| 1326543-97-8

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮
• CAS: 1326543-97-8；910137-96-1
• 化学式: C₄₄H₂₆N₄Ni
• 分子量: 669.407
• InChiKey: DLGRACZQSSVXFD-YLWROZOSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-bromo-5,10,15,20-tetraphenylporphyrin 在 bis(acetylacetonate)nickel(II) 、 (±)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl 、 potassium tert-butylate 、 palladium diacetate 作用下， 以 氯苯 、 甲苯 为溶剂， 反应 63.0h， 生成
  参考文献：
  名称：

  Diporphyrinylamines: Synthesis and Electrochemistry

  摘要：

  The synthesis of three possible diporphyrinylamines is described. All compounds were obtained by using the Buchwald-Hartwig aromatic amination reaction. The electronic spectra of the three porphyrin dimers showed characteristic features found In highly delocalized systems. The first oxidation of these compounds took place on the connecting amine function.

  DOI：

  10.1021/ol2020658

文献信息

• A General and Efficient Palladium-Catalyzed Intramolecular Cyclization Reaction of β-Brominated Porphyrins
  作者：Dong-Mei Shen、Chao Liu、Qing-Yun Chen

  DOI：10.1021/jo0609677

  日期：2006.8.1

  A general and efficient synthesis of fused five-membered porphyrins from the readily available beta-brominated porphyrins via palladium-catalyzed intramolecular cyclization has been developed, which can be applied for various metal complexes of beta-brominated porphyrins or free base ones and generally results in good yields of the fused five-membered porphyrins.