2-iodo-2H,3H,3H-perfluorononane | 922524-02-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机碘化物
• 英文名称: 2-iodo-2H,3H,3H-perfluorononane
• 英文别名: 1,1,1,2,2,3,3,4,4,5,5,6,6,9,9,9-Hexadecafluoro-8-iodononane
• CAS: 922524-02-5
• 化学式: C₉H₃F₁₆I
• 分子量: 542.002
• InChiKey: LASSFECWGDYERA-UHFFFAOYSA-N

物化性质

• 沸点：
  196.6±8.0 °C(Predicted)
• 密度：
  1.909±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  乙酸烯丙酯 、 2-iodo-2H,3H,3H-perfluorononane 在 偶氮二异丁腈 作用下， 反应 10.0h， 生成 6,6,7,7,8,8,9,9,10,10,11,11,11-tridecafluoro-2-iodo-4-(trifluoromethyl)undecyl acetate
  参考文献：
  名称：

  Telomerization of 3,3,3-Trifluoroprop-1-ene and Functionalization of Its Telomers

  摘要：

  这段文字描述了四种3,3,3-三氟丙烯缩聚物的合成（R_F(C₃H₃F₃)_nI，n = 1, 2，R_F = n-C₆F₁₃- 或 (CF₃)₂CF-）及其烯丙基衍生物R_F(C₃H₃F₃)_nCH₂CH=CH₂。这些烯丙基缩聚物是通过三步反应制备的。第一步涉及3,3,3-三氟丙烯（TFP）与康普六氟-2-碘丙烷或十三氟-6-碘己烷的热和过氧化物诱导的大量缩聚反应，形成单加合物和双加合物，其比例取决于初始摩尔比0 = [R_FI]₀/[TFP]₀和反应温度。在180°C（热引发）和150°C（叔丁基过氧化物引发，DTBP）的温度下，单加合物的量增加至50-60%，双加合物增加至25-30%，R₀达到1.5。观察到(CF₃)₂CF^•自由基加成到TFP的=CH₂上是区域选择性的，导致选择性形成单一异构体，与n-C₆F₁₃^•自由基的加成相反。然后，这些缩聚物与丙烯醋酸酯反应，产生R_F(C₃H₃F₃)_nCH₂CH(I)CH₂OCOCH₃（n = 1, 2），产率为50-80%。第三步是将这些碘乙酸酯去碘醋解为R_F(C₃H₃F₃)_nCH₂-CH=CH₂（C,n），产率为50-80%。所有中间体均经过1H、19F核磁共振波谱表征，产物经过13C核磁共振波谱表征。

  DOI：

  10.1135/cccc20081747
• 作为产物：
  描述：

  3,3,3-三氟丙烯 、 全氟己基碘烷 在 二叔丁基过氧化物 作用下， 140.0 ℃ 、1.3 MPa 条件下， 反应 4.0h， 生成 2-iodo-2H,3H,3H-perfluorononane
  参考文献：
  名称：

  Telomerization of 3,3,3-Trifluoroprop-1-ene and Functionalization of Its Telomers

  摘要：

  这段文字描述了四种3,3,3-三氟丙烯缩聚物的合成（R_F(C₃H₃F₃)_nI，n = 1, 2，R_F = n-C₆F₁₃- 或 (CF₃)₂CF-）及其烯丙基衍生物R_F(C₃H₃F₃)_nCH₂CH=CH₂。这些烯丙基缩聚物是通过三步反应制备的。第一步涉及3,3,3-三氟丙烯（TFP）与康普六氟-2-碘丙烷或十三氟-6-碘己烷的热和过氧化物诱导的大量缩聚反应，形成单加合物和双加合物，其比例取决于初始摩尔比0 = [R_FI]₀/[TFP]₀和反应温度。在180°C（热引发）和150°C（叔丁基过氧化物引发，DTBP）的温度下，单加合物的量增加至50-60%，双加合物增加至25-30%，R₀达到1.5。观察到(CF₃)₂CF^•自由基加成到TFP的=CH₂上是区域选择性的，导致选择性形成单一异构体，与n-C₆F₁₃^•自由基的加成相反。然后，这些缩聚物与丙烯醋酸酯反应，产生R_F(C₃H₃F₃)_nCH₂CH(I)CH₂OCOCH₃（n = 1, 2），产率为50-80%。第三步是将这些碘乙酸酯去碘醋解为R_F(C₃H₃F₃)_nCH₂-CH=CH₂（C,n），产率为50-80%。所有中间体均经过1H、19F核磁共振波谱表征，产物经过13C核磁共振波谱表征。

  DOI：

  10.1135/cccc20081747

文献信息

• Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams, and foams stabilizers
  申请人：Boggs Janet

  公开号：US20070149437A1

  公开（公告）日：2007-06-28

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. RF compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F- monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供生产过程和系统，包括反应卤代化合物，脱卤化合物，反应醇，反应烯烃和饱和化合物，将至少含有两个—CF3基团的反应物与具有环状基团的反应物反应。提供RF组分，例如RF中间体，RF表面活性剂，RF单体，RF单体单元，RF金属络合物，RF磷酸酯，RF乙二醇，RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个—CF3基团，至少三个—CF3基团，和/或至少两个—CF3基团和至少两个—CH2—基团。提供包括RF表面活性剂组分的清洁剂，乳化剂，油漆，粘合剂，油墨，润湿剂，发泡剂和消泡剂。提供包括RF单体单元的丙烯酸，树脂和聚合物。提供包括具有RF组分的基底的组合物。提供包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。
• Production processes and systems, compositions, surfactants, monomer units, metal complexes, phosphate esters, glycols, aqueous film forming foams and foam stabilizers
  申请人：Boggs Janet

  公开号：US20070161537A1

  公开（公告）日：2007-07-12

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. R F -compositions such as R F -intermediates, R F -surfactants, R F monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and/or R F -foam stabilizers. The R F portion can include at least two CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F surfactants and/or R F -foam stabilizers are provided.

  提供了生产过程和系统，其中包括反应卤代化合物，去卤化化合物，反应醇，反应烯烃和饱和化合物，反应至少有两个—CF3基团的反应物与具有环状基团的反应物反应。提供了RF组分，例如RF中间体，RF表面活性剂，RF单体，RF单体单元，RF金属配合物，RF磷酸酯，RF乙二醇，RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个CF3基团，至少三个—CF3基团，以及至少两个—CF3基团和至少两个—CH2—基团。提供了包括RF表面活性剂组分的洗涤剂、乳化剂、油漆、粘合剂、油墨、润湿剂、起泡剂和消泡剂。提供了包括RF单体单元的丙烯酸、树脂和聚合物。提供了包括具有RF组分的基底的组合物。提供了可以包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。
• Production Processes and Systems, Compositions, Surfactants, Monomer Units, Metal Complexes, Phosphate Esters, Glycols, Aqueous Film Foams, and Foam Stabilizers
  申请人：Boggs Janet

  公开号：US20070282115A1

  公开（公告）日：2007-12-06

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohols, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. R F -compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供了包括反应卤代化合物、脱卤化合物、反应醇、反应烯烃和饱和化合物、反应至少具有两个-CF3基团的反应物与具有环状基团的反应物的生产过程和系统。提供了RF组分，例如RF中间体、RF表面活性剂、RF单体、RF单体单元、RF金属配合物、RF磷酸酯、RF乙二醇、RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个-CF3基团、至少三个-CF3基团，以及至少两个-CF3基团和至少两个-CH2-基团。提供了包括RF表面活性剂组分的洗涤剂、乳化剂、油漆、粘合剂、油墨、润湿剂、起泡剂和消泡剂。提供了包括RF单体单元的丙烯酸、树脂和聚合物。提供了包括RF组分覆盖在基底上的组合物。提供了可以包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。
• Production Processes and Systems, Compositions, Surfactants, Monomer Units, Metal Complexes, Phosphate Esters, Glycols, Aqueous Film Forming Foams, and Foam Stabilizers
  申请人：Boggs Janet

  公开号：US20080009655A1

  公开（公告）日：2008-01-10

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups. R F -compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and/or R F -foam stabilizers. The R F portion can include at least two —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 — groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供了生产过程和系统，其中包括反应卤代化合物，去卤化化合物，反应醇，反应烯烃和饱和化合物，反应至少具有两个-CF3基团的反应物与具有环状基团的反应物。提供了RF组分，例如RF中间体，RF表面活性剂，RF单体，RF单体单元，RF金属配合物，RF磷酸酯，RF乙二醇，RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个-CF3基团，至少三个-CF3基团，以及至少两个-CF3基团和至少两个-CH2-基团。提供了包括RF表面活性剂组分的洗涤剂，乳化剂，油漆，粘合剂，油墨，润湿剂，泡沫剂和消泡剂。提供了包括RF单体单元的丙烯酸，树脂和聚合物。提供了包括具有RF组分的基板的组合物。提供了含有RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。
• PRODUCTION PROCESSES AND SYSTEMS, COMPOSITIONS, SURFACTANTS, MONOMER UNITS, METAL COMPLEXES, PHOSPHATE ESTERS, GLYCOLS, AQUEOUS FILM FORMING FOAMS, AND FOAM STABILIZERS
  申请人：Boggs Janet

  公开号：US20120071689A1

  公开（公告）日：2012-03-22

  Production processes and systems are provided that include reacting halogenated compounds, dehalogenating compounds, reacting alcohol's, reacting olefins and a saturated compounds, reacting reactants having at least two —CF 3 groups with reactants having cyclic groups, R F -compositions such as R F -intermediates, R F -surfactants, R F -monomers, R F -monomer units, R F -metal complexes, R F -phosphate esters, R F -glycols, R F -urethanes, and or R F -foam stabilizers. The R F portion can include at least two groups —CF 3 groups, at least three —CF 3 groups, and/or at least two —CF 3 groups and at least two —CH 2 groups. Detergents, emulsifiers, paints, adhesives, inks, wetting agents, foamers, and defoamers including the R F -surfactant composition are provided. Acrylics, resins, and polymers are provided that include a R F -monomer unit. Compositions are provided that include a substrate having a R F -composition thereover. Aqueous Film Forming Foam (“AFFF”) formulations are provided that can include R F -surfactants and/or R F -foam stabilizers are provided.

  提供生产过程和系统，包括反应卤代化合物、去卤化化合物、反应醇、反应烯烃和饱和化合物、将至少具有两个—CF3基团的反应物与具有环状基团的反应物反应，RF组分，如RF中间体、RF表面活性剂、RF单体、RF单体单元、RF金属配合物、RF磷酸酯、RF乙二醇、RF聚氨酯和/或RF泡沫稳定剂。RF部分可以包括至少两个—CF3基团、至少三个—CF3基团和/或至少两个—CF3基团和至少两个—CH2基团。提供了包括RF表面活性剂组分的洗涤剂、乳化剂、油漆、粘合剂、油墨、润湿剂、起泡剂和消泡剂。提供了包括RF单体单元的丙烯酸、树脂和聚合物。提供了包括RF组分的基底上的组合物。提供了可以包括RF表面活性剂和/或RF泡沫稳定剂的水性成膜泡沫（“AFFF”）配方。