7H-dibenzo[b,kl]acridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7H-dibenzo[b,kl]acridine
• 英文别名: 12-Azapentacyclo[11.7.1.02,11.04,9.017,21]henicosa-1(20),2,4,6,8,10,13,15,17(21),18-decaene；12-azapentacyclo[11.7.1.02,11.04,9.017,21]henicosa-1(20),2,4,6,8,10,13,15,17(21),18-decaene
• 化学式: C₂₀H₁₃N
• 分子量: 267.33
• InChiKey: VHYZJALXKMYCJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(4-bromophenyl)-4-(pyridin-3-yl)benzofuro[3,2-d]pyrimidine 、 7H-dibenzo[b,kl]acridine 在 potassium phosphate 、 二(三叔丁基膦)钯 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 以74 %的产率得到2-[4-(12-Azapentacyclo[11.7.1.02,11.04,9.017,21]henicosa-1(20),2,4,6,8,10,13,15,17(21),18-decaen-12-yl)phenyl]-4-pyridin-3-yl-[1]benzofuro[3,2-d]pyrimidine
  参考文献：
  名称：

  Compound and organic light emitting diode comprising same

  摘要：

  Provided is a compound of Chemical Formula 1: wherein: R1 to R4 are each independently hydrogen, or groups adjacent to each other can bond to form a substituted or unsubstituted monocyclic or polycyclic ring; L is a direct bond or a substituted or unsubstituted arylene group; and Ar is Chemical Formula D: wherein: Y1 to Y5 each independently is N or CR; at least one of Y1 to Y5 is N; R is hydrogen, deuterium, a halogen group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and adjacent Rs can bond to each other to form a substituted or unsubstituted ring; and when R is two or more, the Rs are the same as or different from each other, and an organic light emitting device comprising the same.

  公开号：

  US11812658B2
• 作为产物：
  描述：

  1,8-二氨基萘 在 四(三苯基膦)钯 吡啶 、 盐酸 、 三溴化硼 、 sodium carbonate 、 一水合肼 、 sodium nitrite 作用下， 以 乙二醇二甲醚 、 二氯甲烷 为溶剂， 反应 115.0h， 生成 7H-dibenzo[b,kl]acridine
  参考文献：
  名称：

  2,8′-Disubstituted-1,1′-Binaphthyls: A New Pattern in Chiral Ligands

  摘要：

  The title binaphthyls 19 and 26, which are the positional isomers of 2-methoxy-2'-(diphenylphosphino)-1,1'-binaphthyl (MOP, 19) and 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN, 26), have been synthesized by Suzuki coupling as the key step (10 + 15 --> 18), followed by functional group transformations, involving C-P and C-N bond formation (18 --> 19 and 18 --> 23). Racemic intermediate 22 was resolved by co-crystallization with N-benzylcinchonidinium chloride and the absolute configuration determined by X-ray crystallography. These novel binaphthyls are configurationally stable and, as such, potentially usable as chiral ligands in asymmetric reactions. Michael addition of the glycine-derived enolate 40 to methyl acrylate, carried out in the presence of (R)-(-)-27 as the chiral phase-transfer catalyst, afforded L-glutamic acid (S)-(+)-43 of 92% ee (after hydrolysis of the primary product).

  DOI：

  10.1002/1521-3765(20021018)8:20<4633::aid-chem4633>3.0.co;2-n

文献信息

• Compound for organic electronic element, organic electronic element using same, and electronic device comprising same
  申请人：Duk San Neolux Co., Ltd.

  公开号：US10297758B2

  公开（公告）日：2019-05-21

  The purpose of the present invention is to provide a compound that can improve the lifespan, low drive voltage and high luminous efficiency of an element, an organic electronic element using same, and an electronic device comprising same.

  本发明的目的是提供一种可提高元件寿命、低驱动电压和高发光效率的化合物、使用该化合物的有机电子元件以及包含该化合物的电子设备。
• COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME, AND ELECTRONIC DEVICE COMPRISING SAME
  申请人：Duk San Neolux Co., Ltd.

  公开号：US20170141311A1

  公开（公告）日：2017-05-18

  The purpose of the present invention is to provide a compound that can improve the lifespan, low drive voltage and high luminous efficiency of an element, an organic electronic element using same, and an electronic device comprising same.
• Compound For Organic Electronic Element, Organic Electronic Element Using Same, And Electronic Device Comprising Same
  申请人：DUK SAN NEOLUX CO., LTD

  公开号：US20190157560A1

  公开（公告）日：2019-05-23

  The purpose of the present invention is to provide a compound that can improve the lifespan, low drive voltage and high luminous efficiency of an element, an organic electronic element using same, and an electronic device comprising same.
• COMPOUND AND ORGANIC LIGHT EMITTING DIODE COMPRISING SAME
  申请人：LG CHEM, LTD.

  公开号：US20210036236A1

  公开（公告）日：2021-02-04

  Provided is a compound of Chemical Formula 1: wherein: R1 to R4 are each independently hydrogen, or groups adjacent to each other can bond to form a substituted or unsubstituted monocyclic or polycyclic ring; L is a direct bond or a substituted or unsubstituted arylene group; and Ar is Chemical Formula D: wherein: Y1 to Y5 each independently is N or CR; at least one of Y1 to Y5 is N; R is hydrogen, deuterium, a halogen group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heteroaryl group, and adjacent Rs can bond to each other to form a substituted or unsubstituted ring; and when R is two or more, the Rs are the same as or different from each other, and an organic light emitting device comprising the same.
• [EN] COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME, AND ELECTRONIC DEVICE COMPRISING SAME<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRONIQUE ORGANIQUE, ÉLÉMENT ÉLECTRONIQUE ORGANIQUE AYANT RECOURS À CE COMPOSÉ, ET DISPOSITIF ÉLECTRONIQUE COMPORTANT CET ÉLÉMENT<br/>[KO] 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2016003202A2

  公开（公告）日：2016-01-07

  본 발명은 소자의 높은 발광효율, 낮은 구동전압 및 수명을 향상시킬 수 있는 화합물, 이를 이용한 유기전기소자 및 그 전자장치를 제공하는 것을 목적으로 한다.