃₅N₃O₄S	581.736
——	p-tolyl 2-azido-3,6-di-O-benzyl-4-O-benzoyl-2-deoxy-1-thio-D-glucopyranoside	1426329-62-5	C₃₄H₃₃N₃O₅S	595.719
——	4-methylphenyl 2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-α,β-D-glucopyranoside	——	C₂₇H₂₉N₃O₄S	491.611
——	tolyl 2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-α-D-glucopyranoside	905704-43-0	C₂₇H₂₉N₃O₄S	491.611
——	p-tolyl 2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-β-D-glucopyranoside	502692-42-4	C₂₇H₂₉N₃O₄S	491.611
——	2-azido-2-deoxy-3,4,6-tri-O-benzyl-1-phenylthio-β-D-glucopyranoside	236115-65-4	C₃₃H₃₃N₃O₄S	567.709
——	4-methylphenyl 2-azido-2-deoxy-1-thio-D-glucopyranoside	——	C₁₃H₁₇N₃O₄S	311.362
——	4-methylphenyl 2-azido-2-deoxy-1-thio-D-glucopyranoside	501088-37-5	C₁₃H₁₇N₃O₄S	311.362
——	(2R,3S,4R,5R)-5-azido-2-(hydroxymethyl)-6-(4-methylphenyl)sulfanyl-4-phenylmethoxyoxan-3-ol	1426329-59-0	C₂₀H₂₃N₃O₄S	401.486
——	p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-thioglucopyranoside	502692-41-3	C₂₇H₂₇N₃O₄S	489.595
——	p-tolyl 2-deoxy-2-azido-3-O-benzyl-4,6-O-benzylidene-1-thio-α-D-glucopyranoside	1235137-50-4	C₂₇H₂₇N₃O₄S	489.595
——	p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside	1320281-36-4	C₂₇H₂₇N₃O₄S	489.595
——	p-tolyl 2-azido-4,6-O-benzylidene-1-thio-α-D-glucopyranoside	929040-55-1	C₂₀H₂₁N₃O₄S	399.47
——	p-tolyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranosyl-β-(1->6)-2-azido-3,4-di-O-benzyl-2-deoxy-1-thio-α-D-glucopyranoside	1380218-20-1	C₅₄H₅₆N₆O₈S	949.14
——	(2R,4aR,7R,8R,8aS)-7-azido-8-[(4-methoxyphenyl)methoxy]-6-(4-methylphenyl)sulfanyl-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxine	1426329-44-3	C₂₈H₂₉N₃O₅S	519.621
——	tolyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-mannopyranosyl-(1->4)-2-azido-3,6-di-O-benzyl-2-deoxy-1-thio-α-D-glucopyranoside	1235137-43-5	C₅₄H₅₅N₃O₉S	922.111
——	2-azido-2-deoxy-3,4,6-tri-O-benzyl-D-glucopyranosyl diphenyl phosphate	——	C₃₉H₃₈N₃O₈P	707.72
——	methyl 2,3,6-tri-O-benzyl-4-O-(3,4,6-tri-O-benzyl-2-azido-2-deoxy-β-D-glucopyranosyl)-α-D-glucopyranoside	——	C₅₅H₅₉N₃O₁₀	922.088
——	methyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranosyl-β-(1->4)-2,3-O-isopropylidene-1-α-L-rhamnopyranoside	1380218-16-5	C₃₇H₄₅N₃O₉	675.779
——	methyl 2-azido-3,4,6-tri-O-benzyl-2-deoxy-α-D-glucopyranosyl-(1→4)-2,3-O-isopropylidene-1-α-L-rhamnopyranoside	1380218-15-4	C₃₇H₄₅N₃O₉	675.779
——	methyl-6-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-2,3,4-tri-O-benzyl-α-D-glucopyranoside	——	C₅₅H₅₉N₃O₁₀	922.088
——	methyl 2-azido-3,4,5-tri-O-benzyl-2-deoxy-D-glucopyranosyl-β-(1->2)-3,4,6-tri-O-benzyl-α-D-mannopyranoside	1380218-18-7	C₅₅H₅₉N₃O₁₀	922.088
——	2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-glucopyranosyl trichloroacetimidate	220688-25-5	C₂₉H₂₉Cl₃N₄O₅	619.932

反应信息

作为反应物：

描述：

4-methylphenyl 3,4,6-tri-O-acetyl-2-azido-2-deoxy-1-thio-α,β-D-glucopyranoside 在 N-溴代丁二酰亚胺(NBS) 、 sodium methylate 作用下，以