三异丙氧基镓 | 4452-61-3

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机铋、钴、镨、钆、镓、铱、铼、钇、铽等
• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 三异丙氧基镓
• 英文名称: Gallium (III) isopropoxide
• 英文别名: gallium;propan-2-olate
• CAS: 4452-61-3
• 化学式: C₉H₂₁GaO₃
• 分子量: 246.987
• InChiKey: RLVZHWWAGSWRBR-UHFFFAOYSA-N

物化性质

• 沸点：
  120°C/1.0mm
• 密度：
  1.35
• 闪点：
  120°C/1.0mm

计算性质

• 辛醇/水分配系数(LogP)：
  -1.12
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  69.2
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• TSCA：
  No
• 危险等级：
  4.1
• 海关编码：
  29051220
• 包装等级：
  II
• 危险类别：
  4.1
• 危险品运输编号：
  UN 2925

反应信息

• 作为反应物：
  描述：

  1-acetylferrocenehydrazinecarbothioamide 、 三异丙氧基镓 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Studies on the synthesis, characterization and antimicrobial and antifertility aspects of sulfur donor ligands and their Al(III) and Ga(III) complexes

  摘要：

  The biologically important complexes of aluminium(III) and gallium(III) derived from 1-acetylferrocenehydrazinecarbothioamide ((LH)-H-1) and 1-acetylferrocene carbodithioic acid ((LH)-H-2) were prepared and investigated using a combination of microanalytical analysis, melting point, electronic, infrared, H-1 NMR and C-13 NMR spectral studies along with X-ray powder diffraction studies. Aluminium and gallium isopropoxides interact with the ligands in molar ratios of 1:1, 1:2 and 1:3 (metal: ligand), resulting in the formation of coloured products. The ligands are coordinated to aluminium(III) and gallium(III) via the azomethine nitrogen atom and the thiolic sulfur atom. On the basis of X-ray powder diffraction study, one of the representative gallium(III) complexes was found to have orthorhombic lattice, having the following lattice parameters: a=8.9200, b=14.6000 and c=7.0000. On the basis of the above studies, for the aluminium(III) and gallium(III) complexes, pentacoordinated structure for 1:1 complex and hexacoordinated structure for 1:2 and 1:3 complexes were assigned. The antimicrobial activities of the ligands and complexes were screened in vitro against bacteria Pseudomonas cepacicola and Bacillus substilis and fungi Collectatrichum capsici and Fusarium oxysporum. The complexes have higher activities than the free ligands do. In vivo studies of the ligands and their corresponding complexes have also been carried out to assess their antifertility activity. The results of these activities indicate the antiandrogenic nature of these complexes.

  DOI：

  10.1515/mgmc-2012-0072
• 作为产物：
  描述：

  氢化钇 、 氢化钆 、 铝 、 镓 、 乙酰丙酮 、 在 氩 作用下， 以 乙二醇甲醚 、 1-methoxyethanol 、 乙二醇 为溶剂， 反应 8.0h， 生成 异丙醇钇(III) 、 aluminum isopropoxide 、 三异丙醇钆 、 三异丙氧基镓
  参考文献：
  名称：

  Phosphor Materials

  摘要：

  本发明涉及新的发光材料。具体地，本发明涉及在A2BX4、ABX4-y:M和A3-zB5X12:Mz形式下的磷光材料的发现。更具体地，本发明涉及发现具有物质组成的磷光材料，其形式为Sr2CeO4、(Y0.82Al0.07La0.06)VO4:Eu0.05和(Y0.5Gd0.5)2.97(Al0.5Gd0.5)5O12:Ce0.03。

  公开号：

  US06203726B1

文献信息

• Phosphor materials
  申请人：Symyx Technologies

  公开号：US06013199A1

  公开（公告）日：2000-01-11

  This invention relates generally to new luminescent materials. Specifically, this invention relates to the discovery of phosphor materials in the forms of A.sub.2 BX.sub.4, ABX.sub.4-y :M and A.sub.3-z B.sub.5 X.sub.12 :M.sub.z. More specifically, this invention relates to the discovery of phosphor materials having compositions of matter in the forms, Sr.sub.2 CeO.sub.4, (Y.sub.0.82 Al.sub.0.07 La.sub.0.06)VO.sub.4 :Eu.sub.0.05 and (Y.sub.0.5 Gd.sub.0.5).sub.2.97 (Al.sub.0.5 Ga.sub.0.5).sub.5 O.sub.12 :CeO.sub.0.03.

  本发明涉及新的发光材料。具体而言，本发明涉及发现了以A.sub.2 BX.sub.4，ABX.sub.4-y:M和A.sub.3-z B.sub.5 X.sub.12:M.sub.z形式的磷光材料。更具体地说，本发明涉及发现了具有以下物质组成的磷光材料，即Sr.sub.2 CeO.sub.4，(Y.sub.0.82 Al.sub.0.07 La.sub.0.06)VO.sub.4 :Eu.sub.0.05和(Y.sub.0.5 Gd.sub.0.5).sub.2.97(Al.sub.0.5 Ga.sub.0.5).sub.5 O.sub.12 :CeO.sub.0.03。
• Gallium complexes with polyalcohols and methods of use
  申请人：——

  公开号：US08153687B2

  公开（公告）日：2012-04-10

  Provided are complexes of gallium and polyalcohols. Also provided are pharmaceutical compositions comprising such complexes and methods of their use. Methods of preparing the complexes are also provided.

  提供了镓和多元醇的复合物。还提供了包含这种复合物的药物组合物和使用它们的方法。还提供了制备这些复合物的方法。