1,3,5-三(4-硝基苯氧基)苯 | 102852-91-5

• 物质功能分类: 有机原料 - 烃类化合物及其衍生物 - 芳香烃
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,3,5-三(4-硝基苯氧基)苯
• 英文名称: 1,3,5-tris(4'-nitrophenoxy)benzene
• 英文别名: 1,3,5-Tris(4-nitrophenoxy)benzene
• CAS: 102852-91-5
• 化学式: C₂₄H₁₅N₃O₉
• 分子量: 489.398
• InChiKey: DXYUVOVIDRJKFE-UHFFFAOYSA-N

物化性质

• 熔点：
  203-204 °C(Solv: chloroform (67-66-3); hexane (110-54-3))
• 沸点：
  615.9±55.0 °C(Predicted)
• 密度：
  1.453±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  165
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  1,3,5-三(4-硝基苯氧基)苯 在 palladium on carbon 氢气 作用下， 以 乙酸乙酯 、 1,2-二氯乙烷 为溶剂， 反应 37.0h， 生成 1,3,5-tris(4-(3-octylureido)phenoxy)benzene
  参考文献：
  名称：

  EP2332906

  摘要：

  公开号：
• 作为产物：
  描述：

  间苯三酚 、 4-fluoro-4-nitrobenzene 在 potassium carbonate 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 18.0h， 以87%的产率得到1,3,5-三(4-硝基苯氧基)苯
  参考文献：
  名称：

  多价可光交联的含香豆素的聚苯并恶嗪，具有增强的热和疏水表面性能†

  摘要：

  在这项研究中，通过4-甲基-7-羟基香豆素和多聚甲醛分别与苯胺，双酚A-NH 2和1,3,5-三（4-氨基苯）在1,4-二恶烷中共存。1 H和13C核磁共振（NMR），傅立叶变换红外（FTIR）和高分辨率质谱支持这三种苯并恶嗪单体的化学结构。使用差示扫描量热法（DSC）和FTIR光谱研究单，双和三香豆素BZ的香豆素单元的固化聚合行为和光二聚化（[2π+2π]环加成）以形成聚（单香豆素） BZ），聚（香豆素BZ）和聚（三香豆素BZ）。DSC测量表明，含香豆素的苯并恶嗪单体的热聚合温度低于模型化合物3-苯基-3,4-二氢-2 H的热聚合温度。-苯并恶嗪（263°C），其归因于香豆素部分的催化作用和香豆素单元中的强吸电子共轭电子C C键。另外，聚（三香豆素BZ）的玻璃化转变温度和热分解温度（T g = 240°C; T d5= 370°C）高于聚（双香豆素BZ）和聚（单香豆素BZ），这与前者较高

  DOI：

  10.1039/c5ra27705a

文献信息

• Multi-armed, TEMPO-functionalized unimolecular initiators for starburst dendrimer synthesis via stable free radical polymerisation. 2. Tris (1,3,5)benzyloxy unimers
  作者：Mohmad Asri Abd Ghani、Dalia Abdallah、Peter M Kazmaier、Barkev Keoshkerian、Erwin Buncel

  DOI：10.1139/v04-106

  日期：2004.9.1

  The synthesis of the trifunctionalized TEMPO-modified unimolecular initiators, unimers I, II, and III is described. Unimer I was prepared via an S_N2 type Williamson ether coupling of 1,3,5-tris(iodomethyl)benzene with a TEMPO-containing ethylbenzene hydroxy derivative. The synthesis of unimer II, however, was accomplished through S_N1 reaction of 1,3,5-tris(bromomethyl)benzene with the hydroxy-ethylbenzene TEMPO derivative in the presence of silver triflate. Synthesis of unimer III started from phloroglucinol and an S_NAr reaction with 1-fluoro-4-nitrobenzene, followed by reduction to the amino compound and Schiff base formation with the TEMPO-derivatized aromatic aldehyde. Stable free radical polymerisation (SFRP) of styrene and acetoxystyrene with unimer I are also described with molecular weights and polydispersities reported. It is concluded that the SFRP of styrene with a triradical initiator meets the requirements of a living system.Key words: stable free radical polymerisation, starburst dendrimer, multi-armed unimolecular initiators.

  描述了三官能TEMPO修饰的单分子引发剂unimers I、II和III的合成。通过1,3,5-三(iodomethyl)苯与含有TEMPO的乙基苯羟基衍生物进行SN2型Williamson醚偶联来制备Unimer I。然而，Unimer II的合成是通过1,3,5-三(bromomethyl)苯与含有羟基乙基苯TEMPO衍生物在三氟乙酸银存在下进行SN1反应实现的。Unimer III的合成始于phloroglucinol和与1-氟-4-硝基苯进行SNAr反应，随后还原为氨基化合物并与TEMPO衍生的芳香醛形成席夫碱。还描述了使用Unimer I对苯乙烯和乙酰氧基苯乙烯进行稳定自由基聚合（SFRP），并报告了分子量和多分散性。总结认为，使用三重自由基引发剂对苯乙烯进行SFRP符合活性体系的要求。关键词：稳定自由基聚合，星芒状树脂，多臂单分子引发剂。
• Multi-armed, TEMPO-functionalized unimolecular initiators for starburst dendrimer synthesis via stable free radical polymerization. 1. Tri azo-functionalized unimer
  作者：Dalia Abdallah、Mohmad Asri Abd Ghani、Michael F Cunningham、Peter M Kazmaier、Barkev Keoshkerian、Erwin Buncel

  DOI：10.1139/v04-107

  日期：2004.9.1

  The synthesis of azobenzene-functionalized multi-armed unimolecular initiators or "unimers" that can be polymerized using styrene or styrenic derivatives via TEMPO (2,2,6,6-tetramethylpiperidenyl-1-oxyl) mediated stable free radical polymerization (SFRP) is described. The unimers are composed of an azobenzene-functionalized core and a TEMPO-modified unit. Homopolymers and copolymers of styrene and acetoxystyrene were synthesized using the mono-and trifunctionalized unimers as initiators under bulk conditions with average molecular weights and polydispersities reported. The studies lay the groundwork for further investigations involving SFRP towards building a light harvesting system by introducing chromophores onto the polymer chains for capturing light and thence transferring it to the azobenzene core.Key words: azo-functionalized unimolecular initiator, stable free radical polymerization, starburst dendrimer.

  描述了合成偶氮苯官能化的多臂单分子引发剂或“unimers”，可以使用苯乙烯或苯乙烯衍生物通过TEMPO（2,2,6,6-四甲基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-氧基-1-
• Molecular balloon, Pd₆L₈ cages: recognition of alkyl sulfate surfactants
  作者：Haeri Lee、Dongwon Kim、Hyejin Oh、Ok-Sang Jung

  DOI：10.1039/c9cc09742b

  日期：——

  The unique molecular balloon system of [Pd6L8](NO3)12 (an inner cavity of 19 × 21 × 25 Å3 ⇄ 13 × 13 × 13 Å3) was carried out via the anion exchange of nitrate with alkyl sulfates.

  通过硝酸盐与烷基硫酸盐的阴离子交换，实现了[Pd6L8]（NO3）12（内腔19×21×25Å3×13×13×13Å3）的独特分子气球系统。
• TERMINALLY MODIFIED POLYBRANCHED POLYIMIDE, METAL-PLATED TERMINALLY MODIFIED POLYBRANCHED POLYIMIDE, AND METHOD FOR PRODUCING THE SAME
  申请人：Ataka Kikuo

  公开号：US20100009206A1

  公开（公告）日：2010-01-14

  A terminally-modified polybranched polyimide which can be efficiently complexed with an inorganic material is obtained by reacting a component (a): tetracarboxylic dianhydride; a component (b): as an amine component, a mixture of a triamine and a diamine (which may be composed of a triamine only); and a component (c): as a terminal component, a compound selected from general formulae (1-1) to (1-4). H 2 N—X—R 1 (1-1) (In the formula, X represents a single bond or an alkylene group having 1 to 3 carbon atoms, and R 1 represents a nitrogen-containing heterocyclic group). H 2 N—X—R 1 (1-2) (In the formula, X is as defined above, and R 1 represents a sulfur-containing heterocyclic group or an aryl group having a thiol or thioether group in the molecule). (In the formula, R represents a nitrogen-containing heterocyclic group). (In the formula, R represents a monovalent residue).

  通过反应组分(a):四羧酸二酐;组分(b):作为胺组分，三胺和二胺的混合物(可以仅由三胺组成);以及组分(c):作为末端组分，从通式(1-1)到(1-4)中选择的化合物，可以获得与无机材料高效络合的终止修饰的多支化聚酰亚胺。 H2N-X-R1(1-1)(式中，X表示单键或具有1到3个碳原子的烷基基团，R1表示含氮杂环基团)。 H2N-X-R1(1-2)(式中，X如上定义，R1表示含硫杂环基团或分子中具有巯基或硫醚基团的芳基基团)。 (式中，R表示含氮杂环基团)。 (式中，R表示单价残基)。
• Terminally modified polybranched polyimide, metal-plated terminally modified polybranched polyimide, and method for producing the same
  申请人：Ube Industries, Ltd.

  公开号：US08093349B2

  公开（公告）日：2012-01-10

  A terminally-modified polybranched polyimide which can be efficiently complexed with an inorganic material is obtained by reacting a component (a): tetracarboxylic dianhydride; a component (b): as an amine component, a mixture of a triamine and a diamine (which may be composed of a triamine only); and a component (c): as a terminal component, a compound selected from general formulae (1-1) to (1-4). H2N—X—R1  (1-1) (In the formula, X represents a single bond or an alkylene group having 1 to 3 carbon atoms, and R1 represents a nitrogen-containing heterocyclic group). H2N—X—R1  (1-2) (In the formula, X is as defined above, and R1 represents a sulfur-containing heterocyclic group or an aryl group having a thiol or thioether group in the molecule.) (In the formula, R represents a nitrogen-containing heterocyclic group.) (In the formula, R represents a monovalent residue.)

  通过反应组分(a)：四羧基二酸酐；组分(b)：作为胺组分，三胺和二胺的混合物（可以仅由三胺组成）；以及组分(c)：作为末端组分，从通式（1-1）到（1-4）中选择的化合物，可以获得可以有效地与无机材料配合的末端修饰的多支化聚酰亚胺。(在公式中，X表示单键或具有1至3个碳原子的烷基基团，R1表示含氮杂环基团)。H2N—X—R1  (1-1)(在公式中，X如上定义，R1表示含硫杂环基团或分子中具有巯基或硫醚基团的芳基基团。)(在公式中，R表示含氮杂环基团。)(在公式中，R表示一价残基。)