7,7-dimethyl-1-vinylbicyclo[2.2.1]heptan-2-one | 125409-77-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 7,7-dimethyl-1-vinylbicyclo[2.2.1]heptan-2-one
• 英文别名: Bicyclo[2.2.1]heptan-2-one, 1-ethenyl-7,7-dimethyl-；1-ethenyl-7,7-dimethylbicyclo[2.2.1]heptan-2-one
• CAS: 125409-77-0
• 化学式: C₁₁H₁₆O
• 分子量: 164.247
• InChiKey: UEVFTEJYOXJPNL-UHFFFAOYSA-N

物化性质

• 沸点：
  212.3±19.0 °C(Predicted)
• 密度：
  1.054±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  7,7-dimethyl-1-vinylbicyclo[2.2.1]heptan-2-one 在 potassium tert-butylate 、 mercury(II) oxide 作用下， 以 四氢呋喃 、 硫酸 、 丙酮 为溶剂， 反应 0.67h， 生成 (-)-1-{(1S,2R,4R)-1-ethenyl-2-hydroxy-7,7-dimethylbicyclo[2.2.1]hept-2-yl}ethan-1-one
  参考文献：
  名称：

  摘要：

  Reactions were studied of (-)-(1S,4R)-1-vinyl-7,7-dimethylbicyclo[2.2.1]heptan-2-one with ethyl acetate lithium derivative, potassium acetylide, ozone, with a system OsO4-N-methylmorpholine N-oxide, and some subsequent transformations of the products obtained.

  DOI：

  10.1023/a:1013180012045

文献信息

• Use Of Polyisobutenyl Succinic Anhydride-Based Block Copolymers In Cosmetic Preparations
  申请人：Wendel Volker

  公开号：US20080199420A1

  公开（公告）日：2008-08-21

  The invention relates to novel cosmetic preparations comprising an O/W emulsion, where the O/W emulsion comprises at least one amphiphilic polymer comprising one or more hydrophobic units A and one or more hydrophilic units B, where the hydrophobic units A are formed from polyisobutenes modified with terminal, polar groups, at least one component with an HLB value in the range from 8 to 20, and at least one oil and/or fat phase and water.

  这项发明涉及一种新型化妆品制剂，包括一种O/W乳液，其中该O/W乳液包括至少一种含有一个或多个疏水单元A和一个或多个亲水单元B的两性聚合物，其中疏水单元A由末端极性基团改性的聚异丁烯形成，至少包括一个HLB值在8到20范围内的成分，以及至少一个油脂相和水。
• Anionic, Ampholytic Copolymers for Low-Voc-Compositions
  申请人：Kim Son Nguyen

  公开号：US20080219934A1

  公开（公告）日：2008-09-11

  The present invention provides cosmetic compositions containing a copolymer obtainable by the copolymerization of at least one methacrylic acid ester, methacrylic acid, acrylic acid, optionally at least one compound containing amino groups and polymerizable by free radical polymerization, and optionally other olefinically unsaturated compounds polymerizable by free radical polymerization. The copolymerization can be carried out in the presence of silicones f) containing polyalkylene oxide.

  本发明提供了一种化妆品组合物，其中包含由至少一种甲基丙烯酸酯，甲基丙烯酸，丙烯酸，可选地至少一种含有氨基团的自由基聚合可聚合化合物以及可选地由自由基聚合可聚合的其他烯烃类不饱和化合物共聚而成的共聚物。共聚反应可以在含有聚烷基氧化物的硅烷f）的存在下进行。
• Hair Setting Compositions Based on T-Butyl Acrylate and Hydroxyalkyl Methacrylate
  申请人：Winter Gabi

  公开号：US20080260658A1

  公开（公告）日：2008-10-23

  The present invention relates to copolymers, which comprises, in copolymerized form, between 25 and 80% by weight of tert-butyl (meth)acrylate, 2 to 60% by weight of hydroxyalkyl (meth)acrylate, 10 to 40% by weight of an anionic or anionogenic, free-radically polymerizable, olefinically unsaturated compound which is or comprises methacrylic acid, and, if appropriate, up to 30% by weight of a further free-radically polymerizable, olefinically unsaturated compound. In addition, the present invention relates to the use of such copolymers in cosmetic preparations, and to such cosmetic preparations per se.

  本发明涉及共聚物，其在共聚形式中包含25至80重量％的叔丁基（甲基）丙烯酸酯，2至60重量％的羟基烷基（甲基）丙烯酸酯，10至40重量％的阴离子或阴离子型，自由基聚合可聚合的烯烃不饱和化合物，其是或包含甲基丙烯酸，并且如有必要，还可包含多达30重量％的其他自由基聚合可聚合的烯烃不饱和化合物。此外，本发明还涉及在化妆品制剂中使用这种共聚物，以及这种化妆品制剂本身。
• Composition containing retinol and a compound capable of screening out UVA radiation
  申请人：L'OREAL

  公开号：US20020137795A1

  公开（公告）日：2002-09-26

  The present invention relates to a composition containing retinol and a compound capable of screening out UVA radiation corresponding to formula (I): 1 which is preferably benzene-1,4-di(3-methylidene-10-camphorsulphonic acid).

  本发明涉及一种包含维生素A醇和一种能够筛选出与式(I)相对应的UVA辐射的化合物的组合物，式(I)最好是苯-1,4-二(3-甲基亚甲基-10-樟脑磺酸)。
• COPOLYMERS FOR COSMETIC APPLICATIONS
  申请人：Kim Son Nguyen

  公开号：US20100135918A1

  公开（公告）日：2010-06-03

  The present invention relates to aqueous skin or hair cosmetic preparations which comprise at least one polymer A which comprises, in copolymerized form, at least one ester of (meth)acrylic acid, at least one olefinically unsaturated, free-radically polymerizable anionogenic or anionic compound, at least one free-radically polymerizable olefinically unsaturated urethane-group-containing compound which comprises no silicone groups and, if appropriate, further free-radically polymerizable compounds.

  本发明涉及至少包含一种聚合物A的水基皮肤或头发化妆品制剂，该聚合物A在共聚物形式下包含至少一种丙烯酸酯，至少一种烯丙基不饱和，自由基聚合的阴离子性或阴离子化合物，至少一种不含硅基的自由基聚合烯丙基不饱和脲基含量化合物，如适当的，还包括其他自由基聚合化合物。