二环戊烯基丙烯酸酯 | 33791-58-1

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 中文名称: 二环戊烯基丙烯酸酯
• 中文别名: 丙烯酸六氢化-4,7-亚甲基-1H-茚基酯
• 英文名称: 2-Propenoic acid, 3a,4,5,6,7,7a-hexahydro-4,7-methano-1H-indenyl ester
• 英文别名: 8-tricyclo[5.2.1.02,6]dec-3-enyl prop-2-enoate
• CAS: 33791-58-1
• 化学式: C₁₃H₁₆O₂
• 分子量: 204.26
• InChiKey: FUAUEJPEWIQMAI-UHFFFAOYSA-N

物化性质

• 熔点：
  -40℃
• 密度：
  1.07
• 闪点：
  131°(268°F)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• TSCA：
  Yes

反应信息

• 作为反应物：
  描述：

  二环戊烯基丙烯酸酯 、 双氧水 生成 3,4-epoxytricyclo[5.2.1.0(2,6)]dec-8-yl acrylate
  参考文献：
  名称：

  TESHIGAHARA, SATOSHI;KANO, YOSHIAKI, TOSO KEHNKYU XOKOKU, 35,(1991) N, S. 47-56

  摘要：

  DOI：
• 作为产物：
  描述：

  二聚环戊二烯 、 丙烯酸 生成 二环戊烯基丙烯酸酯
  参考文献：
  名称：

  TESHIGAHARA, SATOSHI;KANO, YOSHIAKI, TOSO KEHNKYU XOKOKU, 35,(1991) N, S. 47-56

  摘要：

  DOI：

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Ink composition for inkjet-recording and method for inkjet-recording
  申请人：FUJIFILM Corporation

  公开号：EP1927477A1

  公开（公告）日：2008-06-04

  An ink composition for inkjet-recording, which shows a high sensitivity to irradiation with actinic radiation and is able to form an image with superior curability, permitting the image formed after curing to have sufficient adhesiveness to a recording medium, as well as to have excellent flexibility in the formed image portion, and an inkjet-recording method using the same is provided: wherein the ink composition for inkjet-recording comprises (A) a compound having a polymerizable unsaturated bond and a cyclic amine structure in the molecule, (B) a compound having a polymerizable unsaturated bond and an alicyclic structure in the molecule, and (C) a radical polymerization initiator.

  本发明提供了一种喷墨记录用墨水组合物，该组合物对阳极辐射照射具有高灵敏度，能够形成具有优异固化性的图像，使固化后形成的图像对记录介质具有足够的粘附性，并使形成的图像部分具有优异的柔韧性，还提供了使用该组合物的喷墨记录方法： 其中用于喷墨记录的墨水组合物包括 (A) 分子中具有可聚合不饱和键和环胺结构的化合物，(B) 分子中具有可聚合不饱和键和脂环结构的化合物，以及 (C) 自由基聚合引发剂。
• Ink composition, ink jet recording method, method for producing planographic printing plate, and planographic printing plate
  申请人：FUJIFILM Corporation

  公开号：EP2169020A1

  公开（公告）日：2010-03-31

  The invention provides an ink composition comprising a polymerization initiator, a (meth)acrylate having a double bond with a carbon atom having an sp3 hybrid orbital at an α position, and a colorant; an ink jet recording method using the ink composition; a planographic printing plate obtained by using the ink composition; and a method for producing the planographic printing plate.

  本发明提供了一种油墨组合物，该组合物包含聚合引发剂、具有双键的（甲基）丙烯酸酯（其碳原子在 α 位置具有 sp3 杂化轨道）和着色剂；使用该油墨组合物的喷墨记录方法；使用该油墨组合物获得的平版印刷板；以及生产该平版印刷板的方法。
• PHOTOSENSITIVE COMPOSITION, IMAGE FORMING METHOD, FILM FORMING METHOD, RESIN, IMAGE, AND FILM
  申请人：Fujifilm Corporation

  公开号：EP3342792A1

  公开（公告）日：2018-07-04

  Provided are a photosensitive composition containing a resin which includes a structural unit A represented by Formula (1) or (2) and a structural unit B represented by Formula (3), (4), or (5); and a radically polymerizable monomer, an image forming method, a film forming method, a resin, an image, and a film. R11, R21, R31, R41, and R51 represent H or a hydrocarbon group, R12 to R14 and R22 to R24 represent a hydrocarbon group, H, or an OH group, R42, R43, R52, and R53 represent H or a hydrocarbon group, L1 to L3 represent a single bond or a linking group, X1 represents -O- or -NR15-, X2 represent -O- or -NR25-, R15 and R25 represent H or a hydrocarbon group, and Cy1 represents a hydrocarbon group which may contain O and has a cyclic structure.

  本发明提供了一种光敏组合物，该组合物含有一种树脂，其中包括由式（1）或（2）表示的结构单元 A 和由式（3）、（4）或（5）表示的结构单元 B；以及一种可辐射聚合的单体、一种图像形成方法、一种薄膜形成方法、一种树脂、一种图像和一种薄膜。R11、R21、R31、R41 和 R51 代表 H 或烃基，R12 至 R14 和 R22 至 R24 代表烃基、H 或 OH 基，R42、R43、R52 和 R53 代表 H 或烃基、L1 至 L3 代表单键或连接基团，X1 代表-O-或-NR15-，X2 代表-O-或-NR25-，R15 和 R25 代表 H 或烃基，Cy1 代表可能含有 O 并具有环状结构的烃基。
• PHOTOCURABLE COMPOSITION, CURED PRODUCT, AND DENTAL PRODUCT
  申请人：Mitsui Chemicals, Inc.

  公开号：EP3925994A1

  公开（公告）日：2021-12-22

  A photo-curable composition including a di-(meth)acrylic monomer (A) having two (meth)acryloyloxy groups and two urethane bonds, an acrylic monomer (B) having one acryloyl group, and a photopolymerization initiator, as well as a cured product of the photo-curable composition, and a dental product including the cured product.

  一种光固化组合物，包括具有两个(甲基)丙烯酰氧基和两个聚氨酯键的二(甲基)丙烯酸单体(A)、具有一个丙烯酰基的丙烯酸单体(B)和光聚合引发剂，以及光固化组合物的固化产物和包括固化产物的牙科产品。