(2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-Amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoic acid | 123083-98-7
中文名称
——
中文别名
——
英文名称
(2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-Amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoic acid
英文别名
(2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-amino-2,5-dimethoxyphenyl)-7-[tert-butyl(dimethyl)silyl]oxy-11,12,15-trimethoxy-2,6,8,10,14-pentamethylpentadeca-2,4,8-trienoic acid
CAS
123083-98-7
化学式
C37H63NO8Si
mdl
——
分子量
677.995
InChiKey
DGYQIBKIMPUWMC-RFGSJVKESA-N
BEILSTEIN
——
EINECS
——
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物化性质
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计算性质
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ADMET
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安全信息
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SDS
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制备方法与用途
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上下游信息
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文献信息
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表征谱图
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同类化合物
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相关功能分类
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相关结构分类
计算性质
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辛醇/水分配系数(LogP)：8.23
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重原子数：47
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可旋转键数：20
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环数：1.0
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sp3杂化的碳原子比例：0.65
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拓扑面积：119
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氢给体数：2
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氢受体数：9
上下游信息
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上游原料
中文名称 英文名称 CAS号 化学式 分子量 —— Methyl (2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoate 138694-29-8 C38H65NO8Si 692.021 —— Methyl (2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-7-(tert-Butyldimethylsiloxy)-15-(2,5-dimethoxy-3-nitrophenyl)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoate 138694-28-7 C38H63NO10Si 722.004 —— (2R,3R,4E,6S,7R,8S,10S,11R)-<(tert-Butyldimethylsilyl)oxy>-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,8,11-tetramethoxy-N,2,4,6,10-pentamethyl-4-undecenal 138694-27-6 C32H55NO9Si 625.875 —— (2R,3R,4E,6S,7R,8S,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-N,7,8,11-tetramethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 138721-96-7 C34H60N2O10Si 684.943 —— (2R,3R,4E,6S,7R,8S,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 138694-26-5 C33H58N2O10Si 670.916 —— (2Z,4S,5R,6E,8S,9R,10S,12S,13R)-5-tert-butyldimethylsilyloxy-13-<3'-(2'',5''-dimethylpyrrol-1''-yl)-2',5'-dimethoxy-phenyl>-9,10,13-trimethoxy-4,6,8,12-tetramethyl-2,6-tridecadien-1-ol 123115-02-6 C40H67NO7Si 702.06 —— (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-oxo-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 138694-25-4 C33H56N2O10Si 668.901 4-十一碳烯酰胺,11-(2,5-二甲氧基-3-硝基苯基)-3-[[(1,1-二甲基乙基)二甲基甲硅烷基]氧代]-8-羟基-N,7,11-三甲氧基-N,2,4,6,10-五甲基-9-[(2-硫代-3-噻唑烷基)羰基]- (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-9-<(2-thioxo-3-thiazolidinyl)carbonyl>-4-undecenamide 138721-95-6 C37H61N3O11S2Si 816.122 —— (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-8-oxo-9-<(2-thioxo-3-thiazolidinyl)carbonyl>-4-undecenamide 1026339-86-5 C37H59N3O11S2Si 814.106 -
下游产品
中文名称 英文名称 CAS号 化学式 分子量 —— (4E,6Z,8S,9R,10E,12S,13R,14S,16S,17R)-9-(tert-Butyldimethylsiloxy)-13,14,17,20,22-pentamethoxy-4,8,10,12,16-pentamethyl-2-azabicyclo<16.3.1>docosa-1(22),4,6,10,18,20-hexaen-3-one 123083-99-8 C37H61NO7Si 659.979 —— (4E,6Z,10E)-(8S,9R,12S,13R,14S,16S,17R)-9-Hydroxy-13,14,17,20,22-pentamethoxy-4,8,10,12,16-pentamethyl-2-aza-bicyclo[16.3.1]docosa-1(21),4,6,10,18(22),19-hexaen-3-one 123084-00-4 C31H47NO7 545.717 —— (4E,6Z,8S,9R,10E,12S,13R,14S,16S,17R)-9-(tert-Butyldimethylsiloxy)-13,14,17-trimethoxy-4,8,10,12,16-pentamethyl-2-azabicyclo<16.3.1>docosa-4,6,10,18,21-pentaene-3,20,22-trione 123084-02-6 C35H55NO7Si 629.91
反应信息
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作为反应物：描述：(2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-Amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoic acid 在 ammonium cerium(IV) nitrate 、 四丁基氟化铵 、 双(2-氧代-3-恶唑烷基)次磷酰氯 、 N,N-二异丙基乙胺 、 三氟乙酸 作用下， 以 四氢呋喃 、 二氯甲烷 、