过氧化,1,1-二甲基乙基1-甲基乙基 | 15879-99-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 过氧化,1,1-二甲基乙基1-甲基乙基
• 英文名称: Isopropyl-tert-butyl-peroxid
• 英文别名: tert-Butyl-isopropyl-peroxid；Isopropyl-t-butyl-peroxid；Di-tert-butyl-peroxid；2-Methyl-2-[(propan-2-yl)peroxy]propane；2-methyl-2-propan-2-ylperoxypropane
• CAS: 15879-99-9
• 化学式: C₇H₁₆O₂
• 分子量: 132.203
• InChiKey: GXBCWRMJQPLZDU-UHFFFAOYSA-N

物化性质

• 沸点：
  33-34 °C(Press: 10 Torr)
• 密度：
  0.840±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  叔丁基过氧化氢	tert.-butylhydroperoxide	75-91-2	C4H10O2	90.1222
  2-(1-氯乙基过氧)-2-甲基丙烷	α-chloroethyl tert-butyl peroxide	20614-18-0	C6H13ClO2	152.621

反应信息

• 作为反应物：
  描述：

  过氧化,1,1-二甲基乙基1-甲基乙基 在 二-叔-丁基过氧草酸酯 作用下， 反应 32.0h， 生成 丙酮 、 叔丁醇
  参考文献：
  名称：

  Dodonov, V.A.; Zaburdyaeva, S.N., Journal of Organic Chemistry USSR (English Translation), 1986, vol. 22, p. 47 - 49

  摘要：

  DOI：
• 作为产物：
  描述：

  三氟甲磺酸异丙酯 、 tributyl-tert-butylperoxy-stannane 以79%的产率得到过氧化,1,1-二甲基乙基1-甲基乙基
  参考文献：
  名称：

  The peroxide transfer reaction

  摘要：

  DOI：

  10.1021/ja00509a042

文献信息

• RANDOM COPOLYMER FOR FORMING NEUTRAL SURFACE AND METHODS OF MANUFACTURING AND USING THE SAME
  申请人：KANG Min-Hyuck

  公开号：US20120273460A1

  公开（公告）日：2012-11-01

  A random copolymer having a structure represented by the following Formula 1: wherein R is phosphonic acid, Me is a methyl group, x is a number of styrene units, and y is a number of methyl methacrylate units.

  一种随机共聚物的结构式如下所示：式中R为膦酸，Me为甲基，x为苯乙烯单元数，y为甲基丙烯酸甲酯单元数。
• Fluid, stable interpolymer/polyol compositions, process for the production thereof and processes for the production of elastomeric polyurethanes and polyurethane foams therefrom
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0006605A1

  公开（公告）日：1980-01-09

  Fluid, stable polymer-polyols are provided which consist of an organic polyol medium and an interpolymer of a minor amount of polymerized ethylenically unsaturated dicarboxylic acid anhydride, such as maleic acid anhydride, and a major amount of at least one different polymerized ethylenically unsaturated monomer, the interpolymer being in the form of particles that are stably dispersed in the polyol. Polyurethane foams produced from these polymer/ polyols display improved load bearing and compression set when compared with polymer/polyols produced in a similar manner without the ethylenically unsaturated dicarboxylic acid anhydride: elastomers so produced have improved tensile modulus and tear properties.

  提供了流体稳定聚合物多元醇，它由有机多元醇介质和少量聚合乙烯基不饱和二羧酸酐（如马来酸酐）与大量至少一种不同的聚合乙烯基不饱和单体的互聚物组成，互聚物呈颗粒状稳定地分散在多元醇中。与不含乙烯基不饱和二羧酸酐的聚合物/多元醇相比，用这些聚合物/多元醇生产的聚氨酯泡沫塑料的承载能力和压缩永久变形都有所改善：用这种方法生产的弹性体具有更好的拉伸模量和撕裂性能。
• Graft polyester products, method of sizing yarns therewith and a synthetic fiber sized with such graft polyester products
  申请人：BASF WYANDOTTE CORPORATION

  公开号：EP0010582A2

  公开（公告）日：1980-05-14

  There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble. Also disclosed are cross-linked graft polyesters obtained by reacting an unsaturated polyester with at least one polyunsaturated vinyl monomer.

  本发明公开了可用作粘合剂和涂料的接枝聚酯，尤其适用于纺丝和连续长丝合成有机和无机纤维纱线的上浆工艺。本发明的一个实施方案是一种具有游离羧基的纺织品上浆组合物，它是通过对不饱和聚酯反应物和单乙烯基单体反应物的混合物进行加热或辐射而在纺织纱线上就地制备的，不饱和聚酯反应物和单乙烯基单体反应物包括具有至少一个羧基的酸性单乙烯基单体或其与任何单乙烯基单体的混合物。 通过与碱反应，使接枝聚酯具有水分散性或水溶性，从而将尺寸部分中和至 pH 值至少为 6，从而达到退浆的目的。 还公开了通过不饱和聚酯与至少一种多不饱和乙烯基单体反应而获得的交联接枝聚酯。
• Process for preparing cellular foam stabilizer and foam material produced thereby
  申请人：Celotex Corporation

  公开号：EP0070419A2

  公开（公告）日：1983-01-26

  Polyoxyalkylene surfactants for cellular foams can be prepared by reacting a polyoxyalkylene adduct and an esterified unsaturated dibasic acid in the presence of a free-radical initiator.

  用于蜂窝泡沫的聚氧亚烷基表面活性剂可以通过聚氧亚烷基加合物和酯化的不饱和二元酸在自由基引发剂的存在下发生反应来制备。
• Curable mixtures of polyepoxides and amine-terminated graft polymer dispersions
  申请人：BASF WYANDOTTE CORPORATION

  公开号：EP0059369A1

  公开（公告）日：1982-09-08

  Curable mixtures of polyepoxides and amine-terminated polymers are employed. The amine-terminated polymers are prepared by the in situ free radical polymerization of ethylenically unsaturated monomer or monomers in amine-terminated polyoxyalkylene polyether polymers.

  胺封端聚合物是通过乙烯不饱和单体或胺封端聚氧亚烷基聚醚聚合物中的单体原位自由基聚合制备的。