1-甲基环己烷-1,2-二甲酸 | 13185-53-0

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物 - 环羧酸
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1-甲基环己烷-1,2-二甲酸
• 英文名称: (methyl)hexahydrophthalic acid
• 英文别名: methyltetrahydrophthalic acid；1-Methylcyclohexane-1,2-dicarboxylic acid
• CAS: 13185-53-0
• 化学式: C₉H₁₄O₄
• 分子量: 186.208
• InChiKey: PMUPSYZVABJEKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2917209090

上下游信息

• 上游原料

  中文名称	英文名称	CAS号	化学式	分子量
  1-甲基六氢邻苯二甲酸酐	methylhexahydrophthalic anhydride	48122-14-1	C9H12O3	168.192
  1-甲基六氢邻苯二甲酸酐	methylhexahydrophthalic anhydride	48122-14-1	C9H12O3	168.192

反应信息

• 作为产物：
  描述：

  Diketopyrrolopyrrole 、 、 吩噻嗪 、 1-甲基六氢邻苯二甲酸酐 、 甲基丙烯酸羟乙酯 在 氮气 作用下， 以 1,4-二氯苯 为溶剂， 以3.17 g (0.010 mol) of the methyl-hexahydrophthalic acid derivative (isomer mixture) of the formula ##STR43## (obtained by generally known methods from methylhexahydrophthalic anhydride and hydroxyethyl methacrylate)的产率得到1-甲基环己烷-1,2-二甲酸
  参考文献：
  名称：

  Polymerizable diketopyrrolopyrroles and polymers prepared therewith

  摘要：

  公式为## STR1 ##的1,4-二酮吡咯烷酮，其中A和B彼此独立，均为## STR2 ##式的基团，其中R.sub.1是含有聚合反应活性基团的长链基团，而R.sub.2为C.sub.1-C.sub.6烷基，##STR3##或R.sub.1。有关基团R.sub.3-R.sub.9的定义，请参阅权利要求1。这种新型的二酮吡咯烷酮适用于制备具有意外优越的色彩效果的有色聚合物。

  公开号：

  US06048918A1

文献信息

• ACID-RESISTANT BASE AND/OR RADICAL GENERATOR, AND CURABLE RESIN COMPOSITION CONTAINING SAID BASE AND/OR RADICAL GENERATOR
  申请人：WAKO PURE CHEMICAL INDUSTRIES, LTD.

  公开号：US20190002403A1

  公开（公告）日：2019-01-03

  The present invention relates to a compound represented by the general formula (A), a base- and/or radical-generating agent comprising the compound, and so on. In the formula, four pieces of R 1 each independently represents a hydrogen atom or a fluorine atom; four pieces of R 2 each independently represent a fluorine atom or a trifluoromethyl group; R 3 , R 6 , R 7 and R 10 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms; R 4 and R 5 each independently represent a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, or R 4 and R 5 are bonded to each other to represent an alkylene group having 2 to 4 carbon atoms; and R 8 and R 9 each independently represent a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, or an aryl group having 6 to 14 carbon atoms and optionally having a substituent selected from the group consisting of an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkylthio group having 1 to 6 carbon atoms, a dialkylamino group having 2 to 12 carbon atoms, a halogen atom, and a nitro group, or R 8 and R 9 are bonded to each other to represent an alkylene group having 2 to 4 carbon atoms; provided that two or three of the eight groups R 3 to R 10 are each a hydrogen atom, and, in a case where two of the eight groups are each a hydrogen atom, then three to six of the remaining groups are each an alkyl group having 1 to 12 carbon atoms, and, in a case where three of the eight groups are each a hydrogen atom, then four or five of the remaining groups are each an alkyl group having 1 to 12 carbon atoms.

  本发明涉及一种由通式（A）表示的化合物，包括该化合物的生成碱基和/或基团产生剂等。在该式中，四个R1分别独立表示氢原子或氟原子；四个R2分别独立表示氟原子或三氟甲基基团；R3、R6、R7和R10分别独立表示氢原子或具有1至12个碳原子的烷基基团；R4和R5分别独立表示氢原子或具有1至12个碳原子的烷基基团，或者R4和R5相互连接表示具有2至4个碳原子的亚烷基基团；R8和R9分别独立表示氢原子、具有1至12个碳原子的烷基基团或具有6至14个碳原子且可选地具有选自包括具有1至6个碳原子的烷基基团、具有1至6个碳原子的烷氧基团、具有1至6个碳原子的烷硫基团、具有2至12个碳原子的二烷基氨基团、卤素原子和硝基基团的取代基的芳基团，或者R8和R9相互连接表示具有2至4个碳原子的亚烷基基团；前提是八个基团R3至R10中的两个或三个分别是氢原子，并且在其中两个基团分别是氢原子的情况下，其余基团中的三到六个分别是具有1至12个碳原子的烷基基团，而在其中三个基团分别是氢原子的情况下，其余基团中的四个或五个分别是具有1至12个碳原子的烷基基团。
• METHOD FOR PRODUCING COMPOUND HAVING ACID-LABILE GROUP
  申请人：Kyowa Hakko Chemical Co., Ltd.

  公开号：EP1661918A1

  公开（公告）日：2006-05-31

  The present invention provides a process for producing a compound having a group represented by general formula (II): (wherein R1, R2, and R3 may be the same or different, and each represent a substituted or unsubstituted alkyl, a substituted or unsubstituted aryl, or a substituted or unsubstituted aralkyl, or R1 and R2 may bind to each other to form an alicyclic hydrocarbon ring together with the adjacent carbon atoms, or R2 and R3 may bind to each other to form a alicyclic heterocyclic ring together with the adjacent O-C-C that may have a substituent), which comprises allowing a compound having a hydroxyl group to react with halogenated alkyl ether represented by general formula (I): (wherein R1, R2, and R3 are the same as those defined above, respectively and X represents a halogen atom).

  本发明提供了一种生产具有由通式（II）表示的基团的化合物的方法：（其中R1、R2和R3可以相同也可以不同，并且分别表示取代或未取代的烷基、取代或未取代的芳基、或取代或未取代的芳基烷基，或者R1和R2可以相互结合形成与相邻碳原子一起的脂环碳氢环，或者R2和R3可以相互结合形成与相邻的O-C-C一起具有取代基的脂环杂环）的方法，该方法包括允许具有羟基的化合物与由通式（I）表示的卤代烷基醚发生反应：（其中R1、R2和R3分别与上述定义相同，X代表卤素原子）。
• CURABLE COMPOSITION, CURED FILM, OPTICAL FILTER, SOLID IMAGE PICKUP ELEMENT, IMAGE DISPLAY DEVICE, INFRARED SENSOR, DISPERSING AUXILIARY AGENT, DISPERSION, AND METHOD OF MANUFACTURING DISPERSION
  申请人：FUJIFILM Corporation

  公开号：US20200115382A1

  公开（公告）日：2020-04-16

  Provided are a curable composition, a cured film, an optical filter, a solid image pickup element, an image display device, an infrared sensor, a dispersing auxiliary agent, a dispersion, and a method of manufacturing a dispersion. With the curable composition, a cured film having excellent moisture resistance in which the formation of an aggregate derived from a compound having a colorant skeleton is suppressed can be formed. This curable composition includes: a compound A having a structure in which at least one functional group selected from an acid group having a pKa of 3 or lower and a Clog P value of −1.1 or higher, an anionic group obtained by dissociating one or more hydrogen atoms from the acid group, or a salt of the acid group is bonded to a π-conjugated structure of a colorant skeleton and having a maximum absorption wavelength in a wavelength range of 650 to 1200 nm; a curable compound; and a solvent.

  提供了一种可治愈的组合物、治愈膜、光学滤光片、固态图像拾取元件、图像显示装置、红外传感器、分散辅助剂、分散液以及一种制备分散液的方法。利用这种可治愈的组合物，可以形成具有优异耐潮性的治愈膜，其中抑制了由具有色素骨架的化合物衍生的聚集体的形成。这种可治愈的组合物包括：一种化合物A，其结构中至少有一种功能基团，选自具有pKa值为3或更低和Clog P值为-1.1或更高的酸基团、从该酸基团中解离出一个或多个氢原子得到的阴离子基团，或该酸基团的盐，与色素骨架的π共轭结构结合，并在650至1200纳米波长范围内具有最大吸收波长；一种可治愈的化合物；和一种溶剂。
• [EN] POLYFUNCTIONAL HYDROPHTHALIMIDE MONOMER COMPOUNDS<br/>[FR] COMPOSÉS MONOMÈRES D'HYDROPHTHALIMIDE POLYFONCTIONNELS
  申请人：DSM IP ASSETS BV

  公开号：WO2016097403A1

  公开（公告）日：2016-06-23

  The present invention relates to a an imide compound according to anyone of formulas Ia, Ib, Ic, or Ie wherein R1 is H or a C1 -C20 optionally substituted hydrocarbon group; both R2 and R5 are a COOH group or one of R2 and R5 is a COOH group while the other substituent is H, methyl or ethyl group; R3 and R4 are independently H, or C1 -C20 optionally substituted hydrocarbon group; R6 is H or a methyl group; R7 and R8 are independently H, methyl or ethyl.

  本发明涉及一种酰亚胺化合物，根据以下任一式Ia、Ib、Ic或Ie，其中R1为H或C1-C20的可选取代的碳氢基团；R2和R5均为COOH基团，或者R2和R5中的一个是COOH基团，而另一个取代基为H、甲基或乙基基团；R3和R4独立地为H，或C1-C20的可选取代的碳氢基团；R6为H或甲基基团；R7和R8独立地为H、甲基或乙基。
• PROCESS FOR PRODUCING ETHER COMPOUND
  申请人：Kyowa Yuka Co., Ltd.

  公开号：EP1415968A1

  公开（公告）日：2004-05-06

  The present invention provides the following process for produci ng and the like, which enables the production of an ether compound, which is useful for chemical amplification type resist compositions, synthetic intermediates of pharmaceuticals, paints, or the like, with less side reaction and in high yield. A process for producing an ether compound having a group represented by the general formula (II) wherein R1, R2 and R3 may be the same or different, and represent substituted or unsubstituted alkyl, substituted or unsubstituted aryl or substituted or unsubstituted aralkyl, or R1 and R2 form cycloalkyl together with an adjacent carbon atom,    which comprises allowing a compound having a hydroxyl group (including a carboxyl group) to react with an alkenyl ether represented by the general formula (I) wherein R1, R2 and R3 have the same significances as defined above, respectively.

  本发明提供了以下用于生产等的过程，该过程能够生产醚化合物，该化合物对于化学放大型抗蚀组合物、药物合成中间体、涂料等具有用途，且副反应较少且产率高。一种生产具有由通式（II）表示的基团的醚化合物的方法，其中R1、R2和R3可以相同也可以不同，并表示取代或未取代的烷基、取代或未取代的芳基或取代或未取代的芳基烷基，或者R1和R2与相邻碳原子一起形成环烷基，包括允许具有羟基（包括羧基）的化合物与由通式（I）表示的烯基醚发生反应，其中R1、R2和R3分别具有上述定义的相同含义。