N-silver(I) succinimide | 55047-82-0

• 物质功能分类: 有机原料 - 氨基化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: N-silver(I) succinimide
• 英文别名: N-silver succinimide；silver succinimide；succinimide; silver (I)-compound；Succinimid; Silber(I)-Verbindung；succinimide, silver(1+) salt；Silver;pyrrolidin-1-ide-2,5-dione
• CAS: 55047-82-0
• 化学式: Ag*C₄H₄NO₂
• 分子量: 205.949
• InChiKey: RXWQRLQUJZRVHB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.94
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  52.5
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2925190090

反应信息

• 作为反应物：
  描述：

  N-silver(I) succinimide 在 盐酸 作用下， 生成 丁二酰亚胺
  参考文献：
  名称：

  Landsberg, M., Liebigs Annalen der Chemie, 1882, vol. 215, p. 172 - 213

  摘要：

  DOI：
• 作为产物：
  描述：

  丁二酰亚胺 、 silver nitrate 在 sodium ethanolate 作用下， 以 乙醇 、 二甲基亚砜 为溶剂， 以94%的产率得到N-silver(I) succinimide
  参考文献：
  名称：

  Discovery, synthesis, and evaluation of N-substituted amino-2(5H)-oxazolones as novel insecticides activating nicotinic acetylcholine receptors

  摘要：

  N-Substituted amino-2(5H)-oxazolones A are a novel class of insecticides acting as nicotinic acetylcholine receptor (nAChR) agonists and show potent activity against hemipteran insect species. Here we report the discovery and preparation of this class of chemistry. Our efforts in SAR elucidation, biological activity evaluation, as well as mode-of-action studies are also presented. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.bmcl.2014.03.037
• 作为试剂：
  描述：

  N-苯基-4-吗啉甲醛肟氯化物 在 N-silver(I) succinimide 作用下， 以 乙二醇二甲醚 为溶剂， 生成 N-phenyl-morpholine-4-carboximidic acid [3,3']bipyrrolylidene-2,5,2',5'-tetrayl ester
  参考文献：
  名称：

  Ried,W. et al., Chemische Berichte, 1976, vol. 109, p. 1572 - 1574

  摘要：

  DOI：

文献信息

• Synthesis and Reactivity of N-Heterocyclic Carbene Gold(I) and Gold(III) Imidate Complexes and Their Catalytic Activity in 1,5-Enyne Cycloisomerization
  作者：Jonathan P. Reeds、Adrian C. Whitwood、Mark P. Healy、Ian J. S. Fairlamb

  DOI：10.1021/om400310z

  日期：2013.5.24

  imidate ligands in Au(I) and Au(III) (i.e. [AuBr(NHC)] and [AuBr3(NHC)]) complexes have been investigated. [Au(N-imidate)(NHC)] and [AuBr2(N-imidate)(NHC)] complexes were prepared and the structure and bonding of the complexes examined spectroscopically and crystallographically. The [AuBr2(N-imidate)(NHC)] complexes, in combination with Ag salts, were tested for catalytic activity in the cycloisomerization

  已经研究了用（伪）卤化物取代Au（I）和Au（III）（即[AuBr（NHC）]和[AuBr 3（NHC）]）络合物中阴离子亚氨酸酯配体的作用。制备[Au（N-亚氨酸酯）（NHC）]和[AuBr 2（N-亚氨酸酯）（NHC）]配合物，并通过光谱和晶体学检查该配合物的结构和键合。测试了[AuBr 2（N-亚氨酸盐）（NHC）]配合物与银盐的混合物在1,5-烯炔的环异构化中的催化活性，发现比三溴化物类似物（例如[AuBr 3（（NH​​C）]）。阴离子亚氨酸酯配体结构的细微变化对Au（III）配合物的催化活性产生了显着影响。
• Synthesis and reactivity of a stable crystalline diastereomerically pure trifluoromethanesulfinic acid derivative: (S)-(−)-1-trifluoromethylsulfinyl-(R)-4-phenyloxazolidin-2-one
  作者：Vadim D. Romanenko、Claire Thoumazet、Vincent Lavallo、Fook S. Tham、Guy Bertrand

  DOI：10.1039/b303574c

  日期：——

  Efficient synthesis of the title compound, the first diastereomerically pure trifluoromethanesulfinic acid derivative (8), has been achieved by direct trifluoromethanesulfinylation of the lithiated (4R)-(−)-4-phenyloxazolidin-2-one; in contrast to the reaction between CF3S(O)Cl and (1R,2S,5R)-(−)-menthol which occurs with low stereoselectivity ( 98% de.

  通过锂化 (4R)-(-)-4-phenyloxazolidin-2-one 的直接三氟甲烷亚磺酰化，实现了标题化合物的高效合成，这是第一个非对映异构纯的三氟甲亚磺酸衍生物 (8)；与 CF3S(O)Cl 和 (1R,2S,5R)-(-)-薄荷醇之间的反应相反，该反应以低立体选择性 (98% de.
• Preparation and Reactivity of Tris(trifluoromethylselanyl)carbenium [(CF ₃ Se) ₃ C ⁺ ] and Trifluoromethylsulfanylacetic Acid Derivatives [(CF ₃ S) _{3– <i>n</i>} CX _<i>n</i> (O)R]
  作者：Alois Haas、Guido Möller

  DOI：10.1002/cber.19961291112

  日期：1996.11

  Reaction pathways for the synthesis of the (CF3E)3C moieties (E = Se, S) are described. [(CF3Se)3C+][AsF] was found to be a suitable synthon for the preparation of (CF3Se)3C derivatives. It can be prepared either from (CF3Se)3C derivatives. It can be prepared either from (CF3Se)4C or (CF3Se)3CF and AsF5 in liquid SO2. Direct access to (CF3Se)3CF was realized by the reaction of FCBr3 with Hg(SeCF3)2

  描述了合成（CF 3 E）3 C部分（E = Se，S）的反应途径。发现[（CF 3 Se）3 C + ] [AsF]是用于制备（CF 3 Se）3 C衍生物的合适的合成子。它可以由（CF 3 Se）3 C衍生物制备。它可以由（CF 3 Se）4 C或（CF 3 Se）3 CF和AsF 5在液态SO 2中制备。通过FCBr 3的反应可直接进入（CF 3 Se）3 CF与Hg（SeCF 3）2。的治疗[（CF 3 Se）的3 Ç + ] [ASF 6 - ]与卤化钾提供（CF 3 Se）的3 CX（X = F，氯，溴）。与KI的反应不同，因为形成了CF 3 SeSeCF 3和（CF 3 Se）2 C = C（SeCF 3）2作为主要产物。少量（CF 3 Se）3 CC（SeCF 3）3形成了可以隔离和明确表征的特征。仅两条途径导致三重CF 3 S取代的乙酸酯（CF 3 S）3 CC（O）OR
• Trimethylphosphite stabilized N-silver(I) succinimide complexes as CVD precursors
  作者：Xian Tao、Yu-Long Wang、Ke-Cheng Shen、Ying-Zhong Shen

  DOI：10.1016/j.inoche.2010.10.014

  日期：2011.1

  Abstract The preparation of [(MeO) 3 P n ·AgNC 4 H 4 O 2 ] ( n = 1, 2a ; n = 2, 2b ) is described. The molecular structure of 2a was determined by using X-ray single crystal analysis. Complex 2b was tested as Metal Organic Chemical Vapor Deposition (MOCVD) precursor in the deposition of silver for the first time. The thin films obtained were characterized using scanning electron microscopy (SEM) and

  摘要 描述了[(MeO) 3 P n ·AgNC 4 H 4 O 2 ] (n = 1, 2a ; n = 2, 2b) 的制备。2a 的分子结构是通过 X 射线单晶分析确定的。首次将配合物 2b 作为金属有机化学气相沉积 (MOCVD) 前体用于银沉积。使用扫描电子显微镜 (SEM) 和能量色散 X 射线分析 (EDX) 对获得的薄膜进行表征。SEM和EDX研究表明可以获得致密且均匀的银膜。
• Synthesis of Imido-Substituted 3,8-Diphenyl-1,2-diazacycloocta-2,4,6,8-tetraenes and Their Thermolysis
  作者：Seiichi Yogi、Kozo Hokama、Sadamori Takayoshi、Otohiko Tsuge

  DOI：10.1246/bcsj.60.731

  日期：1987.2

  Nucleophilic substitution of 4,7-dichloro-3,8-diphenyl-1,2-diazocine with succinimide, phthalimide, N-methyl-p-toluenesulfonamide, and o-benzosulfimide, in the presence of silver oxide, gave the corresponding 4-mono(imido)- and 4,7-di(imido)-1,2-diazocines. 4-Acetoxy-7-phthalimido- and 4-phenylthio-7-phthalimido-1,2-diazocine were also prepared. Thermolysis of the mono(imido)-1,2-diazocines in xylene under reflux afforded the corresponding di(imido)-1,2-diazocine and/or five pyridine derivatives, whose relative yields depended upon the nature of imido substitutents in the diazocines. However, 4,7-di(imido)-1,2-diazocines did not decompose in xylene under reflux. Thermolysis of 4,7-bis(phthalimido)-1,2-diazocine at 300–310 °C gave 3,6-bis(phthalimido)-2-phenylpyridine with the extrusion of benzonitrile. In the thermolysis of the acetoxy(230–240 °C) or phenylthio-substituted 1,2-diazocine (240–260 °C), 6-acetoxy- and 6-benzoyl-3-phthalimido-2-phenylpyridine, or 6(and 3)-phenylthio-3(and 6)-phthalimido-2-phenylpyridines were isolated together with benzonitrile, respectively. The feature of thermolysis was also discussed.

  在氧化银存在下，用琥珀酰亚胺、邻苯二甲酰亚胺、N-甲基-对甲苯磺酰胺和邻苯并磺酰亚胺对 4,7-二氯-3,8-二苯基-1,2-重氮辛进行亲核取代，得到相应的 4-单(亚氨基)-和4,7-二(亚氨基)-1,2-二氮辛。还制备了4-乙酰氧基-7-邻苯二甲酰亚胺基-和4-苯硫基-7-邻苯二甲酰亚胺基-1,2-重氮辛。单(亚氨基)-1,2-重氮辛在二甲苯中回流下热解得到相应的二(亚氨基)-1,2-重氮辛和/或五种吡啶衍生物，其相对产率取决于重氮辛中亚氨基取代基的性质。然而，4,7-二(亚氨基)-1,2-重氮辛在二甲苯中回流下不分解。 4,7-双（邻苯二甲酰亚胺）-1,2-重氮辛在 300–310 °C 下热解，并挤出苯甲腈，得到 3,6-双（邻苯二甲酰亚胺）-2-苯基吡啶。在乙酰氧基（230–240°C）或苯硫基取代的1,2-重氮辛（240–260°C）、6-乙酰氧基-和6-苯甲酰基-3-邻苯二甲酰亚胺基-2-苯基吡啶或6(和3)-苯硫基-3(和6)-邻苯二甲酰亚胺基-2-苯基吡啶分别与苯甲腈一起分离。还讨论了热解的特点。