3',4',5,7-tetramethyldihydroquercetin-3-yl neopentylene phosphite | 737758-21-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 异黄酮类化合物
• 英文名称: 3',4',5,7-tetramethyldihydroquercetin-3-yl neopentylene phosphite
• CAS: 737758-21-3
• 化学式: C₂₄H₂₉O₉P
• 分子量: 492.463
• InChiKey: MRRSNVFDEKSRNI-PKTZIBPZSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.72
• 重原子数：
  34.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  90.91
• 氢给体数：
  0.0
• 氢受体数：
  9.0

反应信息

• 作为反应物：
  描述：

  3',4',5,7-tetramethyldihydroquercetin-3-yl neopentylene phosphite 在 selenium 作用下， 以 苯 为溶剂， 反应 8.0h， 以95%的产率得到O-3',4',5,7-tetramethyldihydroquercetin-3-yl O,O'-neopentylene phosphoroselenoate
  参考文献：
  名称：

  Phosphorylation of 3',4',5,7-Tetramethyldihydroquercetin

  摘要：

  3',4',5,7-Tetramethyldihydroquercetin was phosphorylated with phosphorous acid derivatives, and similar results were obtained with phosphorochloridites and phosphoramidites. The P-III derivatives obtained were subjected to oxidation. The structures of the products were determined by NMR spectroscopy.

  DOI：

  10.1023/b:rugc.0000018642.90774.a1
• 作为产物：
  描述：

  2-氯-5,5-二甲基-1,3,2-二氧磷杂环己烷 、 3',4',5,7-tetramethyldihydroquercetin 在 三乙胺 作用下， 以 苯 为溶剂， 反应 2.0h， 以70%的产率得到3',4',5,7-tetramethyldihydroquercetin-3-yl neopentylene phosphite
  参考文献：
  名称：

  Phosphorylation of 3',4',5,7-Tetramethyldihydroquercetin

  摘要：

  3',4',5,7-Tetramethyldihydroquercetin was phosphorylated with phosphorous acid derivatives, and similar results were obtained with phosphorochloridites and phosphoramidites. The P-III derivatives obtained were subjected to oxidation. The structures of the products were determined by NMR spectroscopy.

  DOI：

  10.1023/b:rugc.0000018642.90774.a1