N-(2-(perfluorooctyl)ethyl)methacrylamide | 117068-30-1

• 物质功能分类: 有机原料 - 氨基化合物 - 酰胺类化合物
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(2-(perfluorooctyl)ethyl)methacrylamide
• 英文别名: N-[2-(Heptadecafluorooctyl)ethyl]methacrylamide；N-(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)-2-methylprop-2-enamide
• CAS: 117068-30-1
• 化学式: C₁₄H₁₀F₁₇NO
• 分子量: 531.212
• InChiKey: RTFYYCDNYOVCEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  33
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  29.1
• 氢给体数：
  1
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8-十七氟-10-碘庚烷 在 sodium azide 、 甲基三辛基氯化铵 、 一水合肼 、 三乙胺 作用下， 以 乙醚 、 水 为溶剂， 反应 50.0h， 生成 N-(2-(perfluorooctyl)ethyl)methacrylamide
  参考文献：
  名称：

  NMR and fluorescence studies of the self-association behavior of an amphiphilic polyanion bearing hydrocarbon and fluorocarbon hydrophobes

  摘要：

  The association behavior of the terpolymers of sodium 2-acrylamido-2-methylpropanesulfonate (NaAMPS), N-dodecylmethacrylamide (DodMAm), and N-(2-(perfluorooctyl)ethyl)methacrylamide (PFOEMAm) (A/H(x)/F(y)) and their reference copolymers of NaAMPS and PFOEMAm (A/F(y)) was characterized using F-19 and H-1 NMR, steady state fluorescence, and dynamic light scattering techniques in water (or D2O) containing 0.1 M NaCl. The terpolymers formed micelle-like aggregates where hydrophobic microdomains are formed by hydrophobic associations among the perfluorooctylerhyl (PFOE) and dodecyl (Dod) groups, the PFOE group exhibiting a stronger tendency for interpolymer association than the Dod groups. A careful analysis of the characterization data led to a conclusion that the hydrophobic microdomain formed from the terpolymer is microscopically phase separated into the fluorocarbon phase and hydrocarbon phase. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2011.02.015

文献信息

• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Multifunctional polymers
  申请人：ISP Investments Inc.

  公开号：US10087273B2

  公开（公告）日：2018-10-02

  Described herein are multifunctional polymers comprising a first repeating unit having at least one pseudo-cationic moiety, a second repeating unit having at least a hydrophobic moiety, and a third repeating unit, where the weight-average molecular weight is less than about 10,000 Da. In one embodiment the polymers exhibit antimicrobial activity. Also provided are compositions formulated with the multifunctional polymers, and a method of providing antimicrobial activity.

  本文描述的多功能聚合物包含具有至少一个假阳离子分子的第一重复单元、具有至少一个疏水分子的第二重复单元和第三重复单元，其中重量平均分子量小于约 10,000 Da。在一个实施方案中，聚合物具有抗菌活性。此外，还提供了用多功能聚合物配制的组合物，以及提供抗菌活性的方法。
• [EN] ACRYLAMIDE NANO COATING AND PREPARATION METHOD THEREFOR<br/>[FR] NANOREVÊTEMENT D'ACRYLAMIDE ET PROCÉDÉ DE PRÉPARATION S'Y RAPPORTANT<br/>[ZH] 一种丙烯酰胺纳米涂层及其制备方法
  申请人：JIANGSU FAVORED NANOTECHNOLOGY CO LTD

  公开号：WO2020082671A1

  公开（公告）日：2020-04-30

  一种丙烯酰胺纳米涂层，将基材暴露于单体蒸汽氛围中，通过等离子体放电在基材表面发生化学反应形成保护涂层；单体蒸汽为汽化的单体1或者单体2，或者单体1和单体2的混合物；单体1具有如下的式(I)所示结构；单体2具有如下的式(II)所示结构；单体1：(I) 单体2： (II) 其中，R 1、R 2、R 3、R 6、R 7、R 8独立地选自氢、烷基、芳基、卤素、卤代烷基、烯基或卤代烯基，X、Y为氢或卤素；R 4、R 5独立地选自氢、烷基、芳基、卤素、卤代烷基或者具有式(III)所示结构: (III) R 11为碳原子数1-15的直链或者含有支链烷烃亚基，R 12、R 13、R 14、R 15为独立地选自氢、烷基、芳基、卤素或卤代烷基；R 9、R 10独立地选自碳原子数为1-15的直链、含有支链的烷基亚基或者含有芳基亚基；或者R 9、R 10为连接的键； m、n、p、q为0-20的整数，但m、n不同时为0，p、q不同时为0。还公开了一种丙烯酰胺纳米涂层的制备方法。
• MULTIFUNCTIONAL POLYMERS
  申请人：ISP Investments Inc.

  公开号：US20150044161A1

  公开（公告）日：2015-02-12

  Described herein are multifunctional polymers comprising a first repeating unit having at least one pseudo-cationic moiety, a second repeating unit having at least a hydrophobic moiety, and a third repeating unit, where the weight-average molecular weight is less than about 10,000 Da. In one embodiment the polymers exhibit antimicrobial activity. Also provided are compositions formulated with the multifunctional polymers, and a method of providing antimicrobial activity.
• NMR and fluorescence studies of the self-association behavior of an amphiphilic polyanion bearing hydrocarbon and fluorocarbon hydrophobes
  作者：Akihito Hashidzume、Kentaro Matsuda、Takahiro Sato、Yotaro Morishima

  DOI：10.1016/j.polymer.2011.02.015

  日期：2011.3

  The association behavior of the terpolymers of sodium 2-acrylamido-2-methylpropanesulfonate (NaAMPS), N-dodecylmethacrylamide (DodMAm), and N-(2-(perfluorooctyl)ethyl)methacrylamide (PFOEMAm) (A/H(x)/F(y)) and their reference copolymers of NaAMPS and PFOEMAm (A/F(y)) was characterized using F-19 and H-1 NMR, steady state fluorescence, and dynamic light scattering techniques in water (or D2O) containing 0.1 M NaCl. The terpolymers formed micelle-like aggregates where hydrophobic microdomains are formed by hydrophobic associations among the perfluorooctylerhyl (PFOE) and dodecyl (Dod) groups, the PFOE group exhibiting a stronger tendency for interpolymer association than the Dod groups. A careful analysis of the characterization data led to a conclusion that the hydrophobic microdomain formed from the terpolymer is microscopically phase separated into the fluorocarbon phase and hydrocarbon phase. (C) 2011 Elsevier Ltd. All rights reserved.