(1R,2R,3S,4S,5S)-1-(叔-丁基二苯基)硅烷基氧基甲基-2,3-二氧基-O,O-异亚丙基双环[3.1.0]己烷-4-醇 | 915694-38-1

分子结构分类

有机化合物 - 有机氧化合物

中文名称

(1R,2R,3S,4S,5S)-1-(叔-丁基二苯基)硅烷基氧基甲基-2,3-二氧基-O,O-异亚丙基双环[3.1.0]己烷-4-醇

中文别名

——

英文名称

(+)-(1aR,1bR,4aS,5S,5aS)-1a-(tert-butyldiphenylsilyloxymethyl)-3,3-dimethylhexahydro-2,4-dioxa-cyclopropa[a]pentalen-5-ol

英文别名

(3aR,3bR,4aS,5S,5aS)-3b-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethylhexahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3]dioxol-5-ol；(1R,2R,3S,4S,5S)-1-[(tert-butyldiphenylsilyl)oxy]methyl-2,3-O-isopropylidenebicyclo[3.1.0]hexan-2,3,4-triol；(1R,2R,3S,4S,5S)-1-(tert-Butyldiphenyl)silyloxymethyl-2,3-dioxy-O,O-isopropylidenebicyclo[3.1.0]hexan-4-ol；(1R,2R,4S,5S,6S)-2-[[tert-butyl(diphenyl)silyl]oxymethyl]-8,8-dimethyl-7,9-dioxatricyclo[4.3.0.02,4]nonan-5-ol

(1R,2R,3S,4S,5S)-1-(叔-丁基二苯基)硅烷基氧基甲基-2,3-二氧基-O,O-异亚丙基双环[3.1.0]己烷-4-醇化学式

CAS

915694-38-1

化学式

C₂₆H₃₄O₄Si

mdl

——

分子量

438.639

InChiKey

XFSRKIPDQLASTK-SQSAXNKISA-N

BEILSTEIN

——

EINECS

——

物化性质

沸点：

501.7±43.0 °C(Predicted)
密度：

1.16±0.1 g/cm3(Predicted)

计算性质

辛醇/水分配系数(LogP)：

3.46
重原子数：

31
可旋转键数：

6
环数：

5.0
sp3杂化的碳原子比例：

0.54
拓扑面积：

47.9
氢给体数：

1
氢受体数：

4

SDS

SDS：c3bb8946d547d88848640eeef76934e7

查看

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	1-[(tert-butyldiphenylsilyl)oxy]-2-[(4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]but-3-en-2-ol	902799-70-6	C₂₇H₃₆O₄Si	452.666
——	(1R)-(-)-1-[(4R,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl]-2-(tert-butyldiphenylsilyloxy)ethan-1-ol	681853-93-0	C₂₅H₃₄O₄Si	426.628
——	5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose	96690-02-7	C₂₄H₃₂O₅Si	428.601
——	(3aS,4S,6aR)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyl-3a,6a-dihydro-4H-cyclopenta[d][1,3]dioxol-4-ol	303963-93-1	C₂₅H₃₂O₄Si	424.612
——	(-)-1-((4S,5S)-2,2-dimethyl-5-vinyl-1,3-dioxolan-4-yl)-2-(tert-butyldiphenylsilyloxy)ethan-1-one	681853-95-2	C₂₅H₃₂O₄Si	424.612
(3Ar,6ar)-6-((叔丁基二苯基甲硅烷基氧基)甲基)-2,2-二甲基-3ah-环戊并[d][1,3]二氧代l-4(6ah)-酮	(3aR,6aR)-6-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethyl-3aH-cyclopenta[d][1,3]dioxol-4(6aH)-one	303963-92-0	C₂₅H₃₀O₄Si	422.596
乙基(1S,2R,3S,4S,5S)-2,3-O-(异亚丙基)-4-羟基双环[3.1.0]己烷羧酸酯	ethyl (1S,2R,3S,4S,5S)-2,3-O-(isopropylidene)-4-hydroxybicyclo[3.1.0]hexanecarboxylate	793695-59-7	C₁₂H₁₈O₅	242.272
——	ethyl (1S,2R,3S,4S,5S)-3,4-O-isopropylidene-2-hydroxybicyclo[3.1.0]hexanecarboxylate	828935-09-7	C₁₂H₁₈O₅	242.272

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	(+)-(1S,2S,3S,4R,5R)-4-tert-butoxy-5-(tert-butyldiphenylsilyloxymethyl)bicyclo[3.1.0]hexane-2,3-diol	915694-39-2	C₂₇H₃₈O₄Si	454.682
——	(1R,2R,3S,4S,5S)-acetic acid 2-tert-butoxy-1-(tert-butyldiphenyl-silanyloxymethyl)-3,4-dihydroxy bicyclo[3.1.0]hex-3-ylmethyl ester	1355670-53-9	C₃₀H₄₂O₆Si	526.745
——	(+)-(1R,2R,3R,4S,5S)-2-tert-butoxy-4-(tert-butyldiphenylsilyloxy)-1-(tert-butyldiphenylsilyloxymethyl)-bicyclo[3.1.0]hexan-3-ol	915694-40-5	C₄₃H₅₆O₄Si₂	693.086
——	(1R,2R,3R,4S,5S)-2-tert-butoxy-4-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexan-3-ol	1355670-44-8	C₃₃H₅₂O₄Si₂	568.944
——	(1S,2S,3S,4R,5R)-4-tert-butoxy-5-(tert-butyl-diphenylsilanyloxymethyl)-3-fluoromethyl-bicyclo[3.1.0]hexane-2,3-diol	1355670-87-9	C₂₈H₃₉FO₄Si	486.699
——	(3aR,3bR,4aS,5R,5aS)-3b-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethylhexahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3]dioxol-5-amine	1309375-16-3	C₂₆H₃₅NO₃Si	437.654
——	(+)-(1R,2R,3R,4S,5S)-2-tert-butoxy-4-(tert-butyldiphenylsilyloxy)-1-(tert-butyldiphenylsilyloxymethyl)-3-methyl-bicyclo[3.1.0]hexan-3-ol	915694-42-7	C₄₄H₅₈O₄Si₂	707.113
——	(1S,2S,3S,4R,5R)-3-azidomethyl-4-tert-butoxy-5-(tertbutyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexane-2,3-diol	1355670-86-8	C₂₈H₃₉N₃O₄Si	509.721
——	(1R,2R,3R,4S,5S)-acetic acid 2-tert-butoxy-4-(tert-butyldimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3-hydroxy-bicyclo[3.1.0]hex-3-ylmethyl ester	1355670-50-6	C₃₆H₅₆O₆Si₂	641.008
——	(1R,2R,3R,4S,5S)-2-tert-butoxy-1-(hydroxymethyl)spiro[bicyclo[3.1.0]hexane-3,2'-oxiran]-4-ol	1355670-48-2	C₃₄H₅₂O₄Si₂	580.955
——	(((3aR,3bR,4aS,5R,5aS)-5-azido-2,2-dimethyltetrahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3]dioxol-3b(3aH)-yl)methoxy)(tert-butyl)diphenylsilane	1309375-15-2	C₂₆H₃₃N₃O₃Si	463.652
——	((3aS,3bS,4aR,5R,5aR)-5-(tert-butoxy)-4a-(((tert-butyldiphenylsilyl)oxy)methyl)-2-oxidotetrahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3,2]dioxathiol-5a(3aH)-yl)methyl acetate	1355670-55-1	C₃₀H₄₀O₇SSi	572.795
——	(1R,2R,4S,5S)-2-tert-butoxy-4-(tert-butyl-dimethyl-silanyloxy)-1-(tert-butyl-diphenyl-silanyloxymethyl)-bicyclo[3.1.0]hexan-3-one	1355670-46-0	C₃₃H₅₀O₄Si₂	566.929
——	(1S,4aR,5R,5aR,6R)-acetic acid 5-tert-butoxy-5a-(tert-butyldiphenyl-silanyloxymethyl)-3,3-dioxo-tetrahydro-2,4-dioxa-3λ6-thia-cyclopropa[a]pentalen-4a-ylmethyl ester	1355670-54-0	C₃₀H₄₀O₈SSi	588.794
——	(+)-(1R,2R,4S,5S)-2-tert-butoxy-4-(tert-butyldiphenylsilyloxy)-1-(tert-butyldiphenylsilyloxymethyl)-bicyclo[3.1.0]hexan-3-one	915694-41-6	C₄₃H₅₄O₄Si₂	691.07
——	(3aS,3bS,4aR,5R,5aR)-5-(tert-butoxy)-4a-(((tert-butyldiphenylsilyl)oxy)methyl)-5a-(fluoromethyl)hexahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3,2]dioxathiole 2-oxide	1355671-10-1	C₂₈H₃₇FO₅SSi	532.749
——	(1S,4aR,5R,5aR,6S)-(4a-fluoromethyl-5-tert-butoxy-3,3-dioxo-tetrahydro-2,4-dioxa-3λ6-thia-cyclopropa[a]pentalen-5a-ylmethoxy)-tert-butyl-diphenyl-silane	1355670-89-1	C₂₈H₃₇FO₆SSi	548.748
——	(3aS,3bS,4aR,5R,5aR)-5a-(azidomethyl)-5-(tert-butoxy)-4a-(((tert-butyldiphenylsilyl)oxy)methyl)hexahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3,2]dioxathiole 2-oxide	1355671-09-8	C₂₈H₃₇N₃O₅SSi	555.77
——	(1S,4aR,5R,5aR,6S)-(4a-azidomethyl-5-tert-butoxy-3,3-dioxo-tetrahydro-2,4-dioxa-3λ6-thia-cyclopropa[a]pentalen-5a-ylmethoxy)-tert-butyl-diphenyl-silane	1355670-88-0	C₂₈H₃₇N₃O₆SSi	571.77
——	9-((3aR,3bR,4aS,5R,5aS)-3b-(((tert-butyldiphenylsilyl)oxy)methyl)-2,2-dimethylhexahydrocyclopropa[3,4]cyclopenta[1,2-d][1,3]dioxol-5-yl)-6-chloro-9H-purine	1174673-36-9	C₃₁H₃₅ClN₄O₃Si	575.182