methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside | 87326-88-3

分子结构分类

有机化合物 - 有机氧化合物

中文名称

——

中文别名

——

英文名称

methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside

英文别名

(2S,3S,4S,5R,6S)-2-(iodomethyl)-6-methoxy-4,5-bis(phenylmethoxy)oxan-3-ol

methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside化学式

CAS

87326-88-3

化学式

C₂₁H₂₅IO₅

mdl

——

分子量

484.331

InChiKey

GHZVXYINUSPEPM-ADAARDCZSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

3.2
重原子数：

27
可旋转键数：

8
环数：

3.0
sp3杂化的碳原子比例：

0.43
拓扑面积：

57.2
氢给体数：

1
氢受体数：

5

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	Methyl-4-O-acetyl-2,3-di-O-benzyl-6-desoxy-6-iod-α-D-glucopyranosid	87326-89-4	C₂₃H₂₇IO₆	526.368
2,3-二-o-苄基-alpha-d-吡喃葡萄糖苷甲酯	methyl 2,3-di-O-benzyl-α-D-glucopyranoside	17791-36-5	C₂₁H₂₆O₆	374.434
——	methyl 2,3-di-O-benzyl-4,6-O-isopropylidene-α-D-glucopyranoside	76491-08-2	C₂₄H₃₀O₆	414.499
——	methyl 2,3-O-dibenzyl-4,6-O-benzylidene-α-D-glucopyranoside	——	C₂₈H₃₀O₆	462.543
——	4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside	3162-96-7	C₁₄H₁₈O₆	282.293
——	methyl 2,3-di-O-benzyl-6-O-tosyl-α-D-glucopyranoside	54522-57-5	C₂₈H₃₂O₈S	528.623
——	methyl 4,6-O-isopropylidene-α-D-glucopyranoside	15354-29-7	C₁₀H₁₈O₆	234.249
——	methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranoside	87326-90-7	C₂₃H₂₆O₆	398.456
alpha-甲基葡萄糖甙	methyl-alpha-D-glucopyranoside	97-30-3	C₇H₁₄O₆	194.185

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	Methyl-4-O-acetyl-2,3-di-O-benzyl-6-desoxy-6-iod-α-D-glucopyranosid	87326-89-4	C₂₃H₂₇IO₆	526.368
——	methyl 6-deoxy-2,3-bis-O-(phenylmethyl)-α-D-glucopyranoside	56750-58-4	C₂₁H₂₆O₅	358.434
2,3-二-o-苄基-alpha-d-吡喃葡萄糖苷甲酯	methyl 2,3-di-O-benzyl-α-D-glucopyranoside	17791-36-5	C₂₁H₂₆O₆	374.434
——	methyl 2,3-di-O-benzyl-β-L-idopyranoside	87392-25-4	C₂₁H₂₆O₆	374.434
——	methyl 2,3-O-dibenzyl-6-deoxy-4-O-methyl-α-D-glucopyranoside	7045-41-2	C₂₂H₂₈O₅	372.461
——	methyl 4-O-benzoyl-2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside	309263-32-9	C₂₈H₂₉IO₆	588.439
——	methyl 2,3-di-O-benzyl-4-O-crotonyl-6-deoxy-6-iodo-α-D-glucopyranoside	250687-50-4	C₂₅H₂₉IO₆	552.406
——	((2S,3S,4R,5R,6S)-4,5-Bis-benzyloxy-2-iodomethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-triethyl-silane	347897-51-2	C₂₇H₃₉IO₅Si	598.594
——	((2S,3S,4R,5R,6S)-4,5-Bis-benzyloxy-2-iodomethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-tert-butyl-dimethyl-silane	347897-50-1	C₂₇H₃₉IO₅Si	598.594
——	methyl 2,3-di-O-benzyl-6-deoxy-4-O-[(S)-3-methylpentanoyl]-α-D-glucopyranoside	——	C₂₇H₃₆O₆	456.579
——	methyl 2,3-di-O-benzyl-4-O-crotonyl-6-deoxy-α-D-glucopyranoside	250687-53-7	C₂₅H₃₀O₆	426.51
——	methyl 2,3-di-O-benzyl-6-deoxy-4-O-[(R)-3-methyl-4-pentenoyl]-α-D-glucopyranoside	250687-61-7	C₂₇H₃₄O₆	454.563
——	methyl (methyl 2,3-di-O-benzyl-β-L-idopyranosid)uronate	87326-95-2	C₂₂H₂₆O₇	402.444
——	2,2-Dimethyl-propionic acid (2S,3S,4R,5S,6S)-6-allyl-4,5-bis-benzyloxy-2-iodomethyl-tetrahydro-pyran-3-yl ester	440339-69-5	C₂₈H₃₅IO₅	578.487
——	methyl 4-O-benzoyl-2,3-di-O-benzyl-6-O-trityl-β-L-idopyranoside	87326-92-9	C₄₇H₄₄O₇	720.862
——	2,2-Dimethyl-propionic acid (2S,3S,4S,5R)-4,5-bis-benzyloxy-2-iodomethyl-6-oxo-tetrahydro-pyran-3-yl ester	440339-68-4	C₂₅H₂₉IO₆	552.406
——	1D-(1,3/2,4)-1,2-di-O-benzyl-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol	127213-12-1	C₂₅H₃₀O₅	410.51
——	(3S,4S,5R,6S)-4,5-Bis-benzyloxy-6-methoxy-2-methylene-tetrahydro-pyran-3-ol	116386-41-5	C₂₁H₂₄O₅	356.419
——	methyl 2,3-di-O-benzyl-4-O-allyl-6-deoxy-α-D-xylo-hex-5-enopyranoside	681222-90-2	C₂₄H₂₈O₅	396.483
——	(2S,3R,4S,5R)-3,4-bis(benzyloxy)-5-vinyltetrahydrofuran-2-ol	607403-61-2	C₂₀H₂₂O₄	326.392
——	methyl 2,3,4-tri-O-benzyl-α-d-xylo-hex-5-enopyranoside	85716-44-5	C₂₈H₃₀O₅	446.543
——	(2S,3R,4S,5S)-3,4-Bis-benzyloxy-5-(2-iodo-benzyloxy)-2-methoxy-6-methylene-tetrahydro-pyran	194800-88-9	C₂₈H₂₉IO₅	572.44
——	1D-(1,3/2,4)-3-O-acetyl-1,2-di-O-benzyl-4-O-tetrahydropyranyl-5-cyclohexene-1,2,3,4-tetrol	122777-37-1	C₂₇H₃₂O₆	452.547
——	methyl 4-O-acetyl-2,3-di-O-benzyl-6-deoxy-α-D-xylo-hex-5-enopyranoside	87326-90-7	C₂₃H₂₆O₆	398.456
——	methyl 2,3-di-O-benzyl-4-O-(4-methoxybenzyl)-6-deoxy-α-D-xylo-hex-5-enopyranoside	1197981-32-0	C₂₉H₃₂O₆	476.569
甲基 6-脱氧吡喃己糖苷	methyl 6-deoxy-α-D-glucopyranoside	5155-43-1	C₇H₁₄O₅	178.185
——	methyl uronate	87907-55-9	C₄₂H₄₇N₃O₁₁	769.849
——	methyl uronate	87326-96-3	C₄₄H₄₉N₃O₁₂	811.886
——	(2S,3S,4R,4aR,6R,7S,8aR)-6-[4-hydroxy-6-[(4-methoxyphenyl)methoxy]hex-2-ynyl]-3,4-bis(phenylmethoxy)-2-prop-2-enyl-2,3,4,4a,6,7,8,8a-octahydropyrano[3,2-b]pyran-7-ol	344315-30-6	C₃₉H₄₆O₈	642.789
——	(2S,3R,4S,5S)-2-allyloxy-3,4-dibenzyloxy-5-methyloxycyclohexanone	681222-98-0	C₂₄H₂₈O₅	396.483

反应信息

作为反应物：

描述：

methyl 2,3-di-O-benzyl-6-deoxy-6-iodo-α-D-glucopyranoside 生成 Methyl-4-O-acetyl-2,3-di-O-benzyl-6-desoxy-6-iod-α-D-glucopyranosid

参考文献：

名称：

CHOAY, J.;JACQUINET, J. -C.;PETITOU, M.;SINAY, P.

摘要：