(E)-phyt-3-ene | 532426-80-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (E)-phyt-3-ene
• 英文别名: (E)-3,7,11,15-tetramethylhexadec-3-ene
• CAS: 532426-80-5
• 化学式: C₂₀H₄₀
• 分子量: 280.538
• InChiKey: UXTARNPPVKJLKM-LDADJPATSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (E)-phyt-3-ene 在 二苯二硫醚 作用下， 以 正己烷 为溶剂， 生成 (Z)-phyt-3-ene
  参考文献：
  名称：

  Reductive Desulfurization of Allylic Thiols by HS^-/H₂S in Water Gives Clue to Chemical Reactions Widespread in Natural Environments

  摘要：

  The reduction of allylic thiois to alkenes by hydrogen sulfide in aqueous solutions, a novel reaction that may explain reduction processes widely occurring in natural environments, has been discovered. Its mechanism has been studied and suggested to follow an S(RN)1-like pathway involving radical intermediates undergoing 1,4 hydrogen shifts.

  DOI：

  10.1021/ol034374j
• 作为产物：
  描述：

  叶绿醇 在 titanium(IV) isopropylate 、 4-二甲氨基吡啶 、 二异丁基氢化铝 、 三乙胺 、 对甲苯磺酰氯 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 乙醚 、 二氯甲烷 为溶剂， 生成 (E)-phyt-3-ene
  参考文献：
  名称：

  Reductive Desulfurization of Allylic Thiols by HS^-/H₂S in Water Gives Clue to Chemical Reactions Widespread in Natural Environments

  摘要：

  The reduction of allylic thiois to alkenes by hydrogen sulfide in aqueous solutions, a novel reaction that may explain reduction processes widely occurring in natural environments, has been discovered. Its mechanism has been studied and suggested to follow an S(RN)1-like pathway involving radical intermediates undergoing 1,4 hydrogen shifts.

  DOI：

  10.1021/ol034374j

文献信息

• Reductive Desulfurization of Allylic Thiols by HS^-/H₂S in Water Gives Clue to Chemical Reactions Widespread in Natural Environments
  作者：Yanek Hebting、Pierre Adam、Pierre Albrecht

  DOI：10.1021/ol034374j

  日期：2003.5.1

  The reduction of allylic thiois to alkenes by hydrogen sulfide in aqueous solutions, a novel reaction that may explain reduction processes widely occurring in natural environments, has been discovered. Its mechanism has been studied and suggested to follow an S(RN)1-like pathway involving radical intermediates undergoing 1,4 hydrogen shifts.