methyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside | 71117-36-7
中文名称
——
中文别名
——
英文名称
methyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside
英文别名
methyl 4,6-O-benzylidene-β-D-galactopyranoside；Methyl-4,6-O-benzyliden-beta-D-galactopyranoside；(2S,4aR,6R,7R,8R,8aR)-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxine-7,8-diol
CAS
71117-36-7
化学式
C14H18O6
mdl
——
分子量
282.293
InChiKey
VVSWDMJYIDBTMV-IZMFDJJNSA-N
BEILSTEIN
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EINECS
——
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物化性质
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计算性质
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ADMET
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安全信息
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SDS
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制备方法与用途
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上下游信息
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文献信息
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表征谱图
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同类化合物
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相关功能分类
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相关结构分类
计算性质
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辛醇/水分配系数(LogP)：-0.1
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重原子数：20
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可旋转键数：2
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环数：3.0
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sp3杂化的碳原子比例：0.57
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拓扑面积：77.4
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氢给体数：2
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氢受体数：6
上下游信息
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上游原料
中文名称 英文名称 CAS号 化学式 分子量 —— methyl 4,6-O-benzylidene-2-O-levulinoyl-β-D-galactopyranoside 851963-22-9 C19H24O8 380.395 —— methyl 3,4-O-isopropylidene-6-O-(1-methoxy-1-methylethyl)-β-D-galactopyranoside 104530-15-6 C14H26O7 306.356 甲基-Β-D-吡喃半乳糖苷 methyl beta-D-galactopyranoside 1824-94-8 C7H14O6 194.185 -
下游产品
中文名称 英文名称 CAS号 化学式 分子量 —— methyl 4,6-O-benzylidene-β-D-idopyranoside 287191-51-9 C14H18O6 282.293 —— methyl 4,6-O-(phenylmethylene)-β-D-talopyranoside 129263-21-4 C14H18O6 282.293 —— methyl 4,6-O-(S)-benzylidene-3-O-methyl-β-D-idopyranoside 129831-96-5 C15H20O6 296.32 —— methyl 3-O-benzyl-4,6-O-benzylidene-β-D-idopyranoside 1385089-67-7 C21H24O6 372.418 —— methyl 3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside 108739-92-0 C21H24O6 372.418 —— methyl 4,6-O-benzylidene-2-O-methyl-β-D-idopyranoside 6752-76-7 C15H20O6 296.32 —— methyl 4,6-O-benzylidene-2,3-di-O-methyl-β-D-galactopyranoside 175520-83-9 C16H22O6 310.347 —— methyl 2-O-benzyl-4,6-O-benzylidene-β-D-galactopyranoside 108739-91-9 C21H24O6 372.418 —— methyl 4,6-O-benzylidene-3-deoxy-β-D-xylo-hexopyranoside 108740-00-7 C14H18O5 266.294 —— methyl 3-O-allyl-4,6-O-benzylidene-β-D-idopyranoside 1385089-75-7 C17H22O6 322.358 —— methyl 2,4,6-tri-O-benzyl-3-O-methyl-β-D-galactopyranoside 122204-23-3 C29H34O6 478.585 —— methyl 2,6-di-O-benzyl-3-O-methyl-4-O-(2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-β-D-galactopyranoside 108672-21-5 C56H62O11 911.102 —— methyl 2,3,6-tri-O-benzyl-4-O-(3,4,6-tri-O-benzyl-α-D-lyxo-hexapyranosyl)-β-D-galactopyranoside 1401954-90-2 C55H60O10 881.075 —— methyl 2,3,6-tri-O-benzyl-β-D-galactopyranoside 51842-16-1 C28H32O6 464.558 —— methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranoside 86420-73-7 C21H22O7 386.401 —— methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-galactopyranoside 86420-71-5 C21H22O7 386.401 —— methyl 2-O-benzoyl-4,6-O-benzylidene-α-D-galactopyranoside 86420-70-4 C21H22O7 386.401 —— methyl 2,3-di-O-benzyl-β-D-galactopyranoside 6988-40-5 C21H26O6 374.434 —— (1R,22S,23S,25S,28R,30R)-30-methoxy-25-phenyl-2,5,8,15,18,21,24,26,29-nonaoxatetracyclo[20.8.0.09,14.023,28]triaconta-9,11,13-triene 103001-77-0 C28H36O10 532.588 —— methyl 4,6-O-benzylidene-2,3-di-O-benzoyl-β-D-galactopyranoside 86420-74-8 C28H26O8 490.51 —— 2,4,6-tri-O-benzyl-3-O-methyl-D-galactopyranose 90124-32-6 C28H32O6 464.558 —— methyl 2,3-di-O-benzyl-6-O-benzoyl-β-D-galactopyranoside 20786-72-5 C28H30O7 478.542 —— [(2S,4aR,6R,7R,8R,8aS)-7-hydroxy-6-methoxy-2-phenyl-4,4a,6,7,8,8a-hexahydropyrano[3,2-d][1,3]dioxin-8-yl] N-benzoylcarbamate 129217-47-6 C22H23NO8 429.427 —— N-[(1S,2S,6S,7R,9R,12S)-7-methoxy-12-phenyl-3,5,8,11,13-pentaoxatricyclo[7.4.0.02,6]tridecan-4-ylidene]benzamide 129217-38-5 C22H21NO7 411.411 —— methyl 4,6-O-benzylidene-3-deoxy-3-S-ethyl-β-D-idopyranoside 1422739-66-9 C16H22O5S 326.414 —— methyl 3-O-benzenesulfonyl-4,6-O-benzylidene-β-D-galactoside 130187-38-1 C20H22O8S 422.456 —— Methyl 4-O-(α-D-galactopyranosyl)-3-O-methyl-β-D-galactopyranoside 108671-63-2 C14H26O11 370.354 —— methyl 3-amino-4,6-O-benzylidene-3-deoxy-2-O-p-toluoyl-β-D-talopyranoside 1346535-62-3 C22H25NO6 399.444 —— methyl 4,6-O-benzylidene-3-O-p-toluenesulfonyl-β-D-galactopyranoside 86470-08-8 C21H24O8S 436.483 —— methyl 4,6-O-benzylidene-β-D-galactopyranoside 2-O-p-toluenesulfonate 86420-69-1 C21H24O8S 436.483 —— methyl 4,6-O-benzylidene-β-D-galactopyranoside 2,3-di-O-p-toluenesulfonate 6748-86-3 C28H30O10S2 590.672 —— methyl 3-O-methyl-β-D-galactopyranoside 34698-07-2 C8H16O6 208.211 甲基-6-脱氧-β-D-半乳糖苷 methyl β-D-fucopyranoside 24332-98-7 C7H14O5 178.185 —— methyl 3-O-(benzoylcarbamyl)-4,6-O-(phenylmethylene)-2-O-<(trifluoromethyl)sulfonyl>-β-D-galactopyranoside 129217-37-4 C23H22F3NO10S 561.49 - 1
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反应信息
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作为反应物：描述：methyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside 在 吡啶 、 甲醇 、 sodium amalgam 、 氯仿 、 silver(l) oxide 、 碘甲烷 作用下， 生成 methyl 4,6-O-benzylidene-2-O-methyl-β-D-galactopyranoside参考文献：