(+/-) menthyl laurate | 861357-50-8

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (+/-) menthyl laurate
• 英文别名: (-)-Menthyl laurate；(5-methyl-2-propan-2-ylcyclohexyl) dodecanoate
• CAS: 861357-50-8
• 化学式: C₂₂H₄₂O₂
• 分子量: 338.574
• InChiKey: DKFFWVHIJZJJCM-UHFFFAOYSA-N

物化性质

• 沸点：
  379.1±10.0 °C(Predicted)
• 密度：
  0.8915 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  24
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (+/-) menthyl laurate 在 Lipase MY 异丁醇 作用下， 以 正庚烷 为溶剂， 反应 360.0h， 以45%的产率得到L-薄荷醇
  参考文献：
  名称：

  脂肪酶催化的反应和解决酒精的策略

  摘要：

  用假丝酵母念珠菌脂肪酶进行不对称水解，酯交换和酯形成以用于薄荷醇拆分。该反应是在乳化条件下用水溶性酶和在有机介质中用不溶酶制剂实现的。在后一种情况下，观察到对映选择性的增强。讨论了酯交换和酯形成用于制备醇的拆分反应的潜力。

  DOI：

  10.1016/s0040-4039(00)83931-3
• 作为产物：
  描述：

  月桂酰氯 、 L-薄荷醇 生成 (+/-) menthyl laurate
  参考文献：
  名称：

  Brauns, Journal of the American Chemical Society, 1920, vol. 42, p. 1480

  摘要：

  DOI：

文献信息

• ESSENTIAL OIL DERIVATIVES, THEIR PREPARATION AND USES
  申请人：GASPERONI Giovanni

  公开号：US20180265804A1

  公开（公告）日：2018-09-20

  Compounds are described which are derivatives of essential oils, functionalized in order to improve their antibacterial, antiprotozoal and antiviral activity, reduce their volatility and modify their solubility in certain solvents, particularly water. Additionally, also the palatability has been significantly improved with respect to the starting essential oils. These compounds are designed 5 to be used as food ingredients in food products for nutritional purposes and extra-nutritional (as prebiotics) purposes, in both human and animal feed industries, even if these compounds can be successfully used also in cosmetics, detergents and for the control of the microbial load in general.

  描述了一些衍生自精油的化合物，经过官能化以提高其抗菌、抗原虫和抗病毒活性，降低其挥发性并改变其在特定溶剂中（尤其是水中）的溶解性。此外，相较于起始精油，这些化合物的口感也得到了显著改善。这些化合物被设计用作食品中的食品成分，用于营养目的和额外营养（作为益生元）目的，无论是在人类还是动物饲料行业中，即使这些化合物也可以成功用于化妆品、洗涤剂和一般微生物负载控制。
• Process for the preparation of L-menthol
  申请人：——

  公开号：US20020182674A1

  公开（公告）日：2002-12-05

  L-Menthol is prepared from D,L-menthyl derivatives by enantioselective enzymatic cleavage.

  L-Menthol 由 D,L-薄荷衍生物通过对映选择性酶裂解制备而成。
• US6706500B2
  申请人：——

  公开号：US6706500B2

  公开（公告）日：2004-03-16
• [EN] ESSENTIAL OIL DERIVATIVES, THEIR PREPARATION AND USES<br/>[FR] DÉRIVÉS D'HUILES ESSENTIELLES, LEUR PRÉPARATION ET LEURS UTILISATIONS
  申请人：VOLARE & CONNECTING LLC

  公开号：WO2016185249A1

  公开（公告）日：2016-11-24

  Compounds are described which are derivatives of essential oils, functionalized in order to improve their antibacterial, antiprotozoal and antiviral activity, reduce their volatility and modify their solubility in certain solvents, particularly water. Additionally, also the palatability has been significantly improved with respect to the starting essential oils. These compounds are designed 5 to be used as food ingredients in food products for nutritional purposes and extra-nutritional (as prebiotics) purposes, in both human and animal feed industries, even if these compounds can be successfully used also in cosmetics, detergents and for the control of the microbial load in general.
• Brauns, Journal of the American Chemical Society, 1920, vol. 42, p. 1480
  作者：Brauns

  DOI：——

  日期：——