乙烯基二苯基膦 | 2155-96-6

• 物质功能分类: 有机原料 - 有机膦化合物
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 乙烯基二苯基膦
• 中文别名: 二苯乙烯基膦
• 英文名称: Diphenylvinylphosphine
• 英文别名: ethenyl(diphenyl)phosphane
• CAS: 2155-96-6
• 化学式: C₁₄H₁₃P
• mdl: MFCD00008611
• 分子量: 212.231
• InChiKey: AJVBXLXLODZUME-UHFFFAOYSA-N

物化性质

• 熔点：
  70.5-71.5 °C
• 沸点：
  104 °C/0.25 mmHg (lit.)
• 密度：
  1.067 g/mL at 25 °C (lit.)
• 闪点：
  >110°C
• 稳定性/保质期：
  遵照规定使用和储存，则不会发生分解。

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 安全说明：
  S26,S36/37/39
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  2902909090
• 危险性防范说明：
  P261,P305+P351+P338
• 危险性描述：
  H315,H319,H335
• 储存条件：
  存放在阴凉干燥处即可。

SDS

Name:	Vinyldiphenylphosphine Material Safety Data Sheet
Synonym:
CAS:	2155-96-6

Section 1 - Chemical Product MSDS Name:Vinyldiphenylphosphine Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
2155-96-6	Vinyldiphenylphosphine		218-459-2

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Air sensitive.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation. Place under an inert atmosphere.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Handle under an inert atmosphere.
Store protected from air.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Do not expose to air. Store under an inert atmosphere.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 2155-96-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 104 deg C @ .25mm H
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: > 110 deg C (> 230.00 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.0670g/cm3
Molecular Formula: (C6H5)2PCH=CH2
Molecular Weight: 212.23

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to air.
Incompatibilities with Other Materials:
Air.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases.
Hazardous Polymerization: Not available.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 2155-96-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Vinyldiphenylphosphine - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 2155-96-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 2155-96-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 2155-96-6 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  乙烯基二苯基膦 以 丙酮 、 苯 为溶剂， 生成
  参考文献：
  名称：

  含新型三齿叶立德配体的[ClPtNMe 2 NHCH 2 CHPPh 2 CH 2 CH 2 CH 2 PPh 2 ] Cl的形成和晶体结构

  摘要：

  用Me 2 NNH 2处理顺式-[PtCl 2（PPh 2 CH CH 2）2 ]得到标题化合物，该标题化合物是通过连续共轭加成乙烯基而形成的，包括一个P原子对相邻乙烯基的攻击PPh 2 CH CH 2配位体：描述了标题化合物的一些反应。

  DOI：

  10.1039/c39870000643
• 作为产物：
  描述：

  乙烯基氯化镁 、 二苯基氯化膦 生成 乙烯基二苯基膦
  参考文献：
  名称：

  含有间胍基苯基部分的水溶性阳离子膦配体。Heck型反应的合成及应用。

  摘要：

  包含间胍基苯基取代基的阳离子膦配体{Ph（3-n）P [C（6）H（4）-m-NHC（NH（2））（NMe（2））]（n）}（n +） nCl（-）（n = 1-3）（17a-c）是通过在酸性介质中将二甲基氰胺加到叔（间氨基苯基）膦的氨基上而获得的。叔（间氨基苯基）膦Ph（3-n）P（C（6）H（4）-m-NH（2））（n）（4a-c）通过（3- [N ，N-双（三甲基甲硅烷基）氨基]苯基）氯化镁与氯膦Ph（3-n）PCl（n），然后用甲醇对双（三甲基甲硅烷基）氨基进行脱保护。使用与上述类似的保护基合成方法，也可以制备仲（间氨基苯基）膦Ph（H）PC（6）H（4）-m-NH（2）（7）。它可以用作合成带有间氨基苯基取代基的手性二齿膦配体（11、14和15）的基础。胍鎓膦17b和17c易溶于水。钯催化水相中17b和17c，芳基烷基胍鎓膦18和19和TPPTS（P（C（6）H（4）-m-SO（

  DOI：

  10.1021/jo961140n
• 作为试剂：
  描述：

  C,N-diphenylnitrone 在 乙烯基二苯基膦 作用下， 以 苯 为溶剂， 生成 N-苄叉苯胺 、 1-氧化二苯基二氮烯
  参考文献：
  名称：

  二苯基乙烯基膦对硝酮的意外的偶极亲和活性

  摘要：

  二苯基乙烯基膦对硝酮的反应性受其双键的亲极性性质支配，而不是由P III充当氧受体的能力决定。

  DOI：

  10.1039/c39890000388

文献信息

• Tridentate phosphine ligands bearing aza-crown ether lariats
  作者：Levente G. Pap、Navamoney Arulsamy、Elliott B. Hulley

  DOI：10.1016/j.poly.2017.11.012

  日期：2018.2

  Crown ethers are useful macrocycles that act as size-selective binding sites for alkali metals. These frameworks have been incorporated into a number of macromolecular assemblies that use simple cations as reporters and/or activity triggers. Incorporating crown ethers into secondary coordination sphere ligand frameworks for transition metal chemistry will lead to new potential methods for controlling

  冠醚是有用的大环，可作为碱金属的尺寸选择结合位点。这些框架已被并入许多使用简单阳离子作为报告分子和/或活性触发因子的大分子组装体中。将冠醚掺入用于过渡金属化学的二级配位球配体框架中将导致用于控制键形成步骤的新的潜在方法，并且非常需要将传统配体框架与这些部分偶联的途径。本文中，我们报告了一系列三链膦配合物的合成，这些配合物带有束缚的氮杂-冠冕醚（lariats），旨在将氮杂-冠冕大小，套索长度和远端膦取代基的变化模块化，
• Versatile routes to selenoether functionalised tertiary phosphines
  作者：Tom J. Cunningham、Mark R. J. Elsegood、Paul F. Kelly、Martin B. Smith、Paul M. Staniland

  DOI：10.1039/c0dt00004c

  日期：——

  New selenoether functionalised tertiary phosphines, based on aryl (2a, 2b) or alkyl (4) backbones, have been synthesised and characterised. P,Se-chelation has been achieved upon complexation to square-planar PtII (3a) or PdII (3b) metal centres. For 3a and 3b, weak non-covalent M⋯Se contacts were established using single crystal X-ray crystallography.

  基于芳基（2a，2b）或烷基（4）骨架的新型硒醚官能化叔膦已被合成和表征。P，Se-螯合已通过络合至方平面实现铂II（3a）或钯二（3b）金属中心。对于3a和3b，弱的非共价M⋯硒 使用单晶X射线晶体学建立联系。
• Single component cationic palladium proinitiators for the latent polymerization of cycloolefins
  申请人：Bell Andrew

  公开号：US20050187398A1

  公开（公告）日：2005-08-25

  Palladium compound compositions are provided in accordance with Formulae [((R) 3 E) a Pd(Q)(LB) b ] p [WCA] r , where ((R) 3 E) is a Group 15 electron donor ligand, Q is an anionic ligand, LB is a Lewis base, WCA is a weakly coordinating anion, a is 1, 2 or 3, b is 0, 1 or 2, the sum of a and b is 1, 2 or 3 and each of p and r is an integer such that the molecular charge is zero, or [(E(R) 3 )(E(R) 2 R*)Pd(LB)] p [WCA] r where E(R) 2 R* represents a Group 15 neutral electron donor ligand and where R* is an anionic hydrocarbyl containing moiety, bonded to the Pd and having a β hydrogen with respect to the Pd center. Such compound composition exhibits latent polymerization activity in the presence of polycyclic olefins.

  钯化合物组成按照以下公式提供：[((R)3E)aPd(Q)(LB)b]p[WCA]r，其中((R)3E)是第15族电子供体配体，Q是阴离子配体，LB是路易斯碱，WCA是弱配位阴离子，a为1、2或3，b为0、1或2，a和b的总和为1、2或3，p和r各自为整数，使得分子电荷为零，或[(E(R)3)(E(R)2R*)Pd(LB)]p[WCA]r，其中E(R)2R*代表第15族中性电子供体配体，R*是与Pd键合的含有阴离子烃基的部分，并且相对于Pd中心具有β氢。这种化合物组成在多环烯烃存在时表现出潜在的聚合活性。
• Asymmetric synthesis of a chiral arsinophosphine via a metal template promoted asymmetric Diels–Alder reaction between diphenylvinylphosphine and 2-furyldiphenylarsine
  作者：Kien-Wee Tan、Fengli Liu、Yongxin Li、Geok-Kheng Tan、Pak-Hing Leung

  DOI：10.1016/j.jorganchem.2006.07.025

  日期：2006.11

  The asymmetric Diels–Alder reaction between 2-furyldiphenylarsine and diphenylvinylphosphine was achieved stereospecifically by utilizing an organoplatinum reaction promoter containing the ortho-metalated (R)-(1-(dimethylamino) ethyl)-naphthalene as the chiral auxiliary. The optically pure (+)-As–P heterobidentate cycloadduct could be liberated from the template product by successive treatment with

  通过使用含有邻金属化的（R）-（1-（二甲基氨基）乙基）-萘作为手性助剂的有机铂反应促进剂，立体定向地实现了2-呋喃二苯基ar与二苯基乙烯基膦之间的不对称Diels-Alder反应。通过连续用浓盐酸和氰化钾水溶液处理，可以从模板产物中释放出光学纯的（+）-As-P异双齿环加合物。
• ORGANIC MATERIAL CONTAINING OLIGOPHENYLENE SKELETON AND LIGHT-EMITTING DEVICE USING THE SAME
  申请人：National University Corporation Nagoya University

  公开号：EP2236485A1

  公开（公告）日：2010-10-06

  [Object] To provide a wide band-gap material capable of forming a stable amorphous thin film and an organic electroluminescent device using such a compound and having a high light emission efficiency. [Solution] It has been found that a novel oligophenylene derivative, which is applicable as an organic electroluminescent material, can be produced efficiently using a cross-coupling reaction. It has also been found that a highly-efficient blue phosphorescent light-emitting device can be produced using this compound. The present invention is based on these findings.

  提供一种能够形成稳定非晶态薄膜的宽禁带材料，以及使用这种化合物并具有高发光效率的有机电致发光器件。 已经发现，一种新型的寡苯基衍生物可以通过交叉偶联反应有效地制备，该衍生物可用作有机电致发光材料。还发现，使用这种化合物可以制造出高效蓝色磷光发光器件。本发明基于这些发现。