1-甲基环己基邻苯二甲酸酯 | 960-24-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1-甲基环己基邻苯二甲酸酯
• 英文名称: Phthalsaeure-mono-(1-methyl-cyclohex-1-yl)-ester
• 英文别名: Phthalsaeure-(1-methyl-cyclohexylester)；2-(1-Methylcyclohexoxy)carbonylbenzoic acid；2-(1-methylcyclohexyl)oxycarbonylbenzoic acid
• CAS: 960-24-7
• 化学式: C₁₅H₁₈O₄
• 分子量: 262.306
• InChiKey: GONWOZUQGIDGER-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  苯酐 、 1-甲基环己醇 在 三乙胺 、 magnesium bromide 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以90%的产率得到1-甲基环己基邻苯二甲酸酯
  参考文献：
  名称：

  Dual Activation in the Esterification of Hindered Alcohols with Anhydrides Using MgBr₂ and a Tertiary Amine

  摘要：

  DOI：

  10.1021/jo9609485

文献信息

• Dicarboxylic diester, process for producing the same, and refrigerating machine lubricating oil comprising the ester
  申请人：Kawahara Yasuyuki

  公开号：US20050038283A1

  公开（公告）日：2005-02-17

  A diester represented by the formula wherein A represents a cyclohexane ring, cyclohexene ring or benzene ring, X is H or methyl group, R X and R Y are the same or different and each is C3-C18 branched-chain alkyl group, C1-C18 straight-chain alkyl group, C2-C18 straight-chain alkenyl or C3-C18 cycloalkyl, provided that when A is a benzene ring, R X and R Y are different from each other and —COOR X and —COOR Y are attached to two adjacent carbon atoms of the benzene ring, and having the following properties: 1) a total acid number of 0.05 mgKOH/g or less, 2) a sulfated ash content of 10 ppm or less, 3) a sulfur content of 20 ppm or less, 4) a phosphorus content of 20 ppm or less, 5) a peroxide value of 1.0 meq/kg or less, 6) a carbonyl value of 10 or less; 7) a volume resistivity of 1×10 11 Ω·cm or more, 8) a hydroxyl value of 3 mgKOH/g or less, and 9) a water content of 100 ppm or less, a process for preparing the same and a refrigerator lubricating oil comprising the diester.

  由以下公式表示的二酯，其中A代表环己烷环、环己烯环或苯环，X为H或甲基基团，RX和RY相同或不同，且每个均为C3-C18支链烷基基团、C1-C18直链烷基基团、C2-C18直链烯基或C3-C18环烷基，前提是当A为苯环时，RX和RY彼此不同，且—COORX和—COORY连接到苯环的两个相邻碳原子，并具有以下特性：1）总酸值为0.05 mgKOH/g或更低，2）硫酸盐灰分含量为10 ppm或更低，3）硫含量为20 ppm或更低，4）磷含量为20 ppm或更低，5）过氧化值为1.0 meq/kg或更低，6）羰基值为10或更低；7）体积电阻率为1×1011Ω·cm或更高，8）羟值为3 mgKOH/g或更低，9）水含量为100 ppm或更低，制备该二酯的方法以及包含该二酯的制冷剂润滑油。
• DICARBOXYLIC DIESTER, PROCESS FOR PRODUCING THE SAME, AND REFRIGERATING MACHINE LUBRICATING OIL COMPRISING THE ESTER
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1227078A1

  公开（公告）日：2002-07-31

  A diester represented by the formula wherein A represents a cyclohexane ring, cyclohexene ring or benzene ring, X is H or methyl group, RX and RY are the same or different and each is C3-C18 branched-chain alkyl group, C1-C18 straight-chain alkyl group, C2-C18 straight-chain alkenyl or C3-C10 cycloalkyl, provided that when A is a benzene ring, RX and RY are different from each other and -COORX and -COORY are attached to two adjacent carbon atoms of the benzene ring, and having the following properties: 1) a total acid number of 0.05 mgKOH/g or less, 2) a sulfated ash content of 10 ppm or less, 3) a sulfur content of 20 ppm or less, 4) a phosphorus content of 20 ppm or less, 5) a peroxide value of 1.0 meq/kg or less, 6) a carbonyl value of 10 or less; 7) a volume resistivity of 1 x 1011 Ω·cm or more, 8) a hydroxyl value of 3 mgKOH/g or less, and 9) a water content of 100 ppm or less, a process for preparing the same and a refrigerator lubricating oil comprising the diester.

  由式表示的二酯 其中 A 代表环己烷环、环己烯环或苯环，X 为 H 或甲基，RX 和 RY 相同或不同，且各自为 C3-C18 支链烷基、C1-C18 直链烷基、C2-C18 直链烯基或 C3-C10 环烷基，条件是当 A 为苯环时，RX 和 RY 彼此不同，且 -COORX 和 -COORY 连接到苯环的两个相邻碳原子上，并具有以下性质： 1) 总酸数不超过 0.05 mgKOH/g、 2) 硫酸盐灰分含量不超过 10 ppm、 3) 硫含量不超过 20 ppm、 4) 磷含量不超过 20 ppm、 5) 过氧化值等于或小于 1.0 meq/kg、 6) 羰基值等于或小于 10； 7) 体积电阻率等于或大于 1 x 1011 Ω-cm、 8) 羟值为 3 mgKOH/g 或更低，以及 9) 含水量等于或小于 100 ppm、 制备该二元酯的工艺和包含该二元酯的冷冻机润滑油。
• DISPERSIONS OF BLENDED POLYCARBOXYPOLYAMIDE RESINS AND ALKALI DISPERSIBLE RESINS, THEIR PREPARATION AND THEIR USE
  申请人：S.C. Johnson Commercial Markets, Inc.

  公开号：EP0946647A1

  公开（公告）日：1999-10-06
• [EN] DISPERSIONS OF BLENDED POLYCARBOXYPOLYAMIDE RESINS AND ALKALI DISPERSIBLE RESINS, THEIR PREPARATION AND THEIR USE<br/>[FR] DISPERSIONS DE RESINES DE POLYCARBOXYPOLYAMIDE MELANGEES A DES RESINES DISPERSIBLES DANS UN LIQUIDE ALCALIN, LEUR PREPARATION ET LEUR UTILISATION
  申请人：S.C. JOHNSON COMMERCIAL MARKETS, INC.

  公开号：WO1998027162A1

  公开（公告）日：1998-06-25

  (EN) This invention relates to polymer blends comprising a polycarboxypolyamide resin with an alkali dispersible resin. This invention also relates to the use of the polymer blends to prepare aqueous dispersions. The aqueous dispersions were obtained by heating polycarboxypolyamide resins with alkali dispersible resins in an aqueous medium. The invention further relates to coating compositions containing the aqueous dispersions. Such coating compositions include inks, floor finishes, overprint varnishes, sizing, paints and adhesives.(FR) La présente invention concerne des mélanges de polymères comportant une résine de polycarboxypolyamide et une résine dispersible dans un liquide alcalin. Cette invention traite également de l'utilisation des mélanges de polymères en vue de préparer des dispersions aqueuses. Les dispersions aqueuses ont été obtenues par chauffage dans un milieu aqueux des résines de polycarboxypolyamide avec des résines dispersibles dans un liquide alcalin. L'invention concerne par ailleurs des compositions de revêtement contenant des dispersions aqueuses. Parmi lesdites compositions figurent des encres, des revêtements de finition, des vernis de surimpression, des colles, des peintures et des adhésifs.
• [EN] RAPID DRYING LACQUERS CONTAINING IMPROVED RHEOLOGY CONTROL ADDITIVE<br/>[FR] VERNIS À SÉCHAGE RAPIDE CONTENANT UN ADDITIF RHÉOLOGIQUE AMÉLIORÉ
  申请人：AXALTA COATING SYSTEMS IP CO

  公开号：WO2015013593A2

  公开（公告）日：2015-01-29

  This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel graft copolymer with segmented (or block) arms as a replacement material for all or part of the cellulose acetate butyrate binder component. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers are especially useful in providing chip and humidity resistant coatings, especially metallic effect coatings, having excellent adhesion and down flop or metallic effect.