马赛醛 | 67845-30-1

• 物质功能分类: 有机原料 - 醛类化合物
• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 马赛醛
• 中文别名: 6-甲基-8-(1-甲基乙基)双环[2.2.2]辛-5-烯-2-羧醛
• 英文名称: 8-isopropyl-6-methyl-bicyclo[2.2.2]oct-5-ene-2-carbaldehyde
• 英文别名: 5-Methyl-7-isopropyl-bicyclo-[2.2.2]-octen-(5)-aldehyd-(3)；5-Methyl-7-isopropyl-3-formyl-bicyclo-[2.2.2]-octen-(5)；8-Isopropyl-6-methyl-bicyclo[2.2.2]oct-5-en-2-carbaldehyd；5-methyl-7-(1-methylethyl)-bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde；Bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde, 6-methyl-8-(1-methylethyl)-；6-methyl-8-propan-2-ylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde
• CAS: 67845-30-1
• 化学式: C₁₃H₂₀O
• mdl: MFCD24391094
• 分子量: 192.301
• InChiKey: OWFZJSXGDOTWSH-UHFFFAOYSA-N

物化性质

• 沸点：
  262.9±29.0 °C(Predicted)
• 密度：
  0.996±0.06 g/cm3(Predicted)
• LogP：
  3.960 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.769
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• [EN] CLEAVABLE MULTI-ALCOHOL-BASED MICROCAPSULES<br/>[FR] MICROCAPSULES CLIVABLES À BASE D'ALCOOLS MULTIPLES
  申请人：FIRMENICH & CIE

  公开号：WO2021023645A1

  公开（公告）日：2021-02-11

  The present invention relates to a new process for the preparation of microcapsules based on cleavable multi-alcohols. Cleavable multi-alcohol-based microcapsules are also an object of the invention. Perfuming compositions and consumer products comprising said capsules, in particular perfumed consumer products in the form of home care or personal care products, are also part of the invention.

  本发明涉及一种基于可切割多醇制备微胶囊的新工艺。可切割多醇基微胶囊也是本发明的对象。包括这些胶囊的香料组合物和消费品，特别是家居护理或个人护理产品形式的香料消费品，也属于本发明的一部分。
• [EN] IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS AND THEIR USE AS FLAGRANCE INGREDIENTS<br/>[FR] AMÉLIORATIONS DE OU LIÉES À DES COMPOSÉS ORGANIQUES ET LEUR UTILISATION COMME INGRÉDIENTS DE PARFUM
  申请人：GIVAUDAN SA

  公开号：WO2016091895A1

  公开（公告）日：2016-06-16

  A compound represented by the formula (I) wherein (A) is indicating a double bond either at C4 or at C5, or single bonds, R1, R2, R3, R4 are independently selected from H or Me, and R5, R6 are independently selected from Me or Et, and wherein the compound is not 9-hydroxy-5,9-dimethyldec-4-enal or 9-hydroxy-5,9-dimethyldecanal. Said compounds are useful as perfume ingredients in personal care and household care products.

  一种由化学式(I)表示的化合物，其中(A)表示在C4或C5处存在双键，或单键，R1、R2、R3、R4独立地选择自H或Me，R5、R6独立地选择自Me或Et，并且该化合物不是9-羟基-5,9-二甲基癸-4-烯醛或9-羟基-5,9-二甲基癸醛。所述化合物在个人护理和家庭护理产品中作为香料成分是有用的。
• [EN] ENOL ETHER PROPERFUME<br/>[FR] PRO-PARFUM D'ÉTHER ÉNOLIQUE
  申请人：FIRMENICH & CIE

  公开号：WO2021250164A1

  公开（公告）日：2021-12-16

  The present invention relates to compounds of formula (I) as properfume compounds. In particular, the present invention relates to a method to release a compound being a carbonyl of formula (II), a formate ester of formula (III) and/or an alcohol of formula (IV), by exposing the compound of formula (I) to an environment wherein it is oxidized. Moreover, the present invention relates to a perfuming composition and a perfumed consumer product comprising at least one compound of formula (I).

  本发明涉及作为合适香精化合物的公式(I)的化合物。具体而言，本发明涉及一种释放公式(I)化合物的方法，该方法是通过将公式(I)化合物暴露在氧化环境中，释放出公式(II)的醛基、公式(III)的甲酸酯基和/或公式(IV)的醇基。此外，本发明涉及一种香精组合物和一种含有至少一种公式(I)化合物的香精消费产品。
• [EN] IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS<br/>[FR] AMÉLIORATIONS APPORTÉES OU ASSOCIÉES À DES COMPOSÉS ORGANIQUES
  申请人：GIVAUDAN SA

  公开号：WO2014198709A1

  公开（公告）日：2014-12-18

  5, 9-dimethyl-9-hydroxy-decen-4-al, having the formula (I).

  5, 9-二甲基-9-羟基癸烯-4-醛，化学式为（I）。
• [EN] IMPROVEMENTS IN OR RELATING TO ORGANIC COMPOUNDS<br/>[FR] AMÉLIORATIONS APPORTÉES OU LIÉES À DES COMPOSÉS ORGANIQUES
  申请人：GIVAUDAN SA

  公开号：WO2016091894A1

  公开（公告）日：2016-06-16

  A fragrance precursor represented by the formula (1) wherein the wavy bond is indicating an unspecified configuration of the adjacent double bond, X and Y together represent a double bond to a carbon atom which is bearing R1 and R2, with R1 = H, methyl, acetyl or C1-C3 alkoxycarbonyl (e.g. ethoxycarbonyl); and R2 = phenyl optionally substituted with up to 3 (i.e. 0, 1, 2 or 3) groups selected from C1-C4 alkyl (e.g. methyl, ethyl, iso-propyl, tert-butyl), vinyl, hydroxy, C1-C3 alkoxy (e.g. ethoxy), and -O-CH2-O-, e.g. R2 is benzo[d][1,3]dioxol-5-yl, 4-methylphenyl, 4-methoxyphenyl, 4-vinylphenyl or 3-ethoxy-4-hydroxyphenyl or R2 = naphthyl, (naphthyl)methyl, 1,1,2,4,4,8-hexamethyl-1,2,3,4-tetrahydronaphthalen-7-yl, or 1,1,2,4,4,-pentamethyl-1,2,3,4-tetrahydronaphthalen-7-yl or R2 = COR3, wherein R3 is H, C1-C10 alkoxy (e.g. ethoxy, 1-(3,3-dimethylcyclohexyl)ethoxy), C1-C4 alkyl (e.g. methyl, ethyl, propyl, iso-propyl, tert-butyl), e.g. R2 is formyl, acetyl, ethoxycarbonyl, 1-(3,3-dimethylcyclohexyl)ethoxycarbonyl; or wherein X is OR4, with R4 being H, alkyl or alkenyl, and Y is OR5, with R5 being alkyl or alkenyl; the compound being useful as a perfume ingredient.

  一种香精前体，其化学式表示为（1），其中波浪键表示相邻双键的未指定构型，X和Y一起表示一个双键连接到一个碳原子，该碳原子带有R1和R2，其中R1 = H，甲基，乙酰基或C1-C3烷氧羰基（例如乙氧羰基）；R2 = 苯基，可选地取代最多3个（即0, 1, 2或3）个来自C1-C4烷基（例如甲基，乙基，异丙基，叔丁基），乙烯基，羟基，C1-C3烷氧基（例如乙氧基）和-O-CH2-O-的基团，例如R2是苯并[d][1,3]二氧杂环戊-5-基，4-甲基苯基，4-甲氧基苯基，4-乙烯基苯基或3-乙氧基-4-羟基苯基或R2 = 萘基，（萘基）甲基，1,1,2,4,4,8-六甲基-1,2,3,4-四氢萘-7-基，或1,1,2,4,4,-五甲基-1,2,3,4-四氢萘-7-基或R2 = COR3，其中R3为H，C1-C10烷氧基（例如乙氧基，1-(3,3-二甲基环己基)乙氧基），C1-C4烷基（例如甲基，乙基，丙基，异丙基，叔丁基），例如R2是甲酰基，乙酰基，乙氧羰基，1-(3,3-二甲基环己基)乙氧羰基；或其中X为OR4，其中R4为H，烷基或烯基，Y为OR5，其中R5为烷基或烯基；该化合物可用作香精成分。