6,7-diphenoxynaphthalene-2,3-dicarbonitrile | 1220188-63-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6,7-diphenoxynaphthalene-2,3-dicarbonitrile
• 英文别名: 6,7-bis(phenoxy)-2,3-naphthalodinitrile
• CAS: 1220188-63-5
• 化学式: C₂₄H₁₄N₂O₂
• 分子量: 362.387
• InChiKey: WJKSLNSRDQQVFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  66
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6,7-diphenoxynaphthalene-2,3-dicarbonitrile 在 lutetium (III) acetate hydrate 作用下， 以41%的产率得到lutetium bis[(3,4,12,13,21,22,30,31-octaphenoxy)-2,3-naphthalocyanine]
  参考文献：
  名称：

  Synthesis of new lanthanide naphthalocyanine complexes based on 6,7-bis(phenoxy)-2,3-naphthalodinitrile and their spectral and electrochemical investigation

  摘要：

  首次合成了一些基于 6,7 双（苯氧基）-2,3-萘二甲腈的稀土元素萘酞菁和二萘酞菁配合物，并研究了它们的光谱特性。研究了镥[双(八苯氧基)萘酞菁]在疏水薄膜中的电化学行为。

  DOI：

  10.1007/s11172-008-0258-6
• 作为产物：
  描述：

  2,3-二溴-6,7-二氰基萘 、 苯酚 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以64%的产率得到6,7-diphenoxynaphthalene-2,3-dicarbonitrile
  参考文献：
  名称：

  Synthesis of new lanthanide naphthalocyanine complexes based on 6,7-bis(phenoxy)-2,3-naphthalodinitrile and their spectral and electrochemical investigation

  摘要：

  首次合成了一些基于 6,7 双（苯氧基）-2,3-萘二甲腈的稀土元素萘酞菁和二萘酞菁配合物，并研究了它们的光谱特性。研究了镥[双(八苯氧基)萘酞菁]在疏水薄膜中的电化学行为。

  DOI：

  10.1007/s11172-008-0258-6

文献信息

• Novel phenoxy-substituted subphthalocyanines possessing an extended π-system: synthesis and property investigation
  作者：T. V. Dubinina、G. G. Zakirova、M. M. Osipova、E. F. Petrusevich、L. G. Tomilova

  DOI：10.1007/s11172-015-1147-4

  日期：2015.9

  Novel phenoxy-substituted subnaphthalocyanine and binuclear subphthalocyanine were synthesized. Structures of the target compounds were established by 1H NMR spectroscopy and high resolution MALDI-TOF/TOF mass spectrometry. Electronic absorption spectra of the synthesized complexes revealed the bathochromic shift of absorption maximum to the near IR spectral region as compared with subphthalocyanine.

  合成了新型苯氧基取代亚萘酞菁和双核亚萘酞菁。通过 1H NMR 光谱和高分辨率 MALDI-TOF/TOF 质谱确定了目标化合物的结构。与亚酞菁相比，合成复合物的电子吸收光谱显示出吸收最大值向近红外光谱区的浴色转移。
• Red-shifted water dispersible napthalocyanine dyes
  申请人：Vonwiller Charlotte Simone

  公开号：US20070008393A1

  公开（公告）日：2007-01-11

  A naphthalocyanine dye of formula (I) is provided: wherein M is a metal group or is absent; R 1 and R 2 are independently selected from hydrogen or C 1-12 alkoxy; X is selected from O, S or —NH—; Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 , Ar 7 and Ar 8 are selected from phenyl, naphthyl, pyridyl, furanyl, pyrollyl, thiophenyl, each of Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 , Ar 7 and Ar 8 being optionally substituted with 1, 2, 3, 4 or 5 groups, the or each group being independently selected from C 1-12 alkyl, C 1-12 alkoxy, C 1-12 arylalkyl, C 1-12 arylalkoxy, —(OCH 2 CH 2 ) d OR d , cyano, halogen, amino, hydroxyl, thiol, —SR v , —NR u R v , nitro, phenyl, phenoxy, —CO 2 R v , —C(O)R v , —OCOR v , —SO 2 R v , —OSO 2 R v , —NHC(O)R v , —CONR u R v , —CONR u R v , sulfonic acid, sulfonic acid salt and sulfonamide; d is an integer from 2 to 5000; R d is H, C 1-8 alkyl or C(O)C 1-8 alkyl; and R u and R v are independently selected from hydrogen, C 1-12 alkyl, phenyl or phenyl-C 1-8 alkyl. Dyes of this type are especially suitable for use in netpage and Hyperlabel™ systems.
• SUBSTRATE HAVING IR-ABSORBING DYE DISPOSED THEREON
  申请人：Vonwiller Simone Charlotte

  公开号：US20090061179A1

  公开（公告）日：2009-03-05

  A substrate having an IR-absorbing dye disposed thereon. The dye is a naphthalocyanine dye of formula (I): wherein M is a metal group or is absent; R 1 and R 2 are independently selected from the group consisting of: hydrogen and C 1-12 alkoxy; X is selected from the group consisting of: O, S and NH; Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 , Ar 7 and Ar 8 are selected from the group consisting of: phenyl, naphthyl, pyridyl, furanyl, pyrollyl and thiophenyl, each of Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 , Ar 7 and Ar 8 being optionally substituted with 1, 2, 3, 4 or 5 groups, each group being independently selected from the group consisting of: C 1-12 alkyl, C 1-12 alkoxy, C 1-12 arylalkyl, C 1-12 arylalkoxy, (OCH 2 CH 2 ) d OR d , cyano, halogen, amino, hydroxyl, thiol, —SR v , —NR u R v , nitro, phenyl, phenoxy, CO 2 R v , C(O)R v , OCOR v , SO 2 R v , OSO 2 R v , NHC(O)R v , CONR u R v , CONR u R v , sulfonic acid, sulfonic acid salt and sulfonamide; d is an integer from 2 to 5000; R d is H, C 1-8 alkyl or C(O)C 1-8 alkyl; and R u and R v are independently selected from the group consisting of: hydrogen, C 1-12 alkyl, phenyl or phenyl-C 1-8 alkyl; and wherein at least one of Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 , Ar 7 and Ar 8 is substituted with a sulfonic acid or a sulfonic acid salt.
• Method Of Initiating Requested Action Via Substrate Printed With Naphthalocyanine Dye
  申请人：Vonwiller Simone Charlotte

  公开号：US20090284809A1

  公开（公告）日：2009-11-19

  A method of initiating a requested action in a computer system via a printed substrate. The substrate has human-readable information and machine-readable coded data printed thereon. The coded data is indicative of a substrate identity and of a plurality of locations on the substrate. The method comprises the steps of: (a) interacting with the substrate using an optically imaging sensing device; (b) imaging the coded data; (c) generating indicating data in the sensing device using the imaged coded data, the indicating data identifying the substrate identity and a position of the sensing device relative to the substrate; and communicating the indicating data to the computer system so that the computer system can initiate the requested action. The coded data is printed with an ink comprising an IR-absorbing naphthalocyanine dye.
• US7470315B2
  申请人：——

  公开号：US7470315B2

  公开（公告）日：2008-12-30