3,9-二乙基-3',9'-二羟甲基-1,5,7,11-四氧杂螺环[5,5]十一烷 | 65282-19-1

• 物质功能分类: 有机原料 - 杂环化合物
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 3,9-二乙基-3',9'-二羟甲基-1,5,7,11-四氧杂螺环[5,5]十一烷
• 英文名称: 3,9-diethyl-3,9-dihydroxymethyl-1,5,7,11-tetraoxaspiro[5,5]undecane
• 英文别名: (3,9-Diethyl-1,5,7,11-tetraoxaspiro[5.5]undecane-3,9-diyl)dimethanol；[3,9-diethyl-3-(hydroxymethyl)-1,5,7,11-tetraoxaspiro[5.5]undecan-9-yl]methanol
• CAS: 65282-19-1
• 化学式: C₁₃H₂₄O₆
• 分子量: 276.33
• InChiKey: SCNCJKBJMHZKSF-UHFFFAOYSA-N

物化性质

• 沸点：
  367.5±37.0 °C(Predicted)
• 密度：
  1.21±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3,9-二乙基-3',9'-二羟甲基-1,5,7,11-四氧杂螺环[5,5]十一烷 以 吡啶 、 环己烷 、 丙酸酐 为溶剂， 以71.1%的产率得到3,9-diethyl-3,9-dipropionyloxymethyl-1,5,7,11-tetraoxaspiro[5.5]undecane
  参考文献：
  名称：

  Polymeric compositions and composites prepared from spiroorthocarbonates

  摘要：

  提供了聚合物组合物，其为螺环正碳酸酯和环氧树脂的反应产物，并经历了减少的体积聚合收缩。螺环正碳酸酯的一般式为：##STR1## 其中 X=O或S；R.sub.1和R.sub.2分别从H、烷基、芳基、取代烷基和取代芳基组成的群体中独立选择；R.sub.3和R.sub.4=--(CH.sub.2).sub.n--O--R.sub.5；n=1或2；R.sub.5=烷基、芳基、取代芳基、取代烷基、##STR2## R.sub.6=H、烷基、芳基、取代烷基或取代芳基；R.sub.7=烷基、芳基、取代烷基或取代芳基。

  公开号：

  US05808108A1
• 作为产物：
  描述：

  三羟甲基丙烷 在 zinc diacetate 、 尿素 、 potassium hydroxide 作用下， 140.0~215.0 ℃ 、6.67 kPa 条件下， 以42%的产率得到3-乙基-3-氧杂丁环甲醇
  参考文献：
  名称：

  Urea as an Efficient Reagent for the Synthesis of 3-Ethyl-3-(hydroxymethyl)oxetane:  A Novel Component in Cationic Ring-Opening Polymerisation

  摘要：

  Urea is a very attractive chemical raw material for large-scale production as it combines low cost with virtually unlimited supply and essentially no toxic effects. Here, we present a study on its use in the dehydration of trimethylolpropane with formation of 3-ethyl-3-(hydroxymethyl)oxetane. The reaction consists of carbonylation of trimethylolpropane and subsequent extrusion of carbon dioxide. The first step was run at a temperature of 120-160 degreesC at a pressure of approximately 300 mmHg for 1-5 h. Most likely, carbamates of TMP constitute the major product. In the latter step, the temperature was increased to 195-215 degreesC, the pressure was reduced to 10-50 mmHg, and the final product was isolated by distillation. A spiroorthocarbonate of TMP was formed as an unexpected byproduct. The process has been demonstrated on a multikilograin scale. Toxicological screening revealed 3-ethyl-3-(hydroxymethyl)oxetane to be irritating to eye but not to skin.

  DOI：

  10.1021/op010037j

文献信息

• Photopolymerizable vinyl ether based monomeric formulations and polymerizable compositions which may include certain novel spiroorthocarbonates
  申请人：Curators of the University of Missouri

  公开号：US06458865B2

  公开（公告）日：2002-10-01

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供的光聚合物组合物是乙烯醚、包括碘化物盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化物、多元醇和螺环醚碳酸酯。本发明的一个实施例是由乙烯醚、螺环醚碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一个实施例是由乙烯醚、环氧化物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一个实施例是由乙烯醚、环氧化物、多元醇、螺环醚碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一个实施例是某些新型螺环醚碳酸酯化合物。这些新型螺环醚碳酸酯化合物中的每一个都包括至少一个环氧基团作为取代基。
• PHOTOPOLYMERIZABLE VINYL ETHER BASED MONOMERIC FORMULATIONS AND POLYMERIZABLE COMPOSITIONS WHICH MAY INCLUDE CERTAIN NOVEL SPIROORTHOCARBONATES
  申请人：——

  公开号：US20020013380A1

  公开（公告）日：2002-01-31

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组合物，其为乙烯醚、包括碘化物盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化合物、多元醇、螺环正交碳酸酯。本发明的一种实施例是由乙烯醚、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正交碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施例是某些新型螺环正交碳酸酯化合物。这些新型螺环正交碳酸酯化合物中，每个化合物都包括至少一个环氧基团作为取代基。
• Novel spiroorthocarbonates
  申请人：The Curators of the University of Missouri

  公开号：US20030119931A1

  公开（公告）日：2003-06-26

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光固化组合物，它们是乙烯醚、包含碘鎓盐、可见光敏化剂和电子供体化合物的光引发剂体系的反应产物。这些单体/低聚物组合物还可以包括环氧化物、多元醇、螺内酯碳酸酯。本发明的一种实施方式是由乙烯醚、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施方式是由乙烯醚、环氧化物、多元醇、螺内酯碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施方式是一些新型螺内酯碳酸酯化合物。这些新型螺内酯碳酸酯化合物中的每一种都包括至少一个环氧基团作为取代基。
• Polymeric crosslinkable compositions containing spiroorthocarbonates
  申请人：——

  公开号：US20040059067A1

  公开（公告）日：2004-03-25

  Polymeric compositions containing spiroorthocarbonate groups and another functional group which reacts with hydroxyl groups are readily crosslinked on contact with water. These compositions are useful as sealants, coatings and encapsulants.

  含有螺环正碳酸酯基团和另一种与羟基反应的功能基团的聚合物组合物在接触水时能够快速交联。这些组合物可用作密封剂、涂料和封装材料。
• Spiroorthocarbonates containing epoxy groups
  申请人：Curators of the University of Missouri

  公开号：US06653486B2

  公开（公告）日：2003-11-25

  Photopolymerizable compositions are provided which are the reaction products of a vinyl ether, a photoinitiator system comprising an iodonium salt, a visible light sensitizer, and an electron donor compound. These monomeric/oligomeric compositions may also include epoxides, polyols, spiroorthocarbonates. One embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, a spiroorthocarbonate, and a photoinitiator system. Another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, and a photoinitiator system. Still another embodiment of the present invention is a polymerizable composition comprised of a vinyl ether, an epoxide, a polyol, a spiroorthocarbonate, and a photoinitiator system. Still further, another embodiment of the present invention is certain novel spiroorthocarbonate compounds. Each of these novel spiroorthocarbonate compounds include at least one epoxy group as a substituent.

  提供了光聚合组合物，其是乙烯醚、含碘盐的光引发剂体系、可见光敏化剂和电子给体化合物的反应产物。这些单体/低聚物组合物还可以包括环氧化合物、多元醇、螺环正碳酸酯。本发明的一种实施例是由乙烯醚、螺环正碳酸酯和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇和光引发剂体系组成的聚合物组合物。本发明的另一种实施例是由乙烯醚、环氧化合物、多元醇、螺环正碳酸酯和光引发剂体系组成的聚合物组合物。此外，本发明的另一种实施例是某些新型螺环正碳酸酯化合物。这些新型螺环正碳酸酯化合物中，每个都包括至少一个环氧基团作为取代基。