7-(3-bromophenyl)dibenzo[c,h]acridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7-(3-bromophenyl)dibenzo[c,h]acridine
• 英文别名: 7-(3-Bromophenyl)dibenzo[c,h]acridine；13-(3-bromophenyl)-2-azapentacyclo[12.8.0.03,12.04,9.017,22]docosa-1,3(12),4,6,8,10,13,15,17,19,21-undecaene
• 化学式: C₂₇H₁₆BrN
• 分子量: 434.335
• InChiKey: YAEPFSXMSDGBTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  29
• 可旋转键数：
  1
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  7-(3-bromophenyl)dibenzo[c,h]acridine 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 四(三苯基膦)钯 、 乙二醇二甲醚 、 potassium acetate 、 potassium carbonate 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 84.0h， 生成 7-(5'-phenyl-[1,1':3',1''-terbenzene]-3-yl)dibenzo[c,h]acridine
  参考文献：
  名称：

  [EN] COMPOUND FOR ELECTRONIC DEVICE AND ELECTRONIC DEVICE AND DISPLAY DEVICE
  [FR] COMPOSÉ POUR DISPOSITIF ÉLECTRONIQUE, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'AFFICHAGE

  摘要：

  本发明涉及一种吖啶衍生物的化合物，以及有机半导体材料的有机半导体层，包括吖啶衍生物的电子器件，包括吖啶衍生物的有机发光二极管的器件，以及其显示器件和制造方法。（I）其中L从苯基、萘基和联萘基中选择；R1、R2、R3、R4和R5独立地从未取代或取代C6到C18芳基和未取代或取代的吡啶基中选择；取代基从氘、C1到C12烷基和C1到C12烷氧基中选择；a、b、c、d和e独立地从0或1中选择，且2≤a+b+c+d+e≤5。

  公开号：

  WO2018077689A1
• 作为产物：
  描述：

  7-(3-bromophenyl)-5,6,8,9-tetrahydrodibenzo[c,h]acridine 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 1,4-二氧六环 为溶剂， 反应 48.0h， 以74%的产率得到7-(3-bromophenyl)dibenzo[c,h]acridine
  参考文献：
  名称：

  有機半導体材料を含んでいる電子デバイス

  摘要：

  提供至少含有一种化合物的有机半导体材料，以及至少包含该化合物的电子设备。所述化合物由式（I）表示。[其中，R1-4为H、卤素、CN或取代/非取代的C1-20烷基或杂原子烷基、C6-20芳基或C5-20杂原子芳基、C1-20烷氧基或C6-20芳氧基；Ar为取代/非取代的C6-C20芳基或C5-C20杂原子芳基；R5为取代/非取代的C6-20芳基或C5-20杂原子芳基、H、F或从式（I）中除去Ar-R5基的基]【选择图】无

  公开号：

  JP2017025072A

文献信息

• [EN] ORGANIC SEMICONDUCTIVE LAYER COMPRISING PHOSPHINE OXIDE COMPOUNDS<br/>[FR] COUCHE SEMI-CONDUCTRICE ORGANIQUE COMPRENANT DES COMPOSÉS OXYDES DE PHOSPHINE
  申请人：NOVALED GMBH

  公开号：WO2017089399A1

  公开（公告）日：2017-06-01

  The present invention relates to an. organic semiconductive layer which is an electron transport layer and/or an electron injection layer and/or an n-type charge generation layer, the organic semiconductive layer comprising at least one compound of formula (1) wherein R1 and R2 are each independently selected from C1 to C16 alkyl; Ar1 is selected from C6 to C14 arylene or C3 to C12 heteroarylene; Ar2 is independently selected from C14 to C40 arylene or C8 to C40 heteroarylene; R3 is independently selected from H, C1 to C12 alkyl or C10 to C20 aryl; wherein each of Ar1, Ar2 and R3 may each independently be uesubstituted or substituted with at least one C1 to C12 alky group; n is 0 or 1; and m is 1 in case of n = 0; and m is 1 or 2 in case of n = 1, phosphine oxide compounds comprised therein and to organic electroluminescent devices comprising such layers and compounds.

  本发明涉及一种有机半导体层，该层是电子传输层和/或电子注入层和/或n型电荷生成层，该有机半导体层包括至少一种符合式（1）的化合物，其中R1和R2分别独立地选自C1到C16烷基；Ar1选自C6到C14芳基或C3到C12杂芳基；Ar2独立地选自C14到C40芳基或C8到C40杂芳基；R3独立地选自H，C1到C12烷基或C10到C20芳基；其中Ar1、Ar2和R3中的每一个可以独立地未取代或取代为至少一个C1到C12烷基基团；n为0或1；当n=0时，m为1；当n=1时，m为1或2；其中包括磷氧化物化合物以及包含这些层和化合物的有机电致发光器件。
• Organic Semiconducting Material Comprising an Electrical n-Dopant and an Electron Transport Matrix and Electronic Device Comprising the Semiconducting Material
  申请人：Novaled GmbH

  公开号：US20180114921A1

  公开（公告）日：2018-04-26

  The present invention relates to an organic semiconducting material and to an electronic device comprising the semiconducting material, particularly to an electroluminescent device, particularly to an organic light emitting diode (OLED), wherein the semiconducting material comprises a first electron transport matrix compound and an electrical n-dopant; the invention pertains also to a device comprising the electric device and/or the electroluminescent device, particularly to a display device, particularly to a display device comprising the OLED.

  本发明涉及一种有机半导体材料以及包括该半导体材料的电子设备，特别是一种电致发光器件，特别是一种有机发光二极管（OLED），其中该半导体材料包括第一电子传输基质化合物和一种电子n-掺杂剂；该发明还涉及一种包括该电子设备和/或该电致发光器件的设备，特别是一种显示设备，特别是一种包括OLED的显示设备。
• Organic Electroluminescent Device Comprising a Redox-Doped Electron Transport Layer and an Auxiliary Electron Transport Layer
  申请人：Novaled GmbH

  公开号：US20180114940A1

  公开（公告）日：2018-04-26

  The present invention relates to an organic electroluminescent device, particularly to an organic light emitting diode (OLED) including an ETL stack of at least two electron transport layers, wherein the first electron transport layer comprises a first electron transport matrix compound and the second electron transport layer comprises second electron transport matrix compound and a redox n-dopant, and a device comprising the OLED.

  本发明涉及有机电致发光器件，特别是涉及一种包括至少两个电子传输层的有机发光二极管（OLED）的器件，其中第一个电子传输层包括第一个电子传输基质化合物，第二个电子传输层包括第二个电子传输基质化合物和一个氧化还原n掺杂剂，以及包括该OLED的器件。
• [EN] COMPOUND, ORGANIC SEMICONDUCTING MATERIAL COMPRISING THE SAME, ORGANIC ELECTRONIC DEVICE COMPRISING THE SAME, AND DISPLAY DEVICE AND LIGHTING DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ, MATÉRIAU SEMI-CONDUCTEUR ORGANIQUE LE COMPRENANT, DISPOSITIF ÉLECTRONIQUE ORGANIQUE LE COMPRENANT, ET DISPOSITIF D'AFFICHAGE ET DISPOSITIF D'ÉCLAIRAGE LE COMPRENANT
  申请人：NOVALED GMBH

  公开号：WO2020212408A1

  公开（公告）日：2020-10-22

  The present invention relates to an organic semiconducting material comprising a compound comprising at least one dibenzo [c,h) acridine group and at least one CN-group, organic electronic devices comprising the same and display devices comprising the same.

  本发明涉及一种有机半导体材料，包括至少一个二苯并[c，h]芴基团和至少一个CN基团的化合物，以及包含该材料的有机电子器件和显示器件。
• Compound, Organic Electronic Device Comprising the Same, and Display Device and Lighting Device Comprising the Same
  申请人：Novaled GmbH

  公开号：US20200161565A1

  公开（公告）日：2020-05-21

  The present invention relates to a compound of the formula (I) wherein all of R 1 to R 11 , except one, are independently selected from the group consisting of H, D, F, substituted or unsubstituted C 1 to C 18 alkyl, substituted or unsubstituted C 6 to C 42 aryl, substituted or unsubstituted C 3 to C 42 heteroaryl; and adjacent groups R 1 to R 11 may be linked to each other to form a fused ring, wherein the one of R 1 to R 11 not selected from the above groups is a group G, wherein the group G comprises one atom A having an electron pair in a p-orbital thereof; the group G comprises two 6-membered aryl rings which are attached to the atom A, wherein each of the two 6-membered aryl rings is attached to the atom A via a single bond respectively; and wherein the two 6-membered aryl rings attached to the atom A may be connected with each other via a single bond; the group G comprises 12 to 66 carbon atoms in total; the group G is attached to the benzoacridine part of the compound of formula (I) via a single bond or via a C 6 to C 18 arylene group, wherein the C 6 to C 18 arylene group is part of the group G; and the group G is unsubstituted or substituted with one or more substituents independently selected from the group consisting of D, F, C 1 to C 18 alkyl, C 6 to C 42 aryl, C 6 to C 42 heteroaryl, (R 12 ) 2 P═O, CN or G′, wherein the group G′ is defined likewise the group G with the exception that the group G′ is not attached to the benzoacridine part of the compound of formula (I) but to the group G via a single bond or via a C 6 to C 18 arylene group, wherein the C 6 to C 18 arylene group is part of the group G′ provided that in case that the group G is attached to the benzacridine part of the compound of formula (I) via the C 6 to C 18 arylene group, substituents which may be attached to the C 6 to C 18 arylene group are only selected from the group consisting of C 1 to C 18 alkyl, C 6 to C 42 aryl, (R 12 ) 2 P═O and CN; wherein in case that at least one of R 1 to R 11 , which is not the group G, is substituted, the respective substituent or substituents are independently selected from the group consisting of D, F, C 1 to C 18 alkyl, C 6 to C 36 aryl, C 6 to C 42 heteroaryl, (R 12 ) 2 P═O, CN; and wherein R 12 are independently selected from the group consisting of C 1 to C 18 alkyl and C 6 to C 24 aryl, an organic electronic device comprising the compound and a display device or lighting device comprising the organic electronic device.

  本发明涉及式(I)的化合物，其中除一个之外的所有R1至R11均独立选自以下组：H、D、F、取代或未取代的C1至C18烷基、取代或未取代的C6至C42芳基、取代或未取代的C3至C42杂芳基；相邻的R1至R11可能连接在一起形成融合环，其中未从上述组中选择的R1至R11中的一个是一个G基团，其中G基团包含具有p轨道中的一个电子对的一个原子A；G基团包括连接到原子A的两个6元芳环，其中每个6元芳环分别通过单键连接到原子A；连接到原子A的两个6元芳环可以通过单键连接在一起；G基团总共包括12至66个碳原子；G基团通过单键或C6至C18芳撑基与式(I)化合物的苯并蒽部分连接，其中C6至C18芳撑基是G基团的一部分；G基团未取代或取代，其中一个或多个取代基独立选自以下组：D、F、C1至C18烷基、C6至C42芳基、C6至C42杂芳基、（R12）2P═O、CN或G′，其中G′基团的定义与G基团类似，除了G′基团不连接到式(I)化合物的苯并蒽部分，而是通过单键或C6至C18芳撑基连接到G基团，其中C6至C18芳撑基是G′基团的一部分，前提是如果G基团通过C6至C18芳撑基连接到式(I)化合物的苯并蒽部分，则可以连接到C6至C18芳撑基的取代基仅选自C1至C18烷基、C6至C42芳基、（R12）2P═O和CN的组中；如果至少有一个不是G基团的R1至R11取代，则相应的取代基独立选自以下组：D、F、C1至C18烷基、C6至C36芳基、C6至C42杂芳基、（R12）2P═O、CN；其中R12独立选自以下组：C1至C18烷基和C6至C24芳基。本发明还涉及包括该化合物的有机电子器件以及包括该有机电子器件的显示器件或照明装置。