Zinc acrylate | 14643-87-9

• 物质功能分类: 有机原料 - 有机金属类化合物 - 有机锌
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Zinc acrylate
• 英文别名: zinc;prop-2-enoate
• CAS: 14643-87-9
• 化学式: C6H6O4Zn
• 分子量: 207.5
• InChiKey: XKMZOFXGLBYJLS-UHFFFAOYSA-L

物化性质

• 熔点：
  240-244 °C (lit.)
• 密度：
  1,6 g/cm3
• LogP：
  0.46 at 25℃
• 物理描述：
  DryPowder

计算性质

• 辛醇/水分配系数(LogP)：
  -2.16
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• TSCA：
  No
• 危险等级：
  9
• 危险品标志：
  Xn,N
• 安全说明：
  S36
• 危险类别码：
  R21/22,R41,R50
• WGK Germany：
  3
• 海关编码：
  29161100,2916110000
• 危险品运输编号：
  UN 3077

制备方法与用途

用途：

1. 用作过氧化物架桥助剂，能增加交联密度、提高硫化速度并缩短硫化时间。此外，它还能提升与金属的粘结性能。
2. 硫化制品可以得到盐性交联键，从而提高硬度，并显著改善曲挠性能和弹性。
3. 也可用于硫磺硫化体系，以增强拉伸强度并改善曲挠性能。
4. 本品具有耐酸、耐碱、耐油、耐腐蚀及耐高温的特性，适用于NBR、SBR、BR、EPDM 和 EPM 等胶种。

反应信息

• 作为产物：
  描述：

  丙烯酸 生成 Zinc acrylate
  参考文献：
  名称：

  SASAKI, TAKASI

  摘要：

  DOI：
• 作为试剂：
  描述：

  Zinc Oxide 、 、 丙烯酸 、 丙烯酸乙酯 、 、 在 Zinc acrylate 、 carboxylic acid 作用下， 以 Xylene butanol 、 Xylene n-butanol water 为溶剂， 以resulting in a solution of zinc acrylate polymer of 45 wt % in xylene/n-butanol/water (43.3:10.8:0.9 wt %)的产率得到Zinc acrylate
  参考文献：
  名称：

  Antifouling coating composition

  摘要：

  制备防污涂层组合物的工艺包括以下步骤：a）在有机溶剂中制备粘合剂聚合物；b）将粘合剂聚合物和有机溶剂乳化到水中；c）从乳液中去除全部或部分有机溶剂；d）将乳液配制成水性防污涂层组合物。

  公开号：

  US09133347B2

文献信息

• ALKALI-DEVELOPABLE PHOTOSENSITIVE RESIN COMPOSITION AND BETA-DIKETONE COMPOUND
  申请人：Yamada Takashi

  公开号：US20100129753A1

  公开（公告）日：2010-05-27

  An alkali developable photosensitive resin composition contains (J) a photopolymerizable unsaturated compound having a structure resulting from the addition reaction of (B) a compound having a β-diketone moiety or a compound having a β-ketoester group to the (meth)acryloyl group of (A) a compound having at least two (meth)acryloyl groups and a hydroxyl group and subsequent esterification of the hydroxyl group of the resulting addition product with (C) a polybasic acid anhydride. The compound having a β-diketone moiety is preferably a novel β-diketone compound represented by general formula (I): wherein R 1 is a C1-C20 alkyl group; R 2 represents R 11 , OR 11 , COR 11 , SR 11 , CONR 12 R 13 , or CN; R 11 , R 12 , and R 13 are each hydrogen, a C1-C20 alkyl group, etc.; a is 0 to 3; and b is 0 to 4.

  一种可由碱显影的光敏树脂组合物，含有（J）一种光聚合不饱和化合物，该化合物的结构是由（B）含β-二酮基团或含β-酮酯基团的化合物与（A）含至少两个(甲基)丙烯酰基团和一个羟基的化合物中的(甲基)丙烯酰基团发生加成反应，并随后将所得加成产物的羟基与（C）多元酸酐进行酯化反应得到的。含β-二酮基团的化合物最好是表示为通用公式（I）的一种新型β-二酮化合物：其中R1是C1-C20烷基团；R2代表R11、OR11、COR11、SR11、CONR12R13或CN；R11、R12和R13分别是氢、C1-C20烷基团等；a是0到3；b是0到4。
• SILANE COMPOUND, RUBBER COMPOSITION AND TIRE
  申请人：JXTG NIPPON OIL & ENERGY CORPORATION

  公开号：US20190085003A1

  公开（公告）日：2019-03-21

  Disclosed are a silane compound of the general formula (1) described below, as well as a rubber composition including the same, and a tire. A silane compound of the general formula (1) is useful because of its ability to provide a silane compound comprising: a reactive functional group having a high reactivity with an organic polymer material such as rubber, and having a low polarity; and a hydrolyzable group having a high reactivity with an inorganic material such as silica or glass. The symbols in the formula are defined in the specification.

  下面描述的一般式（1）的硅烷化合物，以及包括该硅烷化合物的橡胶组合物和轮胎。一般式（1）的硅烷化合物是有用的，因为它能够提供包括：具有与橡胶等有机聚合物材料高反应性且极性低的反应性功能基团；以及具有与二氧化硅或玻璃等无机材料高反应性的可水解基团的硅烷化合物。该式中的符号在说明书中有定义。
• [EN] SILICA-BASED ZINC CATALYSTS. THEIR PREPARATION AND USE IN THE ALKOXYCARBONYLATION OF AMINES<br/>[FR] CATALYSEURS AU ZINC À BASE DE SILICE, LEUR PRÉPARATION ET LEUR UTILISATION DANS L'ALCOXYCARBONYLATION D'AMINES
  申请人：COVESTRO DEUTSCHLAND AG

  公开号：WO2018210711A1

  公开（公告）日：2018-11-22

  The present invention relates to silica-based heterogeneous zinc compounds which are suitable as catalysts in the reaction of amines with dialkyl carbonates to produce carbamates. The catalysts have the formula [SiO2]-CH2-CHR-X-COOZn[Y], wherein [SiO2] represents a silica carrier selected from the group consisting of ordered mesoporous silica and irregular amorphous narrow pore silica, R represents a moiety selected from the group consisting of hydrogen, -CH3, and -CH2CH3, preferably hydrogen, X is an aliphatic chain of 2 to 11 carbon atoms that optionally comprises ether moieties and [Y] represents a mono anion. The invention is also directed towards a method for the preparation of the aforementioned compounds and towards method for the alkoxycarbonylation of amines.

  本发明涉及硅基杂化锌化合物，适用于作为催化剂在胺与二烷基碳酸酯反应中产生氨基甲酸酯。催化剂的化学式为[SiO2]-CH2-CHR-X-COOZn[Y]，其中[SiO2]代表从有序介孔硅和不规则非晶窄孔硅组成的硅载体，R代表从氢、-CH3和-CH2CH3组成的基团，优选为氢，X是由2至11个碳原子组成的脂肪链，可选地包含醚基团，[Y]代表单阴离子。该发明还涉及上述化合物的制备方法以及胺的烷氧羰基化方法。
• METALLIC CROSSLINKING COAGENT, PREPARATION METHODS THEREOF, AND RESIN COMPOSITION COMPRISING THE SAME
  申请人：KUO CHING CHEMICAL CO., LTD.

  公开号：US20160326196A1

  公开（公告）日：2016-11-10

  Provided are a metallic crosslinking coagent, preparation methods thereof, and a resin composition comprising the metallic crosslinking coagent. With the active-hydrogen containing organic phosphorus compound group and metallophilic acrylate group, the metallic crosslinking coagent provides both stabilizer and flame-retardant effects, enhances the crosslinking efficiency of the resin composition, and improves the compatibility between flame retardant and the polymer. Accordingly, the metallic crosslinking coagent is effective to improve the mechanical properties of the application material and to develop a safe and environmentally friendly flame retardant material.

  提供了一种金属交联交联剂，其制备方法，以及包含该金属交联交联剂的树脂组合物。金属交联交联剂具有活性氢含有机磷化合物基团和金属亲和丙烯酸酯基团，提供了稳定剂和阻燃效果，增强了树脂组合物的交联效率，并改善了阻燃剂与聚合物之间的相容性。因此，金属交联交联剂有效地提高了应用材料的机械性能，并开发了一种安全和环保的阻燃材料。
• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。