1,1,1,2,3,3-六氟-3-(2,2,3,3,3-五氟丙氧基)丙烷 | 1000-28-8

• 物质功能分类: 有机原料 - 醚类化合物及其衍生物
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1,1,1,2,3,3-六氟-3-(2,2,3,3,3-五氟丙氧基)丙烷
• 中文别名: 1H，1H，2'H-全氟二丙醚
• 英文名称: 1,1,1,2,3,3-hexafluoro-3-(2,2,3,3,3-pentafluoropropoxy)propane
• 英文别名: HFE-54-11mec-f；CF3CF2CH2OCF2CFHCF3；<1,1,2,3,3,3-Hexafluor-propyl>-<2,2,3,3,3-pentafluor-propyl>-aether；(1,1,2,3,3,3-Hexafluor-propyl)-(2,2,3,3,3-pentafluor-propyl)-aether；1H,1H,2'H-Perfluorodipropyl ether
• CAS: 1000-28-8
• 化学式: C₆H₃F₁₁O
• 分子量: 300.072
• InChiKey: JOROOXPAFHWVRW-UHFFFAOYSA-N

物化性质

• 沸点：
  86 °C(Press: 761 Torr)
• 密度：
  1.5844

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  12

安全信息

• 危险等级：
  IRRITANT
• 危险品标志：
  Xi
• 安全说明：
  S26
• 危险类别码：
  R36/37/38
• 海关编码：
  2909199090
• 储存条件：
  应存放在室温、密封和干燥的环境中。

反应信息

• 作为反应物：
  描述：

  1,1,1,2,3,3-六氟-3-(2,2,3,3,3-五氟丙氧基)丙烷 在 硫酸 作用下， 生成 2,3,3,3-Tetrafluor-propionsaeure-<2,2,3,3,3-pentafluor-propylester
  参考文献：
  名称：

  Gubanov,V.A. et al., Journal of general chemistry of the USSR, 1965, vol. 35, p. 399 - 400

  摘要：

  DOI：
• 作为产物：
  描述：

  六氟丙烯 、 2,2,3,3,3-五氟-1-丙醇 在 四(三苯基膦)钯 、 1,4-双(二苯基膦)丁烷 作用下， 以 乙腈 为溶剂， 反应 21.0h， 以86%的产率得到1,1,1,2,3,3-六氟-3-(2,2,3,3,3-五氟丙氧基)丙烷
  参考文献：
  名称：

  钯（0）催化的六氟丙烯加氢烷氧基化：在中性条件下合成氢氟醚。

  摘要：

  DOI：

  10.1002/anie.200462200

文献信息

• HYDROFLUOROACETAL COMPOUNDS AND PROCESSES FOR THEIR PREPARATION AND USE
  申请人：Flynn Richard M.

  公开号：US20090326083A1

  公开（公告）日：2009-12-31

  The present disclosure provides a compound according to the formula: R f 1 [CH(—O—CH (3-m) R f 2 m )(—O—CF 2 —CFH—R f 3 )] n [I] wherein n is 1 or 2, wherein m is 1, 2 or 3, wherein, when n is 1, R f 1 is selected from the group consisting of highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein, when n is 2, R f 1 is selected from the group consisting of highly fluorinated alkylene groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein each R f 2 is independently selected from the group consisting of alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein at least one R f 2 is highly fluorinated; wherein each R f 3 is independently selected from the group consisting of fluorine and highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms. Also provided are methods of use and manufacture of such compounds.

  本公开提供了一种按照式子Rf1[CH(—O—CH(3-m)Rf2m)(—O—CF2—CFH—Rf3)]n[I]的化合物，其中n为1或2，m为1、2或3，当n为1时，Rf1选自高度氟化的线性、支链、环状或其组合的烷基基团，可以选择性地被取代，并且可以选择性地包含一个或多个链合杂原子；当n为2时，Rf1选自高度氟化的线性、支链、环状或其组合的烷基烷基团，可以选择性地被取代，并且可以选择性地包含一个或多个链合杂原子；每个Rf2独立地选自线性、支链、环状或其组合的烷基基团，可以选择性地被取代，并且可以选择性地包含一个或多个链合杂原子；至少一个Rf2高度氟化；每个Rf3独立地选自氟和高度氟化的线性、支链、环状或其组合的烷基基团，可以选择性地被取代，并且可以选择性地包含一个或多个链合杂原子。还提供了这种化合物的使用和制造方法。
• Hydrofluoroacetal compounds and processes for their preparation and use
  申请人：3M Innovative Properties Company

  公开号：US08071816B2

  公开（公告）日：2011-12-06

  The present disclosure provides a compound according to the formula: Rf1[CH(—O—CH(3-m)Rf2m)(—O—CF2—CFH—Rf3)]n   [I] wherein n is 1 or 2, wherein m is 1, 2 or 3, wherein, when n is 1, Rf1 is selected from the group consisting of highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein, when n is 2, Rf1 is selected from the group consisting of highly fluorinated alkylene groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein each Rf2 is independently selected from the group consisting of alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms; wherein at least one Rf2 is highly fluorinated; wherein each Rf3 is independently selected from the group consisting of fluorine and highly fluorinated alkyl groups which are linear, branched, cyclic, or a combination thereof, which may optionally be substituted, and which may optionally contain one or more catenated heteroatoms. Also provided are methods of use and manufacture of such compounds.

  本公开提供了一种化合物，其化学式为：Rf1 [CH（—O—CH（3-m）Rf2m）（—O—CF2—CFH—Rf3）]n [I]，其中n为1或2，m为1、2或3，当n为1时，Rf1选自高度氟化的直链、支链、环状或其组合的烷基基团，可选地取代，并可选地含有一个或多个串联的杂原子；当n为2时，Rf1选自高度氟化的直链、支链、环状或其组合的烷基烷基团，可选地取代，并可选地含有一个或多个串联的杂原子；每个Rf2独立地选自线性、支链、环状或其组合的烷基基团，可选地取代，并可选地含有一个或多个串联的杂原子；至少一个Rf2是高度氟化的；每个Rf3独立地选自氟和高度氟化的直链、支链、环状或其组合的烷基基团，可选地取代，并可选地含有一个或多个串联的杂原子。还提供了使用和制造这种化合物的方法。
• PROCESS FOR PRODUCING SYNTHETIC RESIN FOAM
  申请人：Daikin Industries, Ltd.

  公开号：EP1457506A1

  公开（公告）日：2004-09-15

  A process for producing a synthetic resin foam comprising the step of reacting a polyol with a polyisocyanate compound in the presence of a blowing agent to give a polyurethane or polyisocyanurate foam,    the blowing agent being a mixture of 51-90 wt.% 1,1,1,3,3-pentafluoropropane and 49-10 wt.% 1,1,1,3,3-pentafluorobutane.

  一种生产合成树脂泡沫塑料的工艺，包括以下步骤：在发泡剂存在下，使多元醇与多异氰酸酯化合物反应，生成聚氨酯或多异氰脲酸酯泡沫塑料、 发泡剂为 51-90 重量百分比的 1,1,1,3,3-五氟丙烷和 49-10 重量百分比的 1,1,1,3,3-五氟丁烷的混合物。
• Process for producing synthetic resin foam
  申请人：Shibanuma Takashi

  公开号：US20050043422A1

  公开（公告）日：2005-02-24

  A process for producing a synthetic resin foam comprising the step of reacting a polyol with a polyisocyanate compound in the presence of a blowing agent to give a polyurethane or polyisocyanurate foam, the blowing agent being a mixture of 51-90 wt. % 1,1,1,3,3-pentafluoropropane and 49-10 wt. % 1,1,1,3,3-pentafluorobutane.

  一种生产合成树脂泡沫塑料的工艺，包括以下步骤：在发泡剂存在下，使多元醇与多异氰酸酯化合物反应，生成聚氨酯或多异氰脲酸酯泡沫塑料，发泡剂为51-90 wt.%的1,1,1,3,3-五氟丙烷和49-10 wt.%的1,1,1,3,3-五氟丁烷的混合物。
• Fluoropolymer nanoemulsions
  申请人：Chen Wei

  公开号：US20080108749A1

  公开（公告）日：2008-05-08

  This invention teaches novel fluoropolymer nanoemulsion products and process. The fluoropolymer nanoemulsions comprise at least 20% by weight of colloidal fluoropolymer nano-particles with average diameter in the range of 1 to 150 nanometer, 0.1% to 3.0% by weight of halogenated dispersing agents selected from fluoro surfactants, chlorofluoro surfactants, hydrofluoro surfactants, or hydrochlorofluoro surfactants, and any CFC (chlorofluorocarbon) or HFC (hydrofluorocarbon) or any HCFC (hydrochlorofluorocarbon) or any CC (chlorocarbon) was mostly removed from the nanoemulsion to be less than 0.5% by weight of the nanoemulsion.