2-[(4-乙烯基苯氧基)甲基]环氧乙烷 | 2653-39-6

• 物质功能分类: 有机原料 - 醚类化合物及其衍生物 - 醚、醚醇
• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 2-[(4-乙烯基苯氧基)甲基]环氧乙烷
• 英文名称: 4-vinylphenyl glycidyl ether
• 英文别名: 4VPGE；Para-glycidyloxystyrene；Oxirane, ((4-ethenylphenoxy)methyl)-；2-[(4-ethenylphenoxy)methyl]oxirane
• CAS: 2653-39-6
• 化学式: C₁₁H₁₂O₂
• 分子量: 176.215
• InChiKey: AAUXVPAKDMCMMN-UHFFFAOYSA-N

物化性质

• 熔点：
  30 °C
• 沸点：
  117-118 °C(Press: 0.4 Torr)
• 密度：
  1.103±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-[(4-乙烯基苯氧基)甲基]环氧乙烷 、 苯硅烷 在 C₁₀H₁₄CoO₅ 、 4,5-双二苯基膦-9,9-二甲基氧杂蒽 作用下， 以 四氢呋喃 为溶剂， 反应 3.0h， 以87%的产率得到
  参考文献：
  名称：

  钴催化乙烯基芳烃和脂族烯烃的区域发散性氢化硅烷化：配体和硅烷依赖性的区域选择性

  摘要：

  我们报告了由台式稳定Co（acac）2原位生成的催化剂催化的烯烃的区域发散性氢化硅烷化和基于膦或氮的配体。各种各样的乙烯基芳烃和脂肪族烯烃发生反应，从而以高分离产率（平均：84％）和高区域选择性（从91：9到> 99：1）提供支链（45例）或直链（37例）有机硅烷。该转化耐受各种官能团，包括醚，甲硅烷氧基，硫醚，环氧化物，卤素，胺，酯，硼酸酯，乙缩醛，氰基和酮部分。机理研究表明，钴/双膦系统催化的烯烃的硅氢化反应遵循Chalk-Harrod机理（带有Co-H中间体），而钴/吡啶-2,6-二亚胺系统的催化烯烃的硅氢化反应遵循修改后的Chalk-Harrod机制（带有Co-Si中间物）。

  DOI：

  10.1021/acscatal.6b02518
• 作为产物：
  描述：

  4-羟基苯乙烯 、 环氧氯丙烷 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 12.5h， 以5.73 g的产率得到2-[(4-乙烯基苯氧基)甲基]环氧乙烷
  参考文献：
  名称：

  4-乙烯基苯基缩水甘油醚：醇的合成，RAFT聚合和后聚合修饰

  摘要：

  合成了4-乙烯基苯基缩水甘油醚（4VPGE），一种含环氧基的苯乙烯单体，然后在可逆的加成-断裂链转移（RAFT）聚合条件下，以可控制的方式使用1-苯基乙基三硫代碳酸丁酯作为链转移剂进行聚合。通过与苯乙烯的扩链反应证实了所制得的聚合物的高度链端官能化，这提供了定义明确的嵌段共聚物。以苯基缩水甘油醚为模型化合物，通过BF 3鉴定缩水甘油基醇解的最佳反应条件 作为路易斯酸催化剂，随后在聚4VPGE的环氧基上用结构多样的醇库进行后聚合修饰，得到许多β-羟基醚官能化的聚合物。

  DOI：

  10.1021/acs.macromol.5b02437

文献信息

• [EN] LATENT ACIDS AND THEIR USE<br/>[FR] ACIDES LATENTS ET LEUR UTILISATION
  申请人：BASF SE

  公开号：WO2016124493A1

  公开（公告）日：2016-08-11

  Compounds of the formula (I) and (IA) wherein X is -O(CO)-; R1 is C1-C12haloalkyl or C6-C10haloaryl; R2 is located in position 7 of the coumarinyl ring and is OR8; R2a, R2b and R2C independently of each other are hydrogen; R3 is C1-C8haloalkyl or C1-C8haloalkyl; R4 is hydrogen; and R8 is C1-C6alkyI; are suitable as photosensitive acid donors in the preparation of photoresist compositions such as used for example in the preparation of spacers, insulating layers, interlayer dielectric films, insulation layers, planarization layers, protecting layers, overcoat layers, banks for electroluminescence displays and liquid crystal displays (LCD).

  化合物的化学式（I）和（IA），其中X为-O(CO)-；R1为C1-C12卤代烷基或C6-C10卤代芳基；R2位于香豆素环的第7位，为OR8；R2a、R2b和R2C彼此独立地为氢；R3为C1-C8卤代烷基或C1-C8卤代烷基；R4为氢；R8为C1-C6烷基，适用于作为感光酸给体，用于制备光刻胶组合物，例如用于制备间隔层、绝缘层、层间介质膜、绝缘层、平坦化层、保护层、覆盖层、电致发光显示器和液晶显示器（LCD）的制备。
• METHOD FOR PREPARING GLYCIDYLOXYSTYRENE MONOMERS AND POLYMERS THEREOF
  申请人：KUNITSKY KEITH

  公开号：US20080167433A1

  公开（公告）日：2008-07-10

  It was found that glycidyloxystyrenes, including glycidyloxystyrene and substituted glycidyloxystyrene, can be synthesized from hydroxycinnamic acid or substituted hydroxycinnamic acids in a one-pot, two-step process. The substrate can be thermally decarboxylated and then without purification, reacted in the presence of a halomethyl-oxirane and a base. The resulting product can be polymerized or coppolymerized to a fully substituted product.

  发现，包括环氧丙基苯乙烯和取代环氧丙基苯乙烯在内的环氧丙基苯乙烯可以从羟基肉桂酸或取代羟基肉桂酸在一个锅、两步法过程中合成。底物可以在热条件下脱羧，然后在无需纯化的情况下，在卤代甲基环氧烷和碱的存在下反应。得到的产物可以聚合或共聚形成完全取代的产物。
• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Metal compound composition
  申请人：——

  公开号：US20020045708A1

  公开（公告）日：2002-04-18

  The present invention relates to circle over (1)} a metal oxide or metallic Lewis acid composition comprising the metal oxide or the metallic Lewis acid carried on a cross-linked polymer compound, circle over (2)} a metal compound composition comprising the metal compound carried on a cross-linked product of a polymer compound containing a cross-linkable condensing functional group and/or a polymer containing a polymerizable double bond formed by a condensation reaction, circle over (3)} a method for producing a metal compound composition comprising the metal compound carried on a cross-linked polymer compound, which comprises mixing a non-cross-linked polymer compound containing a cross-linkable condensing functional group and/or a polymer compound containing a polymerizable double bond formed by a condensation reaction with a metal compound, and then cross-linking the polymer compound, circle over (4)} a carrier for carrying a metal compound comprising a 1st polymer compound containing a cross-linkable condensing functional group and/or a 2nd polymer compound containing a polymerizable double bond formed by a condensation reaction as a non-cross-linked polymer compound and circle over (5)} a method for improving solvent resistance, heat resistance and durability of a metal compound comprising mixing a non-cross-linked polymer compound containing a cross-linkable condensing functional group and/or a polymer compound containing a polymerizable double bond formed by a condensation reaction with a metal compound, and then cross-linking said polymer compounds.

  本发明涉及以下内容：circle over (1)}一种金属氧化物或金属路易斯酸组合物，包括承载于交联聚合物化合物上的金属氧化物或金属路易斯酸；circle over (2)}一种金属化合物组合物，包括承载于含有可交联缩合官能团的聚合物化合物的交联产物上的金属化合物和/或由缩合反应形成的聚合物中的聚合性双键；circle over (3)}一种制备金属化合物组合物的方法，包括将含有可交联缩合官能团的非交联聚合物化合物和/或由缩合反应形成的聚合物化合物与金属化合物混合，然后交联聚合物化合物；circle over (4)}一种用作载体的聚合物化合物，包括作为非交联聚合物化合物的含有可交联缩合官能团的第一聚合物化合物和/或含有由缩合反应形成的聚合性双键的第二聚合物化合物；circle over (5)}一种提高金属化合物耐溶剂、耐热和耐久性的方法，包括将含有可交联缩合官能团的非交联聚合物化合物和/或由缩合反应形成的聚合物化合物与金属化合物混合，然后交联所述聚合物化合物。
• Palladium catalyst composition
  申请人：Kobayashi Shu

  公开号：US20060019822A1

  公开（公告）日：2006-01-26

  The present invention discloses 1) a catalyst composition consisting of a crosslinked organic polymer compound and a palladium catalyst, wherein said catalyst is physically carried on said crosslinked organic polymer compound, 2) a manufacturing method of the above catalyst composition 1), characterized by homogenizing a straight chain organic polymer compound, having a crosslinkable functional group, and a palladium catalyst in a solvent dissolving said straight chain organic polymer compound, then depositing a composition thus formed and subjecting the crosslinkable functional group in said deposit to a crosslinking reaction, 3) a method for substitution reaction at an allyl position, characterized by reacting an allyl carbonate and a neucleophilic agent in the presence of the above catalyst composition 1), and 4) a method for oxidizing an alcohol, characterized by subjecting the above catalyst composition 1) to reaction with an alcohol. The catalyst composition of the present invention can be safely and easily handled without danger of spontaneous ignition, and the like, and is extremely useful as a catalyst for various chemical reactions, and further activity thereof is not decreased by repeated use thereof and a metal catalyst does not leak from a polymer compound which is a carrier thereof.

  本发明揭示了以下内容：1）由交联有机聚合物化合物和钯催化剂组成的催化剂组合物，其中所述催化剂物理上载在所述交联有机聚合物化合物上，2）上述催化剂组合物1）的制造方法，其特征在于在溶解所述直链有机聚合物化合物的溶剂中均质化具有可交联功能基团的直链有机聚合物化合物和钯催化剂，然后沉积形成的组合物并使所述沉积物中的可交联功能基团发生交联反应，3）一种在烯丙基位置进行取代反应的方法，其特征在于在上述催化剂组合物1）的存在下，将烯丙基碳酸酯和亲核试剂反应，4）一种氧化醇的方法，其特征在于将上述催化剂组合物1）与醇反应。本发明的催化剂组合物可以安全、容易地处理，没有自发着火等危险，并且极其有用作为各种化学反应的催化剂，其活性不会因重复使用而降低，并且金属催化剂不会从作为载体的聚合物化合物中泄漏。