5-(4-acryloyloxlphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II) | 1312887-56-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮
• 英文名称: 5-(4-acryloyloxlphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II)
• CAS: 1312887-56-1
• 化学式: C₅₀H₃₀N₄O₈Zn
• 分子量: 880.2
• InChiKey: QTZDLMUDRACORF-MTHKHLJQSA-L

反应信息

• 作为反应物：
  描述：

  5-(4-acryloyloxlphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II) 在 sodium hydroxide 作用下， 以 水 、 丙酮 为溶剂， 以70%的产率得到sodium 5-(4-acryloyloxlphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II)
  参考文献：
  名称：

  Self-assembly of novel tris(p-carboxyphenyl) porphyrin monomer and its copolymers with acrylamide in aqueous media

  摘要：

  The novel porphyrin monomer 5-(4-acryloyloxylphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II) (ZnAOTCPP) and its corresponding sodium salt (ZnAOTCPP-Na) were synthesized. The latter compound exhibited a new band in excitation spectra due to formation of porphyrin aggregates in water, which were derived from its surface-activity when the concentration was higher than its critical association concentration (CAC). The porphyrins were copolymerized with acrylamide (AM) to prepare water-soluble copolymers with random and micro-blocky structures, which all displayed very new absorption and fluorescence emission bands in the long wavelength region compared with the porphyrin monomer. Furthermore, the micro-blocky copolymer exhibited an additional new absorption band at even longer wavelength region compared with the random copolymer. The experimental results and analysis showed that the porphyrin units in the random copolymer chains self-assembled to form porphyrin association complexes by hydrophobic association and pi-pi stacking interactions, and covalent restrictions of polymer chains in the micro-blocky copolymer. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.03.008
• 作为产物：
  描述：

  5-(4-acryloyloxyphenyl)-10,15,20-tris (4-carboxyphenyl)porphyrin 在 zinc acetate dehydrate 、 溶剂黄146 作用下， 以 四氢呋喃 为溶剂， 以91%的产率得到5-(4-acryloyloxlphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II)
  参考文献：
  名称：

  Self-assembly of novel tris(p-carboxyphenyl) porphyrin monomer and its copolymers with acrylamide in aqueous media

  摘要：

  The novel porphyrin monomer 5-(4-acryloyloxylphenyl)-10,15,20-tris(4-carboxyphenyl)porphyrinate zinc(II) (ZnAOTCPP) and its corresponding sodium salt (ZnAOTCPP-Na) were synthesized. The latter compound exhibited a new band in excitation spectra due to formation of porphyrin aggregates in water, which were derived from its surface-activity when the concentration was higher than its critical association concentration (CAC). The porphyrins were copolymerized with acrylamide (AM) to prepare water-soluble copolymers with random and micro-blocky structures, which all displayed very new absorption and fluorescence emission bands in the long wavelength region compared with the porphyrin monomer. Furthermore, the micro-blocky copolymer exhibited an additional new absorption band at even longer wavelength region compared with the random copolymer. The experimental results and analysis showed that the porphyrin units in the random copolymer chains self-assembled to form porphyrin association complexes by hydrophobic association and pi-pi stacking interactions, and covalent restrictions of polymer chains in the micro-blocky copolymer. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2011.03.008