甲基九氟丁醚 | 163702-07-6

• 物质功能分类: 有机原料 - 有机氟化合物 - 氟丙烷系列
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 甲基九氟丁醚
• 中文别名: 全氟丁基甲基醚
• 英文名称: nonafluorobutyl methyl ether
• 英文别名: methyl perfluorobutyl ether；methyl nonafluorobutyl ether；nonafluoro-n-butyl methyl ether；1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxybutane；Novec 7100；Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-methoxy-
• CAS: 163702-07-6
• 化学式: C₅H₃F₉O
• mdl: MFCD00674093
• 分子量: 250.064
• InChiKey: OKIYQFLILPKULA-UHFFFAOYSA-N

物化性质

• 熔点：
  -135 °C (lit.)
• 沸点：
  60 °C (lit.)
• 密度：
  1.529 g/mL at 20 °C 1.52 g/mL at 25 °C (lit.)
• 闪点：
  -18℃
• LogP：
  4.670 (est)
• 物理描述：
  Liquid
• 大气OH速率常数：
  7.20e-15 cm3/molecule*sec

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  10

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S23,S24/25
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  29091990
• 储存条件：
  室温

SDS

Methyl Nonafluorobutyl Ether Revision number: 5
SAFETY DATA SHEET

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Section 1. IDENTIFICATION
Product name: Methyl Nonafluorobutyl Ether

Revision number: 5

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Section 2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDS Not classified
Not classified
HEALTH HAZARDS
ENVIRONMENTAL HAZARDS Not classified
GHS label elements, including precautionary statements
Pictograms or hazard symbols None
No signal word
Signal word
Hazard statements None
None
Precautionary statements:

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Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture: Substance
Components: Methyl Nonafluorobutyl Ether
Percent: >98.0%(GC)
CAS Number: 163702-07-6
Synonyms: Methyl Perfluorobutyl Ether , Nonafluorobutyl Methyl Ether , Perfluorobutyl Methyl
Ether
C5H3F9O
Chemical Formula:

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Section 4. FIRST AID MEASURES
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical advice/attention if you feel unwell.
Skin contact: Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation or rash occurs: Get medical advice/attention.
Eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion: Get medical advice/attention if you feel unwell. Rinse mouth.
A rescuer should wear personal protective equipment, such as rubber gloves and air-
Protection of first-aiders:
tight goggles.

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Section 5. FIRE-FIGHTING MEASURES
Suitable extinguishing Dry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
from the chemical: generate poisonous fume.
Methyl Nonafluorobutyl Ether

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Section 5. FIRE-FIGHTING MEASURES
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protective When extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

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Section 6. ACCIDENTAL RELEASE MEASURES
Use personal protective equipment. Keep people away from and upwind of spill/leak.
Personal precautions,
protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
emergency procedures: around the leakage area by roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Absorb spilled material in a suitable absorbent (e.g. rag, dry sand, earth, saw-dust).
containment and cleaning In case of large amount of spillage, contain a spill by bunding. Adhered or collected
up: material should be promptly disposed of, in accordance with appropriate laws and
regulations.

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Section 7. HANDLING AND STORAGE
Precautions for safe handling
Technical measures: Handling is performed in a well ventilated place. Wear suitable protective equipment.
Prevent generation of vapour or mist. Wash hands and face thoroughly after
handling.
Use a ventilation, local exhaust if vapour or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Storage conditions: Keep container tightly closed. Store in a cool and dark place.
Store away from incompatible materials such as oxidizing agents.
Packaging material: Comply with laws.

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Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Install a closed system or local exhaust as possible so that workers should not be
Engineering controls:
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Vapor respirator. Follow local and national regulations.
Hand protection: Protective gloves.
Eye protection: Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

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Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C): Liquid
Form: Clear
Colorless - Almost colorless
Colour:
Odour: No data available
pH: No data available
Melting point/freezing point:No data available
No data available
Boiling point/range:
Flash point: No data available
Flammability or explosive
limits:
No data available
Lower:
Upper: No data available
1.53
Relative density:
Solubility(ies):
No data available
[Water]
[Other solvents] No data available
Methyl Nonafluorobutyl Ether

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Section 10. STABILITY AND REACTIVITY
Chemical stability: Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride
products:

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Section 11. TOXICOLOGICAL INFORMATION
Acute Toxicity: No data available
Skin corrosion/irritation: No data available
Serious eye No data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
IARC = No data available
No data available
NTP =
Reproductive toxicity: No data available

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Section 12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: No data available
Crustacea: No data available
Algae: No data available
Persistence / degradability: No data available
Bioaccumulative No data available
potential(BCF):
Mobility in soil
No data available
Log Pow:
Soil adsorption (Koc): No data available
Henry's Law No data available
constant(PaM3/mol):

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Section 13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. Observe all federal, state and local
regulations when disposing of the substance.

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Section 14. TRANSPORT INFORMATION
Hazards Class: Does not correspond to the classification standard of the United Nations
Not listed
UN-No:

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Section 15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.
Methyl Nonafluorobutyl Ether

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

简介

九氟丁基甲醚是一种无色澄清且无味的液体物质，专门用以替代氟利昂等对臭氧层有破坏作用的物质。该产品在新型的氟氯化碳取代物产品家族中具有最低毒性，在8小时平均工作时间内的时间加权平均限制浓度为750ppm。

应用

甲基九氟丁醚主要应用于精密电子仪器和医疗设备的清洗剂及溶剂，用于替代CFC-113、三氯乙烷、四氯化碳等。

反应信息

• 作为反应物：
  描述：

  甲基九氟丁醚 、 Methoxyperfluorobutane 生成 C4F9OCH3 perfluorobutyl methyl ether
  参考文献：
  名称：

  Fluorinated ketones as lubricant deposition solvents for magnetic media applications

  摘要：

  描述了一种润滑剂组合物，其中包括全氟聚醚润滑剂和氟酮溶剂。该润滑剂组合物可以涂覆在磁性介质等基底上。在涂层干燥后，薄而均匀的润滑膜覆盖在基底表面。氟酮溶剂可以溶解广泛的全氟聚醚化合物，但不能溶解潜在的污染物，如水和碳氢化合物。此外，该溶剂对全球变暖的不良影响潜力较低。

  公开号：

  US06403149B1
• 作为产物：
  描述：

  甲醚 、 七氟丁酰氟 在 silver fluoride 、 水 作用下， 反应 60.0h， 以81.8%的产率得到甲基九氟丁醚
  参考文献：
  名称：

  含氟醚的制备方法

  摘要：

  本发明涉及“含氟醚的制备方法”，属于化学合成领域。该方法在腈类溶剂的条件下，以碳酰氟、三氟乙酰氟、五氟丙酰氟、七氟正丁酰氟、七氟异丁酰氟等酰氟为原料，与金属氟化物发生加成反应得到全氟醇盐，然后在水催化作用下，全氟醇盐与低毒甚至无毒无害的烷基化试剂发生烷基化反应得到含氟醚。本发明方法不仅反应条件温和、含氟醚收率高，而且低毒甚至无毒无害的试剂作为安全的烷基化试剂，工艺安全可靠，在工业上可通过普通的蒸馏手段进行有效分离。

  公开号：

  CN110002968B
• 作为试剂：
  描述：

  1,4-bis(allyloxy)-1H,1H,4H,4H-perfluorobutane 在 溴 、 甲基九氟丁醚 作用下， 反应 12.0h， 以72.2%的产率得到1-(allyloxy)-4-(2,3-dibromopropoxy)-1H,1H,4H,4H-perfluorobutane
  参考文献：
  名称：

  지문 방지용 플로오로실리콘 화합물 및 이의 제조 방법

  摘要：

  本发明涉及一种指纹防止用氟硅化合物及其制备方法，具体来说，涉及以分子两端取代有氢基的氟代烷基或全氟代聚合物化合物作为起始物质的指纹防止用氟硅化合物及其制备方法。根据本发明的化合物表示为下列化学式9。化学式9：

  公开号：

  KR20180014678A

文献信息

• 一种全氟丁基甲醚的制备方法
  申请人：浙江巨圣氟化学有限公司

  公开号：CN107382678B

  公开（公告）日：2020-12-18

  本发明公开了一种全氟丁基甲醚的制备方法，向七氟异丁烯基甲醚和溶剂的混合物中通入氟氮混合气进行反应，反应温度为‑50～10℃，当氟气与七氟异丁烯基甲醚摩尔比为0.5‑1：1时停止通入氟氮混合气，继续反应5‑20分钟，升温到室温，脱除尾气，将反应液精馏得到全氟丁基甲醚产品。本发明具有工艺简单、收率高、成本低的优点。
• Perfluoroalkyl haloalkyl ethers and compositions and applications thereof
  申请人：3M Innovative Properties Company

  公开号：US06653512B1

  公开（公告）日：2003-11-25

  Described are compositions comprising perfluoroalkyl haloalkyl ethers and, optionally, surfactant; uses for perfluoroalkyl haloalkyl ether compounds and compositions thereof, optionally comprising surfactant; and perfluoroalkyl haloalkyl ethers.

  本文描述了包含全氟烷基卤代醚和（可选）表面活性剂的组合物；使用全氟烷基卤代醚化合物及其组合物（可选包含表面活性剂）的用途；以及全氟烷基卤代醚。
• Kinetics and mechanism of gas-phase reactions of n-C4F9OCH3, i-C4F9OCH3, n-C4F9OC(O)H, and i-C4F9OC(O)H with OH radicals in an environmental reaction chamber at 253–328K
  作者：L. Chen、T. Uchimaru、S. Kutsuna、K. Tokuhashi、A. Sekiya

  DOI：10.1016/j.cplett.2011.08.049

  日期：2011.10

  The rate constants of the reactions of n-C4F9OCH3 (k1), i-C4F9OCH3 (k2), n-C4F9OC(O)H (k3), and i-C4F9OC(O)H (k4) with OH radicals were studied in an 11.5-dm3 environmental reaction chamber. k1 and k2 were determined to be (1.44 ± 0.33) × 10–12 exp[–(1450 ± 70)/T] and (1.59 ± 0.41) × 10–12 exp[–(1470 ± 80)/T] cm3 molecule–1 s–1 at 253–328 K. At 298 K, k3 and k4 were deduced to be (1.71 ± 0.32) × 10–14

  的反应的速率常数Ñ -C 4 ˚F 9 OCH 3（ķ 1），我-C 4 ˚F 9 OCH 3（ķ 2），Ñ -C 4 ˚F 9 OC（O）H（ķ 3），和在11.5dm 3的环境反应室内研究了带有OH自由基的i -C 4 F 9 OC（O）H（k 4）。k 1和k 2被确定为（1.44±0.33）×10 –12 exp [–（1450±70）/ T ]和（1.59±0.41）×10 –12 exp [–（1470±80）/ T ] cm 3 分子–1  s –1在253–328K。在298 K时，k 3和k 4被推导为（1.71±0.32）×10 –14和（1.67±0.19）×10 –14  cm 3 分子–1  s –1。n -C 4 F 9 OCH 3与OH基反应的观察产物为n-C 4 F 9 OC（O）H，CF 3 CF 2 CF 2 C（O）F和COF 2以及用于i -C 4 F
• Cleaning process and composition
  申请人：3M Innovative Properties Company

  公开号：US20010044404A1

  公开（公告）日：2001-11-22

  A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.

  一种用于从基板表面去除污染物的过程，包括将基板与至少一种单烷氧基，双烷氧基或三烷氧基取代的全氟烷，全氟环烷烃，含全氟环烷基的全氟烷，或含全氟环烷基的全氟烷基化合物的清洁组合物接触，该化合物可选地含有额外的链状杂原子。这些化合物具有良好的溶解性能，同时符合环保要求。
• Use of fluorinated ketones in fire extinguishing compositions
  申请人：3M Innovative Properties Company

  公开号：US20030089877A1

  公开（公告）日：2003-05-15

  Fire extinguishing compositions and methods for extinguishing, controlling, or preventing fires are described wherein the extinguishing agent is a fluorinated ketone having up to two hydrogen atoms, alone, or in admixture with a co-extinguishing agent selected from hydrofluorocarbons, hydrochlorofluorocarbons, perfluorocarbons, perfluoropolyethers, hydrofluoroethers, hydrofluoropolyethers, chlorofluorocarbons, bromofluorocarbons, bromochlorofluorocarbons, iodofluorocarbons, hydrobromofluorocarbons, and mixtures thereof.

  本文描述了用于灭火、控制或预防火灾的灭火剂组合物和方法，其中灭火剂是一种含有最多两个氢原子的氟酮，单独使用或与一种共同灭火剂混合使用，所述共同灭火剂包括氢氟碳化物、氯氟碳化物、全氟碳化物、全氟聚醚、氢氟醚、氢氟聚醚、氯氟碳化氢、溴氟碳化氢、溴氯氟碳化氢、碘氟碳化氢、氢溴氟碳化氢和其混合物。