erbium(III) acetate tetrahydrate | 15280-57-6

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: erbium(III) acetate tetrahydrate
• 英文别名: Erbium(3+);acetate;hydrate
• CAS: 15280-57-6
• 化学式: 3C₂H₃O₂*Er*4H₂O
• 分子量: 416.455
• InChiKey: OMFORKHAHKQQER-UHFFFAOYSA-M

物化性质

• 熔点：
  >300°C
• 密度：
  2,11 g/cm3
• 溶解度：
  溶于H2O
• 稳定性/保质期：

  在常温常压下稳定，需避免与水分、潮湿、氧化物、酸及二氧化碳接触。其相对密度为1.611，在25℃时，每100克水中可溶解10.37克的无水物。该物质不溶于乙醚，仅难溶于热乙醇。

计算性质

• 辛醇/水分配系数(LogP)：
  -2.07
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  41.1
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• TSCA：
  Yes
• WGK Germany：
  3
• 储存条件：
  请将产品存放在常温环境下，密闭避光且保持干燥通风。

SDS

---

Section 1: Product Identification
Chemical Name: Erbium (III) acetate hydrate (99.9%-Er) (REO)
CAS Registry Number: 15280-57-6
Formula: Er(OOCCH3)3.XH2O
EINECS Number: none
Chemical Family: metal acetate salt
Synonym: Acetic acid, erbium(+3) salt, hydrate

---

Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 15280-57-6 100% no data no data

---

Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Ingestion
Eye Contact: Causes slight to mild irritation of the eyes.
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: No information on the physiological effects of ingestion.
Acute Health Affects: Irritating to skin, eyes and respiratory tract.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No

---

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Ingestion: Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious).

---

SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

---

SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

---

SECTION 7: Handling and Storage
Handling and Storage: Store in a sealed container. Keep away from heat and moisture.

---

SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

---

SECTION 9: Physical and Chemical Properties
Color and Form: pink xtl.
Molecular Weight: 344.44
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: 2.114
Odor: none
Solubility in Water: soluble

---

SECTION 10: Stability and Reactivity
Stability: air and moisture stable solid
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: Oxidizing agents and active metals
Decomposition Products: Carbon dioxide, carbon monoxide, organic vapors, and metal oxides and carbonates.

---

SECTION 11: Toxicological Information
RTECS Data: No specific information available on this product.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available

---

SECTION 12: Ecological Information
Ecological Information: No information available

---

SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

---

SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

---

SECTION 15: Regulatory Information
TSCA: Not listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

用途：科研试剂、生化研究

生产方法： 取10g氧化铒，溶于500mL 50%的醋酸水中，加热使氧化铒完全溶解。若有不溶物，过滤得清液。再将此水溶液置于75℃水浴中，蒸去大部分水分，待结晶析出后进行过滤收集。将晶体置于装有氢氧化钠和高氯酸镁的真空干燥器中抽真空干燥，即可得到四水醋酸铒。

反应信息

• 作为反应物：
  描述：

  erbium(III) acetate tetrahydrate 以 neat (no solvent) 为溶剂， 反应 12.0h， 生成 erbium(III) acetate
  参考文献：
  名称：

  Yb3Al5O12 承载的 Er3+ 的磁性和光学性质——实验和理论

  摘要：

  摘要 使用最近开发的基于 DFT 平面波代码组合的方法来提取晶体场参数和局部原子，如涉及电子 - 电子，自旋轨道和塞曼项的哈密顿量，我们计算了地面和激发多重态的能级Yb3+ 和 Er3+ 离子存在于镱和钇铝石榴石（YbAG 和 YAG）中，包括它们的晶体和磁场分裂。将获得的能级和衍生的磁特性与来自磁力测定、光致发光和近红外光谱的实验数据进行比较。

  DOI：

  10.1016/j.jallcom.2019.151903
• 作为产物：
  描述：

  erbium(III) oxide 在 acetic acid 作用下， 以 溶剂黄146 为溶剂， 生成 erbium(III) acetate tetrahydrate
  参考文献：
  名称：

  Nadezhdina, G. V.; Ivanov, V. I.; Shubina, V., Zhurnal Obshchei Khimii, 1966, vol. 36, p. 1563 - 1565

  摘要：

  DOI：
• 作为试剂：
  描述：

  6,7-diphenoxynaphthalene-2,3-dicarbonitrile 在 erbium(III) acetate tetrahydrate 作用下， 以47%的产率得到erbium bis[(3,4,12,13,21,22,30,31-octaphenoxy)-2,3-naphthalocyanine]
  参考文献：
  名称：

  Synthesis of new lanthanide naphthalocyanine complexes based on 6,7-bis(phenoxy)-2,3-naphthalodinitrile and their spectral and electrochemical investigation

  摘要：

  首次合成了一些基于 6,7 双（苯氧基）-2,3-萘二甲腈的稀土元素萘酞菁和二萘酞菁配合物，并研究了它们的光谱特性。研究了镥[双(八苯氧基)萘酞菁]在疏水薄膜中的电化学行为。

  DOI：

  10.1007/s11172-008-0258-6

文献信息

• Synthesis, characterization, and antitumor activity of rare earth metal complexes of benzoic acid nitrogen mustard
  作者：Sufeng Zhou、Yun Fu、Xizhi Fan、Yanfang Zhang、Changzheng Li

  DOI：10.1007/s00044-012-0286-5

  日期：2013.6

  Benzoic acid nitrogen mustard and its rare earth metal complexes were synthesized and characterized by elemental analyses, IR, electronic spectrum, and EPR. The interaction of synthesized complexes with Ct-DNA was investigated and reviewed as a mixed manner of both intercalation and alkylation via fluorescence titration. Their biological activities were also evaluated in K562 and Vero cell lines, indicating

  合成了苯甲酸氮芥末及其稀土金属配合物，并通过元素分析，红外，电子光谱和EPR对其进行了表征。合成的复合物与Ct-DNA的相互作用进行了研究，并通过荧光滴定以嵌入和烷基化的混合方式进行了综述。还在K 562和Vero细胞系中评估了它们的生物学活性，表明复合物具有显着的抑制作用。但是，与苯甲酸氮芥末相比，没有协同作用而不是拮抗作用。彗星试验还探讨了通过细胞凋亡的可能机制。
• Helical Metallohost−Guest Complexes via Site-Selective Transmetalation of Homotrinuclear Complexes
  作者：Shigehisa Akine、Takanori Taniguchi、Tatsuya Nabeshima

  DOI：10.1021/ja0646702

  日期：2006.12.1

  process "guest exchange" took place quantitatively when rare earth metals were used as a guest. In the case of alkaline earth metals, selectivity of Ca2+ > Sr2+ > Ba2+ >> Mg2+ was observed. On the other hand, the transmetalation did not take place at all when alkali metals were used for the guest. Accordingly, the trinuclear complex [LZn3]2+ is excellent in discriminating charge of the guest ions. The

  我们设计了一种新型的双 (N2O2) 螯合配体，可在 位点的金属化上提供 C 形 O6 位点。UV-vis 和 1H NMR 滴定清楚地表明，H4L 和醋酸锌 (II) 之间的络合通过高度协同的过程提供了 1:3 络合物 [LZn3]2+。尽管双核金属宿主 [LZn2] 的 O6 识别位点充满了额外的 Zn2+，但 O6 位点可以结合客体离子，同时释放最初结合的 Zn2+。当稀土金属被用作客体时，新的识别过程“客体交换”发生在数量上。在碱土金属的情况下，观察到 Ca2+ > Sr2+ > Ba2+ >> Mg2+ 的选择性。另一方面，当碱金属用作客体时，根本没有发生金属转移。因此，三核络合物 [LZn3]2+ 在区分客体离子的电荷方面非常出色。由此获得的金属宿主-客体复合物具有螺旋结构，螺旋的半径 d 和缠绕角θ取决于客体的大小。La3+ 复合物的 theta 最小（288 度），Sc3+
• Confining Excitation Energy in Er³⁺-Sensitized Upconversion Nanocrystals through Tm³⁺-Mediated Transient Energy Trapping
  作者：Qiushui Chen、Xiaoji Xie、Bolong Huang、Liangliang Liang、Sanyang Han、Zhigao Yi、Yu Wang、Ying Li、Dianyuan Fan、Ling Huang、Xiaogang Liu

  DOI：10.1002/anie.201703012

  日期：2017.6.19

  A new class of lanthanide‐doped upconversion nanoparticles are presented that are without Yb3+ or Nd3+ sensitizers in the host lattice. In erbium‐enriched core–shell NaErF4:Tm (0.5 mol %)@NaYF4 nanoparticles, a high degree of energy migration between Er3+ ions occurs to suppress the effect of concentration quenching upon surface coating. Unlike the conventional Yb3+‐Er3+ system, the Er3+ ion can serve

  提出了一种新型的镧系元素掺杂的上转换纳米粒子，它们在主体晶格中没有Yb 3+或Nd 3+敏化剂。在富含的核壳NaErF 4：Tm（0.5 mol％）@ NaYF 4纳米颗粒中，发生了Er 3+离子之间的高度能量迁移，从而抑制了表面涂层上浓度淬灭的影响。与传统的Yb 3+ -Er 3+系统不同，Er 3+离子既可以用作敏化剂也可以用作活化剂，以实现有效的上转换过程。重要的是，适当掺杂Tm 3+已经证明通过能量俘获进一步增强上转换发光。这使所得的纳米颗粒具有鲜红色（约700倍的增强）和在多个激发波长下均可实现的近红外发光。这是减轻浓度猝灭效应的基本新途径，从而为生物应用中的红色发射上转换纳米探针提供了一种便捷的方法。
• Selective synthesis and spectroscopic properties of alkyl-substituted lanthanide(III) mono-, di-, and triphthalocyanines
  作者：V. E. Pushkarev、M. O. Breusova、E. V. Shulishov、Yu. V. Tomilov

  DOI：10.1007/s11172-006-0081-x

  日期：2005.9

  Methods for the selective synthesis of mono-(RPcLnOAc), di-(RPc2Ln), and triphthalocyanines (RPc3Ln2) of rare-earth metals (Ln = Lu, Er, Eu) from symmetrically substituted 2,3,9,10,16,17,23,24-octaalkylphthalocyanines RPcH2 (R = Et, Bu) were developed. The synthesized complexes were characterized by NMR spectroscopy, mass spectrometry, and electronic absorption spectra. The conditions for 1H NMR spectra

  从对称取代的 2,3,9,10,16 选择性合成稀土金属 (Ln = Lu, Er, Eu) 的单 (RPcLnOAc)、二 (RPc2Ln) 和三酞菁 (RPc3Ln2) 的方法，开发了 17,23,24-八烷基酞菁 RPcH2 (R = Et, Bu)。合成的配合物通过核磁共振光谱、质谱和电子吸收光谱进行表征。优化了 1H NMR 谱记录的条件。发现了改变合成化合物光谱特性的规律，这取决于镧系元素的性质和金属酞菁配合物的平面性。
• Synthesis and investigation of spectral and electrochemical properties of alkyl-substituted planar binuclear phthalocyanine complexes sharing a common naphthalene ring
  作者：Tatiana V. Dubinina、Aleksey V. Ivanov、Natalia E. Borisova、Stanislav A. Trashin、Stanislav I. Gurskiy、Larisa G. Tomilova、Nikolay S. Zefirov

  DOI：10.1016/j.ica.2010.02.011

  日期：2010.5

  -butyl-substituted planar binuclear phthalocyanines sharing a common naphthalene ring with Mg as a central metal were synthesized with high yields and characterized by UV/Vis spectra, luminescence spectra, NMR, electrochemical, and spectroelectrochemical measurements. On the base of these complexes, the metal-free phthalocyanine ligands and the series of binuclear phthalocyanine complexes of rare earth elements

  摘要合成了以Mg为中心金属共用萘环的六叔丁基和十二烷基正丁基取代的平面双核酞菁，并通过UV / Vis光谱，发光光谱，NMR，电化学和光谱电化学表征测量。在这些配合物的基础上，合成了无金属的酞菁配体和一系列稀土元素（REE）双核酞菁配合物。获得的所有化合物均显示三核酞菁具有近855 nm的强烈近红外吸收。通过加入乙二醇作为分解剂，可以实现NMR光谱分辨率的关键提高。氧化过程中的光谱电化学测量显示在709和800 nm处吸光度发生可逆变化。