1-癸基-3-甲基咪唑鎓硝酸盐 | 1057409-91-2

• 物质功能分类: 有机原料 - 杂环化合物
• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 1-癸基-3-甲基咪唑鎓硝酸盐
• 中文别名: 1-癸基-3-甲基咪唑硝酸盐
• 英文名称: 1-decyl-3-methylimidazolium nitrate
• 英文别名: 1-decyl-3-methylimidazol-3-ium;nitrate
• CAS: 1057409-91-2
• 化学式: C₁₄H₂₇N₂*NO₃
• 分子量: 285.387
• InChiKey: KHEZVFOGTIMXJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.21
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  71.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  silver nitrate 、 1-癸基-3-甲基咪唑溴盐 以 水 为溶剂， 生成 silver(I) bromide 、 1-癸基-3-甲基咪唑鎓硝酸盐
  参考文献：
  名称：

  Anion effects on ionogel formation in N,N′-dialkylimidazolium-based ionic liquids

  摘要：

  Addition of an appropriate concentration of water to either 1-decyl-3-methylimidazolium bromide or its nitrate analog is shown to trigger the self-assembly of the ionic liquid (IL) and the concomitant formation of gel ("ionogel") phases adopting a rich variety of structural motifs. Infrared and H-1 nuclear magnetic resonance studies indicate that water addition disrupts hydrogen bonding between the imidazolium ring and the IL anion, and that gelation involves the partial replacement of these bonds with H-bonds between the anion and water. Using small angle X-ray scattering, the relationship of the water content and the nature of the IL anion to the mesoscopic structure of the ionogels has been determined. Of particular note is the observation that by adjustment of the ionogel composition (water content or anion), near-monodomain materials can be formed with either lamellar, 2-D hexagonal or 3-D cubic structures with tunable lattice dimensions. Published by Elsevier B.V.

  DOI：

  10.1016/j.ica.2004.06.042