1,5-二(2,3-环氧丙氧基)-2,2,3,3,4,4-六氟戊烷 | 4798-39-4

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 烃类卤化物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 1,5-二(2,3-环氧丙氧基)-2,2,3,3,4,4-六氟戊烷
• 英文名称: 2,2,3,3,4,4-hexafluoro-1,5-pentanediol diglycidyl ether
• 英文别名: 1,5-Bis(2,3-epoxypropoxy)-2,2,3,3,4,4-hexafluoropentane；2-[[2,2,3,3,4,4-hexafluoro-5-(oxiran-2-ylmethoxy)pentoxy]methyl]oxirane
• CAS: 4798-39-4
• 化学式: C₁₁H₁₄F₆O₄
• 分子量: 324.22
• InChiKey: OIGSRLUDJHIAPI-UHFFFAOYSA-N

物化性质

• 沸点：
  341.2±42.0 °C(Predicted)
• 密度：
  1.408±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  21
• 可旋转键数：
  10
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  43.5
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,5-二(2,3-环氧丙氧基)-2,2,3,3,4,4-六氟戊烷 以 二甲基亚砜 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  含氟间隔基的新型β-羟基和β-羧基双季铵盐的合成

  摘要：

  描述了其中疏水部分被部分氟化的新的阳离子亲金试剂的合成。这些双季铵盐是由β-羟胺和β-羧胺的甲基碘与季铵盐进行季铵化反应而得，它们是由两种具有足够反应活性的中间体，即ω-ω'二环氧和ω-ω'二溴乙酸酯与二醇反应而合成的，式为HOCH 2（CF 2）3 CH 2 OH。

  DOI：

  10.1016/s0022-1139(98)00266-8
• 作为产物：
  描述：

  2,2,3,3,4,4-六氟环-1,5-戊二醇 、 环氧氯丙烷 在 四丁基硫酸氢铵 sodium hydroxide 作用下， 以 水 为溶剂， 反应 15.0h， 以72%的产率得到1,5-二(2,3-环氧丙氧基)-2,2,3,3,4,4-六氟戊烷
  参考文献：
  名称：

  Synthèse de nouveaux diépoxides hautement fluorés, précurseurs de tensioactifs bolaphiles à espaceur fluoré

  摘要：

  In this paper, we describe the synthesis of new highly fluorinated diepoxides from diols of general formula HOCH2(CF2)(n)CH2OH which are not often used in organic synthesis because of their strong acidity, resulting in poor reactivity towards polyaddition and polycondensation. These highly fluorinated diepoxides are obtained by condensation of these diols with epichlorohydrin, in basic medium and with the phase transfer catalyst, tetrabutylammoniumhydrogenosulfate. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-1139(97)00045-6

文献信息

• Curable composition for photo imprints, method for forming pattern, fine pattern, and method for manufacturing semiconductor device
  申请人：FUJIFILM Corporation

  公开号：US10175576B2

  公开（公告）日：2019-01-08

  Provided is a curable composition for photo imprints excellent in the mold releasability and the ink jettability. The curable composition for photo imprints, comprising: a polymerizable compound (A); a photo-polymerization initiator (B); and a mold releasing agent (C), the mold releasing agent (C) being represented by the formula (I) below. Rf represents a C1-8 fluorine-containing alkyl group having two or more fluorine atoms; m represents 1 or 2; L represents a single bond or divalent linking group; n represents 1 or 2; X represents a single bond, oxygen atom, sulfur atom, or nitrogen atom; R1 represents a C1-8 substituent being free from a polymerizable group; R2 represents a hydrogen atom, C1-8 substituent, or divalent linking group; p represents 1 or 2, q represents 0 or 1, and r represents 1 or 2; R1 and R2 may combine with each other to form a ring.

  本发明提供了一种用于照片印记的固化组合物，该组合物具有优异的脱模性和油墨润湿性。这种用于照片印记的可固化组合物包括：可聚合化合物（A）；光聚合引发剂（B）；和脱模剂（C），脱模剂（C）由下式（I）表示。Rf 代表具有两个或两个以上氟原子的 C1-8 含氟烷基；m 代表 1 或 2；L 代表单键或二价连接基团；n 代表 1 或 2；X 代表单键、氧原子、硫原子或氮原子；R1 代表不含可聚合基团的 C1-8 代基；R2 代表氢原子、C1-8 代基或二价连接基团；p 代表 1 或 2，q 代表 0 或 1，r 代表 1 或 2；R1 和 R2 可相互结合形成一个环。
• INSERTION POLYNORBORNENE-BASED THERMOSET RESINS
  申请人：Transfert Plus, S.E.C.

  公开号：EP3080170B1

  公开（公告）日：2020-02-05
• CURABLE COMPOSITION FOR PHOTO IMPRINTS, METHOD FOR FORMING PATTERN, FINE PATTERN, AND METHOD FOR MANUFACTURING SEMICONDUCTOR DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20150185606A1

  公开（公告）日：2015-07-02

  Provided is a curable composition for photo imprints excellent in the mold releasability and the ink jettability. THe curable composition for photo imprints, comprising: a polymerizable compound (A); a photo-polymerization initiator (B); and a mold releasing agent (C), the mold releasing agent (C) being represented by the formula (I) below. Rf represents a C 1-8 fluorine-containing alkyl group having two or more fluorine atoms; m represents 1 or 2; L represents a single bond or divalent linking group; n represents 1 or 2; X represents a single bond, oxygen atom, sulfur atom, or nitrogen atom; R 1 represents a C 1-8 substituent being free from a polymerizable group; R 2 represents a hydrogen atom, C 1-8 substituent, or divalent linking group; p represents 1 or 2, q represents 0 or 1, and r represents 1 or 2; R 1 and R 2 may combine with each other to form a ring.
• MONODISPERSE LUBRICANT INCLUDING MULTIDENTATE PERFLUOROPOLYETHER STRUCTURES
  申请人：HGST Netherlands B.V.

  公开号：US20160068778A1

  公开（公告）日：2016-03-10

  In one embodiment, a method for forming a substantially monodisperse lubricant includes: providing a plurality of perfluoropolyether (PFPE) precursors, each PFPE precursor including two end segments and a PFPE backbone disposed therebetween; protecting one of the end segments of each PFPE precursor with one or more protecting agents to form a plurality of mono-protected PFPE precursors, each mono-protected PFPE precursor including a protected end segment and an unprotected end segment; and coupling the unprotected end segment of each of the mono-protected PFPE precursors to the unprotected end segment of another of the mono-protected PFPE precursors via a coupling agent to form multidentate PFPE structures. In another embodiment, a substantially monodisperse lubricant includes a plurality of multidentate perfluoropolyether (PFPE) structures, each multidentate PFPE structure including at least two end segments and a middle segment therebetween, wherein the multidentate PFPE structures have a molecular weight that is substantially the same.
• CURABLE COMPOSITION FOR OPTICAL IMPRINTING AND PATTERN FORMING METHOD
  申请人：FUJIFILM Corporation

  公开号：US20160211143A1

  公开（公告）日：2016-07-21

  A curable composition for optical imprinting which is excellent in ink jet adequacy and releasability, a pattern forming method, a fine pattern, and a method for manufacturing a semiconductor device are provided. The curable composition for optical imprinting contains a polymerizable compound (A), a photopolymerization initiator (B), and a compound (C) expressed by General Formula (I); in General Formula (I), A represents a dihydric to hexahydric polyhydric alcohol residue. p represents 0 to 2, q represents 1 to 6, p+q represents an integer of 2 to 6, each of m and n independently represents 0 to 20. r expressed by Formula (1) is 6 to 20. Each R independently represents an alkyl group having 1 to 10 carbon atoms, an aryl group, or an acyl group.